PERCHLOROETHYLENE

Process: by Ethylene dichloride oxychlorination

List of chemicals:

Ethylene dichloride

Chlorine or hydrogen chlorine

Oxygen

Recycled by-products

Copper chloride (catalyst)

Raw Materials Availability

Trade of Ethylene dichloride in the Philippines

Year Import (kg) Trade (USD) Export Trade (USD)

2002 103 1791 - -
2003 37 1,208 - -
2005 7,364 9,844 - -
2008 10 382 - -
2011 8,022 5,671 - -
2012 137 1,028 - -
2013 21,595 7,520 - -

Trade of Hydrogen Chloride in the Philippines

Year Import (kg) Trade (USD) Export Trade (USD)

2009 6,665,161 970,753 38,978 12,993
2010 4,799,309 1,198,347 1,868 21,787
2011 1,804,109 979,468 493,600 89,232
2012 2,260,315 902,228 440,000 111,160
2013 3,038,490 1,002,102 - -
2014 1,573,707 669,375 364,904 91,724
2015 1,255,795 414,168 44,137 16,034
List of Target Supplier of Raw Materials in the Philippines

Raw Materials Company Location

Ethylene Marubeni Philippines Makati City, Philippines
Corporation
JG Summit Petrochemical Batangas, Philippines
Corporation
Chlorine The Alpha Enterprise Cabuyao, Laguna
 Category Processes
EDC Oxychlorination Hydrocarbon EDC Chlorination
Chlorinolysis

Existing process in the YES YES YES

market
Raw materials used Ethylene(C2H4) Mixed Hydrocarbon Ethylene (C2H4)
Chlorine(Cl2) (CH4, C2H6, C3H8, Chlorine (Cl2)
Oxygen (O2) C3H6)
Hydrogen Chloride Chlorine (Cl2)
(HCl)
Availability of raw ALL ALL ALL
materials in the
Philippine market
Price of Raw Materials Ethylene 1.119 Chlorine (0.4712
(USD/MT) Propane 0.926 USD/kg)
Propylene 0.7566 Ethylene Dichloride
Chlorine 4.2 (0.3482 USD/kg)
By-product Trichloroethylene Carbon Tetrachloride Trichloroethylene
Hydrogen Chloride Hydrogen Chloride
Energy consumption of High High
the process
Yield of product High High
Environmentally- Yes No Yes w/ safety plan
friendly
Aspen availability Yes Yes Some

EDC CHLORINATION

CRITERIA RATING Weight

Existing process in the market 2 5% Yes

Availability of raw materials in 3 20% Chlorine, Ethylene

the Ph Dichloride, Hydrogen
Chloride, Chlorocarbon
only

Energy Consumption of the 3 15% high

process

Environmental impact 4 20% Yes w/ safety plan

Equipment maintenance 2 10% low

Yield of product 3 15% high

Price of raw materials 3 10% Chlorine (0.4712

USD/kg), Ethylene
Dichloride (0.3482
USD/kg), Hydrogen
Chloride (0.3467
USD/kg), Chlorocarbon
(3.9038 USD/kg)

Aspen Avalilability 3 5% Some?

HYDROCARBON CHLORINOLYSIS

CRITERIA RATING Weight

Existing process in the market 3 5% Yes

Availability of raw materials in 5 20% Ethylene, Propane,

the Ph Propylene, Chlorine

Energy Consumption of the 3 15% high

process

Environmental impact 4 20% Yes

Equipment maintenance 3 10% low

Yield of product 3 15% high

Price of raw materials 3 10% Ethylene 1.119

(USD/kg) Propane 0.926
Propylene 0.7566
Chlorine 4.2

Aspen Avalilability 3 5% YES

 Alternative Criteria
Existing Availability Price of Energy Yield of Environmentally- ASPEN
process in of raw raw consumption product friendly availability
the market materials materials of the
in the PH (USD/kg) process
market
EDC 3 5 3 4 4 5 5
Oxychlorination
Hydrocarbon 3 5 3 3 3 4 3
Chlorinolysis
EDC 2 3 3 3 3 4 3
Chlorination
PROCESSES: