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The elementary irreversible gas-phase reaction PBR with jacketing heat exchanger
A B + C is carried out adiabatically in a PBR
packed with a catalyst. Pure A enters the reactor
at a volumetric flow rate of 20 drn3/s at a
pressure of 10 atm and a temperature of 450 K.
The heat is removed by a heat exchanger
jacketing the reactor. The flow rate of coolant
through the jacket is sufficiently high that the
ambient exchanger temperature is constant at Ta
= 50 C.
Additional information:
HAO (273 K) = -70 kJ/mol
HBO (273 K) = -50 kJ/mol
HCO (273 K) = -40 kJ/mol
CPA = 40J/mol-K
CPB = 25 J/mol-K
CPC = 15 J/mol-K Additional information:
E 1 1
k = 0.133 exp[R(450 T) HAO (273 K) = -70 kJ/mol
E = 31.4 kJ/mol HBO (273 K) = -50 kJ/mol
Ua J HCO (273 K) = -40 kJ/mol
= 0.08 skgcatK CPA = 40J/mol-K
a
CPB = 25 J/mol-K
CPC = 15 J/mol-K
E 1 1
REQUIRED k = 0.133 exp[R(450 T)
a) Plot the temperature and conversion E = 31.4 kJ/mol
profiles for this PBR Ua J
= 0.08 skgcatK
a
b) How would the profiles change if Ua/
were increased by a factor of 3000? Conditions:
c) Plot the pressure profile if there is a Adiabatic
pressure drop with = 0.019 1? non-isothermal
gas phase
d) Plot the temperature and conversion
irreversible reaction A B + C
profile for co-current flow with mc = 0.2
kg/s, CpC = 5,000 J/kg K and an entering
coolant temperature of 50 C.
e) Plot the temperature and conversion
profile for co-current flow with mc = 0.2 SOLUTION
kg/s, CpC = 5,000 J/kg K and an entering
coolant temperature of 50 C.
(a) Plot the temperature and conversion profiles
f) Find X and T for a fluidized CSTR
for this PBR
with 80 kg of catalys
Energy balance:
Mole balance
For a PBR:
dX rA
=
dW FA0
Rate law:
A B + C
For a first order reaction:
= kCA
Where k is:
1 1
= 1 [ ( )]
1
Stoichiometry:
For a gas phase reaction:
0 (1) 0
= (1+)
Combine:
from mole balance:
dX rA
=
dW FA0
1 1 0 (1) 0
= [ ( )]
1 (1+) Differential equation for energy balance balance
( )+( )(() )
= ( + )
Combining mole balance, rate law and
stoichiometry equation:
dX 1 1 1 0 (1) 0
= (1 [ ( )]
dW VA0 1 (1+)
Parameter evaluation and Algorithm: Equations used:
1) Ordinary Differential Equation
calculate the parameters
= =
= 40 + 50(1) (70)
= 20 /
=
= [15(1) + 25(1)] 40(1) = 0
Solution:
Algorithm
Same equations from a) are used in this part. The
only difference is that Ua/ were increased by a
factor of 3000.
Equations used:
1) Ordinary Differential Equation
Answers:
=
= ( ) 0 (1 + )
2 0
0
which is the formula given for PBR.
Equations used:
1) Ordinary Differential Equations
=
= ( ) 0 (1 + )
2 0
0
0.019 1013250
= ( ) (1 + )
2 450 /1013250
Program results:
Polymath code:
Solution:
Equations used:
( ))
=
The conversion increases as the weight of the
catalyst inside the packed bed reactor increases.
Solution:
Algorithm
The Polymath program used a numerical
Answers: integration algorithm called Runge-Kutta-
Fehlberg (RKF45) which solves numerical
problems of ordinary differential equations.
Equations used:
Polymath code:
Answers:
Polymath report: