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Q.1 [C]
H 2 PO 4 HPO 42
H 3 PO 4 Na 3 PO 4
10 10 0 0
0 0 10 10
HPO 24
pH Pka 2 log 8 log1 8
H 2 PO 4
Q.2 [A]
Final pH = 4; H 10 4
H by drop 10 4 10 7 10 4
Moles of H in 1L 10 4
pH = 4 log 2 = 3.7
Q.3 [D]
HPO 24
Using 7.4 8 log
H2 PO4
H 3 PO 4 NaOH
NaH 2 PO 4 H 2 O
5m mole x5
0 0 5m moles
NaH 2 PO 4 NaOH
Na 2 HPO 4 H 2 O
5 x
5 x x
x
Solving, 7.4 8 log
5 x
x 1
5 x 4
x=1
V = 60 ml
Q.4 [A]
K 1010
M sp 10 9
X 0.1
2
then K sp M 2 Y M Y 2
2
10 9 0.01 10 20
4s3 1020
1
10 20 3
s
4
Q.5 [B]
Sol. Isoelectronic point implies net charge on the species must be zero so considering it as triprotic
Pka 2 Pka 3
acid 2 nd ionisation of H+ must be complete so it will be amphiprotic & pH
2
8.96 10.53
2
= 9.74
Comprehensions
Q.13 [A]
Sol. The stronger acid will be more deprotonated than weaker acid at same pH
Q.14 [C, D]
Sol. for same acid lines must intersect at 0.5 as ordinato, So A & C are pairs & B & D
Q.15 [B]
105
100
10 7
Q.16 [C]
K sp 107
Sol. First Br starts precipitating in the form of AgBr(s) when Ag 105 M
Br 102
Q.17 [D]
K sp 10 5
Ag
2
10 3
solution Cl 10
107
Ag Br 10 2 3 102 104
ppt ppt 10
Q.1
25 106 V 5 10 3 1
5 103 103
V 200L
25 10 6 5
125 10 9 1.25 10 7 10 6
So OH in significant
water
1014
OH H H 7
8 108 M
water water net 1.25 10
12.5 10 8
8 108 V 5 103 1
4.5 108 V 5 103
5 10 3
V
4.5 108
106
L
9
Q.2
1
pH 2 pKa log C 2.7
2
Ka
0.1 10 0.1 2 10
3
5
; 1 1
0.11
0.1 10
2 3
2 10 5
2 102 2 104 0
pH 3 2.7
pH pH 2
So 1 2
pH 3
Q.3
HA H A
Sol.
C 1 C C
C 2 C
Ka H
1 1 1
pKa pH log
1
log pH pKa
1
10 pH pKa
1
10 pH pKa 1
1 10 pKa pH
pH pKa
1 10
Q.4
Sol.
2
Cf f Ci i
2
Ci Ka 0.1 2 105
2 106
Cf 12 Ci i2
Also, 2 105
1 f 1 i
Cf f f 2 105
1 f
2 106 f 2 105
t 10
10 ; f
1 f 11
11
Cf 2 106 2.2 106
10
Conserving WA Cf Vf Ci Vi
106
Vf
22
106
Vwater 1 L 45453L
22
Q.5
Zn OH 2(s) Zn 2 2OH
Sol.
a s1 s 2 s1 x
2
K sp Zn 2 OH
S1x 2 .(1)
2
Zn 2 4OH Zn OH 4
2
Zn OH 4
Kf 4
Zn 2 OH
2
Zn OH 2 s 2OH Zn OH 4
a s1 s 3 x s2
s2
K sp K f .(2)
x2
1 2
2
K sp K f s1 s 2 s 2 s1 s 2
2
s 2 1.2 10 17 1016 1.44 10 18
s 1.2 10 9
K sp 1.2 1017
OH x 9
108 104
s1 1.2 10
POH = H
pH = 10
Q.6
Ca OH 2 s Ca 2 2OH
s 2s
4.42 105
S 3
4
= 0.022 M
1
Moles dissolved 0.022 0.011
2
Ca OH 2 Ca 2 2OH
s1 s
s1 2s1 0.2
2
s1 2s1 0.2 4.42 10 5
2
s1 s1 0.1 1.105 105
Neglecting s1
1.105 10 5
s1 1.1103
0.01
Q.7
1
moles in 103 L 1.78 105 M
56
2
Fe 3 SCN Fe SCN
1.78 105 x 0
1.78 10 5
6 10 6 x 6 10 6
6 10
6
6 10 6 1 103
1.78 10 5
6 10 6 x 6 10
6
k dissociation 7.142
6 10 6 103
11.8 10 6 x 6 10 6 7.142
6 7.142
x 6 10 6 3.61 103 = 0.0036 M
11.8 103
Q.8
Sol.