Professional Documents
Culture Documents
c Dr. M. Zahurul Haq (BUET) Thermodynamics Relations ME 6101 (2011) 1 / 22 c Dr. M. Zahurul Haq (BUET) Thermodynamics Relations ME 6101 (2011) 2 / 22
c Dr. M. Zahurul Haq (BUET) Thermodynamics Relations ME 6101 (2011) 3 / 22
c Dr. M. Zahurul Haq (BUET) Thermodynamics Relations ME 6101 (2011) 4 / 22
CP & Thermodynamics Relationships Tds Relationships
s s
s = s(v , T ) ds = T v
dT + v T
dv
s s P
dh = Tds + vdP = h
s P = T
Cv = T T v
& v T = + T v , Maxwells Relation (C)
h h s s
CP = T = = T P
P s P T P T P Tds = Cv dT + T dv 1st Tds
CP
s
s 2
v T v
P T = P T T P = T T P T = T T 2 P
s s
using Maxwells relation: P s
= T v
s = s(P, T ) ds = T P
dT + P T
dP
T P s
s
v
CP = T T P
& P T = T P , Maxwells Relation (D)
2 v
v R v
Ideal gas: = T P = P & T 2
= 0 7 CP 6= f (P) Tds = CP dT T dP 2nd Tds
P
v
T P
van der Walls gas: = T P = P a R1 2b
v2
( v) s = s(P, v ) ds = P s
dP + v s
dv
v P
2 R 2 2a3 6ab R P2 2 s
s
v
= v v4
7 CP = f (P) = T v
dP Cv = T T v & CP = T T P
T 2 P 3 P1 T 2 P
a 2b
P 2 (1 v )
v T T
Tds = Cv dP + CP dv 3rd Tds
P v v P
c Dr. M. Zahurul Haq (BUET) Thermodynamics Relations ME 6101 (2011) 5 / 22 c Dr. M. Zahurul Haq (BUET) Thermodynamics Relations ME 6101 (2011) 6 / 22
u u u
u = u (v , T ) du = T v dT + v T dv = Cv dT + v T dv h
h
h
h = h(P, T ) dh = T P dT + P T dP = Cp dT + P T dP
P
dv Pdv (- 1st Tds Eq.)
du = Tds Pdv = Cv dT + T v
2nd Tds
T v dh = Tds + dP = CP dT T dP + vdP (- Eqn.)
T P
u P
=T P h v
v T T v
=v T
P T T P
u
RT
Ideal gas: v T = v P = 0 h
= v TR
u u
P P u u Ideal gas: P = 0 h 6= f (P)
P
T
v T = 0 = P T v T = v P T P T = 0 h h v
Pv h h
u u P T = 0 = v T P T = v T v T = 0
v T = 0 u 6= f (v ) : P T = 0 u 6= f (P) h h
P T = 0 h 6= f (P) : v T = 0 h 6= f (v )
du = Cv dT = f (T )
dh = CP dT = f (T )
van der Waals gas:
u
RT a a van der Waals gas: = h = f (T , P)
v T = v b P = v2
du = Cv dT + v2
dv = f (T , v )
c Dr. M. Zahurul Haq (BUET) Thermodynamics Relations ME 6101 (2011) 7 / 22
c Dr. M. Zahurul Haq (BUET) Thermodynamics Relations ME 6101 (2011) 8 / 22
CP Cv
s s
s = s(v , T ) ds = T v
dT + v dv
h T i
s s s v s CP s Cv
= + - = , =
for isobar: T P T v v T T P T P
vT v T T
s v P
dhP = CP dTP CP CV = T v T T P = T T v T P
z
y x
for isotherm: f (x , y, x ) = 0 x y z x y z
= 1
v
dhT = v T dPT P
T
v
P
v
P
v T P v T P = 1 v T T P = T v
T P
P v 2
v
= T P
CP Cv = T T v T P v T T P
v
T011 1 For liquids & solids, T P
0 CP Cv C
h2 h1 = (h2 h2 ) + (h2 h1 ) + (h1 h1 ) v
2 P
T P is +ve & v T is -ve for all known substances, CP Cv
2
RP v
RT
= P02 v T T P T2
dP + T12 CPo dTP
RP v
3 as T 0, Cp Cv , at T = 0, CP = Cv
P01 v T T P T
dP
1
c Dr. M. Zahurul Haq (BUET) Thermodynamics Relations ME 6101 (2011) 9 / 22 c Dr. M. Zahurul Haq (BUET) Thermodynamics Relations ME 6101 (2011) 10 / 22
1
dP = dT dv
kT kT v
c Dr. M. Zahurul Haq (BUET) Thermodynamics Relations ME 6101 (2011) 11 / 22
c Dr. M. Zahurul Haq (BUET) Thermodynamics Relations ME 6101 (2011) 12 / 22
Applications of Tds Relationships Example: 15 cm3 Hg @0o C & 1 bar 1000 bar
c Dr. M. Zahurul Haq (BUET) Thermodynamics Relations ME 6101 (2011) 13 / 22 c Dr. M. Zahurul Haq (BUET) Thermodynamics Relations ME 6101 (2011) 14 / 22
e792
e772
e773 e769
A cooling effect cannot be achieved by throttling unless the fluid is
T
ve : temperature increase
below its maximum inversion temperature. For hydrogen its value
JT = 0 : temperature same
P h is -68o C and hydrogen must be cooled below this temperature if
+ve : temperature drop
further cooling is to be achieved.
c Dr. M. Zahurul Haq (BUET) Thermodynamics Relations ME 6101 (2011) 19 / 22
c Dr. M. Zahurul Haq (BUET) Thermodynamics Relations ME 6101 (2011) 20 / 22
Liquefaction by Cooling Liquefaction by Cooling
e793
" #
RT a 1 RT
P= v b v2
= JT = CP
v e797
P + a2 (v b) 2a3
v v
e796
Maximum inversion temperature = 6.75Tc Two performance parameters:
Minimum inversion temperature = 0.75Tc Yield, z : mass of liquid produced per unit mass of gas compressed.
I If air is compressed to a pressure of 200 bar and a temperature of Sp. work required, wz : work per unit mas of liquid produced.
52o C, after the throttling to 1 bar it will be cooled to 23o C. In case of y h7 h2 Win
z = = wz =
helium, throttling from the came condition will result in 64o C. m h7 h5 z
c Dr. M. Zahurul Haq (BUET) Thermodynamics Relations ME 6101 (2011) 21 / 22
c Dr. M. Zahurul Haq (BUET) Thermodynamics Relations ME 6101 (2011) 22 / 22