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Strengthening mechanisms
Subjects of interest
• Introduction/Objectives
• Grain boundary strengthening
• Yield-point phenomenon
• Strain ageing
• Solid-solution strengthening
• Strengthening from second phase particles
• Martensitic strengthening
• Strain hardening or cold working
• Bauschinger effect
• Preferred orientation (texture)
Sometimes
ductility or Grain boundary Strengthening Fibre
strengthening mechanisms strengthening
toughness are
sacrificed.
Fine-particle
Strain ageing strengthening
Solid-solution
strengthening
Suranaree University of Technology May-Aug 2007
Grain boundary strengthening
Grain boundaries
Grain boundary separates two Grain boundary structure contains
grains having different grain boundary dislocations,
crystallographic orientations. which are not mobile and produce
extensive slip.
Angle of misalignment
High energy grain boundary
serves as preferential sites
for solid state reactions; High-angle
grain
boundary
1) Diffusion
Low-angle
2) Phase transformation grain
boundary
3) Precipitation
Angle of misalignment
250 x 1000 x
Temperature
Tendency for grain boundary
Strain rate sliding (as in creep).
Equicohesive temperature
There are two important roles of the grain boundary which acts as
a barrier to dislocation motion;
contributes to a discontinuity
of slip planes from one grain The motion of a dislocation as it encounters
a grain boundary.
to another.
σ o = σ i + kD −1 2 …Eq. 1
L Where M is a linear
D=
NLM magnification of the Note: The grain size obtained by this
photomicrograph. method will be somewhat smaller
than the actual grain size. In some
…Eq. 4 case, a factor 2/3 is used.
Suranaree University of Technology Tapany Udomphol May-Aug 2007
ASTM standard comparison chart
G = −2.9542 + 1.4427 ln na
…Eq. 5
1.4427
Grain diameter D ≈ 1 / na or D 2 ≈ 1 / n a
D 2 ≈ 20 × 10 −10 m 2 , D ≈ 44.7 × 10 −6 m
1
= 149 m −1 2
D
σ o = σ i + kD −1 2 = 150 + (0.70)(149) = 254.3 MPa
Portevin-LeChaterier effect.
Suranaree University of Technology Tapany Udomphol May-Aug 2007
Blue brittleness
Alloys
• The addition of solute atoms raises the C2>C1 %solute
yield stress and the stress-stain curve
as a whole.
C1% solute
Pure polycrystal
• Therefore from Eq.1 σ
σ o = σ i + kD −1 2
Impurity atoms
Tensile strength
Yield stress
Ductility
1) Elastic interaction
2) Modulus interaction
3) Stacking-fault interaction
4) Electrical interaction
5) Short-range order interaction
6) Long-range order interaction
Modulus interaction
• The presence of the solute atom locally alter the modulus of
the crystal. Solute atom with small shear modulus will reduce
the energy of the strain field.
Stacking-fault interaction
Solute atoms Stacking fault Separation
within the energy between partial
stacking fault dislocations
• Second
Dispersed second-phase phase
particles in the matrix.
particles in
matrix.
0.0 f2 0.0 f2
σ1
0.5 f2 0.5 f2
σ 1.0 f2 σ 1.0 f2
σ2 At equal stress
At equal strain ε2
ε1
ε ε
(a) At equal strain (b) At equal stress
Shear stress
GP zone
than pure aluminium. Over aged
Orawan’s
mechanism
of
dispersion
hardening.
Wavy slips
Suranaree University of Technology Tapany Udomphol May-Aug 2007
Fibre strengthening
P = σ f A f + σ m Am …Eq. 11 Ac = A f + Am
where
V f + Vm = 1
Where Af and Am are the cross- Likewise
sectional areas of fibre and matrix.
E c = E f V f + E mVm …Eq. 13
E c = E f V f − (1 − V f ) E m
V f = 0.10 , E c = 380(0.10) + 0.9(60) = 92 GPa
V f = 0.60 , E c = 380(0.60) + 0.4(60) = 252 GPa
3
Composite
ge
S ta
but fibres deform elastically.
e2
ag
St
• Stage 3 : Both matrix and fibres
I
e
Matrix
ag
St
Strain
undergo plastic deformation.
σ mu − σ m'
V f ( crit ) =
Composite strength
σ fu − σ m' …Eq. 14
σf
V f (crit)
σu
• The minimum volume fraction
of fibre which must be exceeded to σ ’m V f (min)
Temperature
be done without transformation to
pearlite or bainite.
• Highest strengths are achieved by the
greatest possible deformation at the
lowest temperature at transformation
does not occur. TTT diagram showing steps
in ausforming process.
1) Recovery
2) Recrystallisation
3) Grain growth
Normal to processing
direction
Homogeneously distributed.
Extruded bar 50 µm
Extrusion direction
• Mechanical fibering increases
mechanical properties along the
working (fibre) direction, with the Alignment of carbides along the
extrusion direction in β-Ti alloy.
transverse direction having inferior
properties. anisotropic properties.