Professional Documents
Culture Documents
R. C. BUCHAN,*R. J. SULLIVAN,*
MILTON WILLIAMS,* AND H. H. SPAIN*
ABSTRACT
The dehydration of natural g a s in the field i s I Methods used for predicting trouble are presented.
discussed from the producers' standpoint. The need The three principal dehydration methods in use
which involve the use of line traps, wet-type units,
for reducing the water content of g a s to eliminate
and dry-t.we
- - - units are described: and the advan-
freezing in gas-lift systems and to meet the speci- tages and disadvantages of each method are dis-
fications imposed by g a s purchasers is winced out. cussed.
is a s s u m e d in t h i s d i s c u s s i o n t o be t h e w e l l head.
2. Temperature of ground a t line depth.
3. Rate of g a s flow.
Although t h e temperature of g a s produced from a
well may sometimes be estimated from t h e depth of
the well, t h e bottom-hole temperature, and t h e flow
rate, i t is usually a d v i s a b l e t o determine t h i s tem-
perature directly.
Fig. 1 i n d i c a t e s the minimum ground temperatures
t h a t can b e e x p e c t e d in T e x a s and L o u i s i a n a a t a
s o i l depth of 18 in. T h e d a t a upon which t h i s chart
i s based c o n s i s t e d of s c a t t e r e d measurements of
the a c t u a l ground temperature, supplemented by
atmospheric temperature d a t a , obtained from t h e
United S t a t e s Weather Bureau, combined with d a t a
on the relation of ground temperature t o atmospheric
temperature. T h e minimum ground temperature a t a
s o i l depth Af 36 in. i s ordinarily about 5 F. higher
than the temperatures indicated in Fig. 1.
After wellhead a n d ground temperatures have
been e s t a b l i s h e d , the g a s temperature a t a n y d i s -
t a n c e from t h e well head may be e s t i m a t e d by u s e of
F i g . 2. T h i s i s a chart which g i v e s t h e relation,
for various r a t e s of flow, between t h e g a s tempera-
ture a t a n y point along a line a n d the difference be-
tween g a s and ground temperatures. T h e r e l a t i o n s
-
utilized in Fig. 2 have been deduced from experi-
mental d a t a from various s o u r c e s which embrace
r e s u l t s o n line s i z e s from 2 t o 22 in. Surprisingly, Fig. 2 - Chart for Estimating Temperature Drop
Along Gas L i n e s
the line s i z e is not a n important factor. Although
the effect of line pressure i s disregarded in Fig. 2, ture and ground temperature a t line depth i s as-
pressure d o e s have a minor effect on the tempera- sumed t o b e 5 0 F., and in which t h e flow rate is
ture-distance relation. E s t i m a t e s made by u s e of assumed t o be 3 MMcf per day. From the point on
Fig. 2 a r e reasonably c l o s e for g a s p r e s s u r e s of t h e ordinate corresponding t o the temperature differ-
a b o u t 1,500 psi. At higher p r e s s u r e s t h e line tem- , e n c e , a dotted line is drawn parallel t o t h e guide
peratures e s t i m a t e d from t h e s e r e l a t i o n s may b e line for a r a t e of 3 MMcf per day. T h e dotted line
s l i g h t l y low, a n d a t lower p r e s s u r e s they may be s h o w s the relation between temperature difference
somewhat high. a t any point and d i s t a n c e from well head for the
T h e s o l i d l i n e s of Fig. 2 are intended only t o conditions assumed.
s e r v e a s guide lines. T o use the chart, a line par- Fig. 2 h a s been very useful for predicting tem-
a l l e l t o the guide line for t h e appropriate flow rate peratures in s y s t e m s and for s e l e c t i n g the s i t e of a
i s drawn through t h e point on the ordinate corre- dehydrator or h e a t e r s where a wide choice of loca-
sponding t o t h e e x p e c t e d or a c t u a l difference in tions i s possible.
temperature between wellhead g a s a n d ground a t F i g . 3 p r e s e n t s d a t a published by D. L. K a t z ' of
line level. If it i s n e c e s s a r y t o interpolate between t h e University of Michigan for the prediction of
t h e various flow r a t e s for which guide l i n e s a r e temperatures and p r e s s u r e s under which g a s e s of
shown, a linear interpolation may b e made between various d e n s i t i e s form hydrates. In t h i s graph the
'the i n t e r c e p t s on a n y grid l i n e s parallel t o the a r e a above- any particular curve r e p r e s e n t s t h e tem-
a b s c i s s a . T h e r e l a t i o n s of Fig. 2 a r e for s t a b i l i z e d ' perature-pressure region in which hydrates c a n
conditions of flow. It should b e borne in mind that e x i s t , provided there is sufficient water present,
a s much as s e v e r a l d a y s may b e required for s t a - and the a r e a below the curve r e p r e s e n t s the region
bilization of temperature. in which hydrates cannot exist. T h e d a t a u s e d in
T h e use of Fig. 2 is illustrated by a n example
in which the difference between wellhead tempera- 'References are at the end of the paper.
10 BUCHAN, SULLIVAN, WILLIAMS, AND SPAIN
choked or throttled.
; 600
Z
G a s may contain water as water vapor, or as 400
water vapor p l u s liquid water. T h e maximum amount
of water vapor which a g a s can contain i s c a l l e d
i t s water-vapor c a p a c i t y and d e p e n d s on t h e pres-
200 1 Flnd ontt801 pressure on ordlnote,
s u r e and temperature of the gas. T h e higher t h e f l n ~ lpre5.lure on absclo.lo
2 T e m p e r ~ t u r e corrsrpondmnq to tnot
temperature and t h e lower the pressure, t h e greater polnt 8s the rnlnlmum #ntllal
t e m p e r ~ l u r e l o prevent freerrnq
i s the water-vapor capacity. T h e composition of t h e
g a s may a l s o affect the water-vapor capacity, but 100
100 200 400 600 BOO I 0 0 0 2000
t h i s effect i s usually s m a l l and may b e neglected FINAL PRESSURE PSlA
in most c a s e s .
T h e dependence of water-vapor c a p a c i t y on pres-
s u r e a n d temperature is shown in Fig. 5. In t h i s
Fig. 4 -
Katz' C u r v e s for P e r m i s s i b l e Expansion
of a 0.6 Gravity Natural G a s without Hydrate
figure, t h e water-vapor c a p a c i t y is plotted a g a i n s t Formation
DEHYDRATION O F NATURAL GAS 11 ,
Water-vapor
. .-
LBS PER SO IN
Table 2
Dehydration P lants
Vet-type Dehydrators:
Diethylene glycol 900 100 830 50.0 94 24 6.0 $116,827
Diethylene glycol 1,200 12 960 11.O 93 34 8.0 26,550
D i e t h ~ l e n eglycol 1,500 20 805 22 .O 80 12 3.6 55,021
D i e t h ~ l e n eg l y c o l 1,000 50* 740 46.0 77 34 9.5 %,399
Dry-type Dehydrators:
F l o r i te 1,500 13 3.3 33,764
Florite 840 -5 1.9 39,642
Florite 1,500 16 3.4 47,264
Florite 500 8 6.4 48,002
Florite 800 15 4.4 49,914
A c t i v a t e d alumina 1,500 Not yet
determined
.... 38,387
Activated alumina 800 - 10 1.4 70,000
S i l i c a gel b e a d s 1,000 -10 1.3 30,100
T h i s plant i s d e s i g n e d in such a way that i t s c a p a c i t y c a n be i n c r e a s e d to 100 MMcf by an e s t i m a t e d additional i n v e s t m e n t of $30,000.
-. ..:
2 .L
, ,.
..vrn/
:: rc
I., " I -I CL ,rr>.
,ma-
2%t i m e s t h a t obtained a t 750 psi, a s s u m i n g a l l other one i s in operation, t h e other i s being regenerated.
v a r i a b l e s a r e kept constant. Increasing t h e p r e s s u r e Regeneration i s accomplished by beating a s m a l l
above the optimum d o e s not appreciably reduce the volume of g a s taken from the main stream, p a s s i n g
amount of water in the dehydrated gas. L i t t l e work i t through the tower, then through a heat e x c h a n g e r
h a s been done t o indicate the maximum p r e s s u r e and separator t o remove liquid water. T h e g a s u s e d
which i s f e a s i b l e in wet-type dehydrators, but it i s for regeneration i s then recombined a h e a d of t h e
probably above 1,500 psi. T h e rate a t which t h e absorption tower in operation a s the dehydrator.
absorbent i s circulated i s another variable that af- F l o r i t e , a c t i v a t e d alumina, and s i l i c a g e l have
f e c t s r e s u l t s , and the circulating rate usually u s e d b e e n u s e d a s drying agents. Activated alumina h a s
v a r i e s from 1 0 0 to 200 g a l per n ~ i l l i o ncubic feet. given s l i g h t l y better r e s u l t s with r e s p e c t t o capac-
T h e average dew point lowering obtainable in pre- ity, but F l o r i t e apparently w i t h s t a n d s attrition
s e n t ~ l a n t si s 4 0 t o 5 0 F. However, it h a s b e e n better. Neither i s s a t i s f a c t o r y for u s e where g a s
noted in individual c a s e s t h a t a better r e s u l t i s temperatures a r e above 1 0 0 F. In s u c h c a s e s s i l i c a
obtainable. T h e circulating rate and the heating g e l in t h e form of b e a d s i s recommended, and i t
f a c i l i t i e s used should be s u c h that the glycol in a p p e a r s p o s s i b l e t o allow t h i s mineral t o a b s o r b
the absorbent c o n t a i n s a s little water a s p o s s i b l e , about 7.5 percent water before regeneration. T h e
i.e., it should contain not more than about 2 per- time c y c l e of a b s o r b e r s in operation c a n be varied
cent water, e v e n though many plants operate s a t i s - provided i t s t a y s within the c a p a c i t y of e a c h tower.
factorily with a s much as 5 percent water. Dew p o i n t s a s low a s -10 F. a r e frequently ob-
Indirect h e a t e r s have been used in t h e s e p l a n t s , tained; and in t h i s r e s p e c t dry-bed type dehydrators
i.e., s t e a m or Dowtherm baths which provide tem- a r e outstanding. T a b l e 2 s h o w s some of the dry-
peratures in a range from 3 0 0 t o 4 5 0 F. Direct
heaters, some of which have the s t i l l mounted on
top, appear s a t i s f a c t o r y and a r e being used more
widely.
T h e installed c o s t of wet-type plants h a s been
fairly high, particularly in the larger plants. Re-
c e n t d e v e l o p n ~ e n t s indicate t h a t triethylene glycol
i s a much better absorbent than diethylene glycol
for this use.3 It i s probable t h a t by using triethyl-
e n e glycol p r e s e n t plants using diethylene glycol
c a n be improved considerably, and new installa-
t i o n s made in t h e future will be somewhat l e s s ex- Fig. 10 - Solid-dessicant Type Dehydration Unit
pensive a s a r e s u l t of the u s e of a better absorbent. bed u n i t s in u s e , the operating conditions, and t h e
Wet-type dehydrators used in the p a s t have done r e s u l t s obtained.
an a c c e p t a b l e job using d i e t h ~ l e n eglycol; and with Fig. 11 i s a photograph of a dry-bed unit oper-
improvement it i s p o s s i b l e that they could s a t i s f y a t i n g a t a compressor plant t o handle g a s which
a majority of the requirements where the u s e of originated a s low-pressure l e a s e g a s gathered and
traps d o e s not give sufficiently low dew points, or compressed to 9 5 0 psi. T h e temperature of t h e g a s
where extremely low dew points a r e unnecessary. leaving the compressors i s 220 F.; and a radiator-
B e s i d e s the u s e of better absorbents, current de- fan type g a s cooler i s u s e d t o reduce t h i s t o a
velopment work on absorber design and on s t i l l r e a s o n a b l e temperature. T h i s r e s u l t s in a g a s tem-
' perature varying from about 9 0 t o 110 F. It w a s
design should r e s u l t in better operation and higher
c a p a c i t i e s a t lower installation c o s t s . found that, when the g a s temperature w a s 1 1 0 F.,
6.5 LlLlcf per d a y could not be properly dehydrated
Dry-bed Type Dehydrator in the unit which had a rated c a p a c i t y of 1 0 RlMcf
In the p a s t s e v e r a l y e a r s dry-bed dehydrators per d a y a t 7 0 F. T h e a c t i v a t e d alumina bed w a s
have been a d a p t e d t o the oil-field problem. T h e replaced with s i l i c a gel beads. When treating 6.5
method used, shown diagrammatically in Fig. 10, hlhlcf per d a y a t 95 t o 1 0 0 F., a -10 F. dew point
c o n s i s t s of p a s s i n g g a s to be dehydrated through a g a s i s obtained by the u s e of the s i l i c a g e l bed.
bed of mineral having the capacity t o a b s o r b the T h e installed c o s t of dry-bed u n i t s i s approxi-
water v a p o r - p r e s e n t until the mineral h a s absorbed mately the s a m e or s l i g h t l y higher than the wet-
a n amount of water e q u a l to about 5 percent of i t s type dehydrator using diethylene glycol a s t h e ab-
weight. T w o absorption towers are used; and while sorbent. Dry-bed units lend t h e m s e l v e s readily t o
DMYDRATION OF NATURAL GAS 15
CONCLUSION
E a c h of the three general methods of dehydration
Fig. 11 - Dry-bed Type Gas Dehydrator d i s c u s s e d h a s a d v a n t a g e s and disadvantages, a n d
e a c h i s applicable t o certain problems. T h e line
before they have a harmful effect on the bed. Better
trap h a s the advantage of simplicity and low in-
dehydration and e a s i e r regeneration should be pos-
s t a l l a t i o n and operating c o s t s , but i t h a s a limited
s i b l e , a s w e l l a s reduction of pressure drops through
application. T h e wet-type dehydrator will usually
t h e mineral. T h e u s e of horizontal absorbers h a s
be cheaper to i n s t a l l and operate than the dry-rype
not been a d e q u a t e l y investigated. Some additional
unit; however, t h e wet-type unit may not reduce t h e
study is d e s i r a b l e t o improve the heating and cool-
water content sufficiently t o meet a l l s a l e s con-
ing procedures during regeneration. F a s t e r heating,
for example, may be t h e a n s w e r t o t h e problem of tracts. T h e dry-type dehydrator i s h i g h e s t in c o s t ,
exposing the mineral to liquid water during the re- but can obtain the lowest water content. T h e r e i s a
need for considerable further s t u d y t o provide better
generation cycle.
methods of dehydrating g a s , a s well a s to develop
Combination Units better d e s i g n s of equipment to utilize the present
In some i n s t a n c e s combination u n i t s may have methods. E a c h dehydration -problem should be
advantages. F o r example, if a dry-bed unit is in- s t u d i e d carefully before s e l e c t i n g a method and
s t a l l e d a n d t h e volume of g a s t o be dehydrated ex- equipment. T h e major factors which must be taken
c e e d s t h e capacity of the installation, some of the into account a r e volume, pressure, temperature, and
g a s can by-pass the dehydration plant, if liquid the dew point required in view of the local tempera-
water i s removed, and be recombined with dehy- ture conditions or requirements imposed by g a s
drated g a s provided the dew point of t h e dehydrated purchasers.
16 BUCHAN, SULLIVAN, WILLIAMS, AND SPAIN