Perhitungan Neraca Massa dan Energi

Molecular Weight(Kg/Kgmol):
H2 2.016 (i)C4H10 58.124 C7H8
N2 28.013 C4H9 56.108 H2O
CH4 16.043 (n)C4H10 58.124 H2NCH2CH2
C2H4 28.054 C6H12 84.163 TIBAL
C2H6 30.07 C6H14 86.178

A.Ethylene Preparation
Laju alir massa gas masuk(Kg/hr) 18458
basis= 1 jam operasi
Massa gas masuk(Kg) 18458
BM Campuran gas masuk(Kg/Kgmol) 28.0556726
Mol gas masuk(Kgmol) 657.906166

1. Ethylene Storage Tank(C-2503)

H2 0.0005%
CH4 0.0099%
C2H4 99.8388% C-2503
C2H6 0.1504%
H2O 0.0004%

Akumulasi= input-output
Akumulasi= 0

Neraca Massa Pada Ethylene Storage Tank(C-2503)

Komponen Input Output
H2 0.0066316941 0.0066316941
CH4 1.0449240727 1.0449240727
C2H4 18427.14704497 18427.147044966
C2H6 29.7539905487 29.7539905487
H2O 0.0474087183 0.0474087183
Total 18458 18458
B. Hexene-1 Preparation
Laju Alir massa(Kg/hr) 224.8
Basis=1 jam operasi
Massa liquid masuk(Kg) 224.8
BM Campuran (Kg/Kgmol) 84.233992779
Mol Liquid 2.668756313

1. Co-monomer Feed Pump(G-1614/15)

G-1614/15
C6H12 96.08%
C6H14 3.91% G-1614/15
H2O 0.01%

Akumulasi= Input-Output
Akumulasi= 0

Neraca Massa Pada Co-monomer Feed Pump

Komponen Input Output
C6H12 215.8080506054 215.8080506054
C6H14 8.9863243102 8.9863243102
H2O 0.0056250845 0.0056250845
Total 224.8 224.8

C. Hydrogen Preparation
Laju Alir massa gas masuk (Kg/hr) 11.78
Basis=1 jam operasi
Massa gas masuk (Kg) 11.78
BM Campuran(Kg/Kgmol) 2.51499133
Mol gas masuk (Kgmol) 4.6839127672

1.Hydrogen Booster Compressor(K-1903/04)

H2 96.6983%
N2 0.30% K-1903/04
CH4 3.0014%

Akumulasi= Input - Output

Akumulasi= 0

Neraca massa Pada Hydrogen Booster Compressor(K-1903/04)

komponen Input Output
H2 9.1309962631 9.1309962631
N2 0.393631345 0.393631345
CH4 2.2553723919 2.2553723919
Total 11.78 11.78

d. TIBAL Preparation
Laju Alir Massa TIBAL masuk (Kg/hr) 4.36
Basis = 1 jam operasi
Massa TIBAL masuk (Kg) 4.36
BM TIBAL (Kg/Kgmol) 198.328
Mol TIBAL masuk (Kgmol) 0.0219837844
TIBAL 100%
G-1803/04

Neraca Massa Pada TIBAL Pump (G-1803/04)

Komponen Input Output
TIBAL 4.36 4.36

e. Catalyst Preparation
Laju Alir Massa Catalyst Masuk (Kg/hr) 25
Basis = 1 jam operasi
Massa Catalyst masuk (Kg) 25

1. Catalyst Mixer C-3921~3924

99,9%
0,000062 %

Catalyst Feed 25
C-(3921-3924)
Catalyst 30%
Hexane 70%
Neraca Massa Total
Catalyst Feed + Hexane = Catalyst out
F1 + F2 = F3
% Catalyst x Massa + F2 x (%N-hexane) = F3 x %Catalyst Out
7.5 x F2 . 0% F3 . 2,6%
7.5 F3 . 2,6%
F3 288.462
Massa Hexane yang ditambahkan
Massa Hexane 17.5
Massa Hexane yang ditambahkan massa Catalyst - massa Hexane
270.962

f. FP2 and Toluene Preparation

Laju Alir Massa FP2 Yang Masuk (Lt/hr) 16
Laju Alir Massa Toluene Yang Masuk (Lt/hr) 200
Desnitas FP2 860.062
Desnitas Toluen 864
Basis = 1 jam operasi

Massa Toluen masuk

Massa FP2 masuk 152.528 G-(1814-1815)

Massa yang masuk pada Pum G-(1814-1815) 2067.861

Neraca Massa Yang Keluar dari Fouling pump G-(1814-1815)
Komponen Input Output
2067.861 2067.861
 92.142
18.015
60.1
198.328

2.Ethylene Compressor(K-2504/05)

H2 H2
CH4 CH4
C-2503 C2H4 C2H4
C2H6 C2H6
H2O H2O

Neraca Massa Pada Ethylene Comp

Komponen
H2
CH4
C2H4
C2H6
H2O
Total

5
 C6H12
5 C6H14
H2O

ut-Output

2.Hydrogen Cooler(E-1905)

H2 H2 96.6983%
04 N2 N2 0.30%
CH4 CH4 3.0014%

Akumulasi=
Akumulasi=

Neraca Massa Pada Hydrogen Cooler(E-1905)

Komponen Input Output
H2 9.130996 9.13099626
N2 0.393631 0.39363135
CH4 2.255372 2.25537239
Total 11.78 11.78
 TIBAL

2. Catalyst Pump G-3941~G-3944

Hexane
H2O

Catalyst Out C-
924) 2.6% catalyst
97.4% Hexane (3
92
1-
39
24
)
G-(3921-3924
ssa Hexane
Massa Yang Terdapat di Slurry Catalyst Tank
Flow Ratio to reaktor/circulating (wt/wt)
Flow In Reaktor

Asumsi Banyaknya Flow Setelah Dikurang Untuk Masuk k

Jadi catalyst yang keluar dari Slurry Catalyst Tank (Kg/hr)
Dan Catalyst yang masih tertampung dalam Slurry Cataly

BM campuran 90.21932
1915.333
hylene Compressor(K-2504/05)

0.0005%
0.0099%
99.8388% K-2504/05
0.1504%
0.0004%

Akumulasi Input-Output
Akumulasi 0

aca Massa Pada Ethylene Compressor(K-2504/05)

Input Output
0.0066316941 0.006632
1.0449240727 1.044924
18427.147045 18427.15
29.753990549 29.75399
0.0474087183 0.047409
18458 18458
 3. Hydrogen to 1st and 2nd reactor

H2 H2 96.6983%H FEED= 4.6839128

E-1905 N2 N2 0.30%
CH4 CH4 3.0014%

Input- Output Flow ratio H FEED 2/H FEED=0.0189

0

gen Cooler(E-1905) Neraca Massa Total Hydrogen to 1st Reacto

H FEED= H FEED 2 + H FEED 3
4.59538682
0.08852595
 To Reaktor
0.85 Kg/hr

G-(3921-3924)

urry Catalyst Tank 288.462

ulating (wt/wt) 1.70%
0.85

etelah Dikurang Untuk Masuk ke Reaktor (Kg/hr) 50

dari Slurry Catalyst Tank (Kg/hr) 50.85
tertampung dalam Slurry Catalyst Tank (Kg/hr) 237.612
 3.Ethylene Cooler

H2 H2 0.0005%
CH4 CH4 0.0099%
C2H4 C2H4 99.8388% E-2
C2H6 C2H6 0.1504%
H2O H2O 0.0004%

Neraca Massa pada Ethylene Cooler

Komponen Input Output
H2 0.0066317 0.0066317
CH4 1.0449241 1.0449241
C2H4 18427.14704497 18427.147044966
C2H6 29.753991 29.753991
H2O 0.0474 0.0474087183
Total 18458 18458
o 1st and 2nd reactor H FEED 2
H2 96.70%
H FEED= 4.6839128 Kgmol N2 0.30%
CH4 3.00%

H FEED 3
EED 2/H FEED=0.0189 H2 96.70%
N2 0.30%
CH4 3.00%
Total Hydrogen to 1st Reactor & 2nd Reactor Komponen input
EED= H FEED 2 + H FEED 3 H FEED
H FEED 3 H2 9.1310
H FEED 2 N2 0.3936
CH4 2.2553723919
Total 11.7800
 4. Ethylen to 1st Reactors & 2nd Rea

H2 H2 0.00%
CH4 CH4 0.01%
E-2506 C2H4 C2H4 99.84%
C2H6 C2H6 0.15%
H2O H2O 0.00%

Akumulasi Input - Output Flow ratio E Feed 2/E Feed

Akumulasi 0

Neraca Massa Total Ethylene to 1st R

E Feed = E Feed 2 + E Fe
311.255407
346.650759

Neraca Massa Ethylene to 1st Reacto

Komponen Input
E FEEED
H2 0.0066317
CH4 1.0449241
C2H4 18427.1470
C2H6 29.753991
H2O 0.0474
Total 18458.0
 output
H FEED 2 H FEED 3
0.172576 8.95842
0.00744 0.386192
0.042627 2.212746
11.7800
st Reactors & 2nd Reactor E FEED 2
H2 0.00%
CH4 0.01%
C2H4 99.84%
E FEED=657.91 Kgmol
C2H6 0.15%
H2O 0.00%

E FEED 3
w ratio E Feed 2/E Feed = 52.69% H2 0.00%
CH4 0.01%
C2H4 99.84%
C2H6 0.15%
H2O 0.00%

Total Ethylene to 1st Reactor & 2nd Reactor

ed = E Feed 2 + E Feed 3
E FEED 3
E FEED 2

Ethylene to 1st Reactor & 2nd Reactor

Output
E FEED 2 E FEED 3
0.003494 0.003137
0.5506 0.494354
9709.254 8717.875
15.67738 14.07661
0.02498 0.022429
18458