CHEMISTRY

Phe.wt as"''"u~,; "' b''"'~"~ w l<>tm J ""h

dm1ers The \'an! jJ-<,1), 1:1clo< 1s o~.t '
Whnl " th~ d~'g"'" uf "'"""'"'"'" (f
"
" 2 :md J
Soild c"' !x>n rea~1< \\llh
pherol'' presence of'
a ll .Ji, o\!de> CO
h () 5~ of degte<E
c 11 Jx S\stem
d on all:tltlcdl

Whch on~ ot' the 101\onmg ooluloom

produce;; ma.'unum dcauon m 001lmg
p"ull '' c 1
a 11 I M glucose
II~ M >UCro<;e "'
b
c IJIMBaCI2 ' '"'"'' >; proce<;cs AS

d <I I M MgSO., -> NO-Igl

I 2 g of m:eloc :t<HI "hen dossoh ed on IlK I g
of t..rl;en~ rmsed the bmlmg pmm of ,( > "ilLNO,(aql
be1vcne \J> lt2<>- \\'hal " th~ aluc lf I aunt -> Q, (g_ Ill nUn!
""'-' HolY< lhcl<>< of oceuc """I m ClsJH,Oigl >CC)(gtHIgl
betvenc (MN:>J elc,auon wnstnn1
\>enLene" 2."W't Sd-'CI the cunocl "'"""' usrng the cOO.,;
g<len belo\\
'h '
;
a I :md}
b 2aodl
' ,. 2 and 4
"Whm \15
d lan~.t

"'"
the number of degr
Which one of the follcmmg os !he wrre<t
< H_.(l =feO,., <
statc~lli'l11'' A chenucal reacuon 11111 he
spontaneous d' I " accompamed hi a
a 3_ 2
b 4.J '* deere= of
a enthaljl\ oftheS<stom

' ' b entmr; of the >'5tem

c mtemal ""~'ll' of the"' <tem
' 'siak'Tltents
cnmponem " sten~ the
d l'meenen,." <11'thes_15!em
number of pllasc>s that ean " Fm llll fldtabauc process_ \\hal " the
relatott bet\\ecn tempcrntum and
";;;'" eqmltbnum" thr"' pr~>ure''
'"tem can hale rlegall 1c d~g""'s of
freed<>m
J nw number of phases 111 a" stem docs
not deptmd on the an~>urtl> of the
1""""' wbstarrCL"J presem m
eqwilbrJum
Whch <11" the slal~nwnls !?"en abo1 e s/are

' :~ r
C(>ffe<\ ''
T
a I MJ 3
b I nnl)
www.examrace.com
 ., IO't1'H!';:V ,,
"'""
>..A.' " tn 'L.) 'tll"tV
""
'
'"'' ~ .... "
U<>f ~l"I""J

""'"'
t' \Jmn.> "' ., ,
e
''
;, ""! '"'''~ll""''' f "><: ~"! '"~ puru,J""'' OUft!IUitifl( 1
""! 'P"I' \11 '
~1"'''1"'"" j!l "1"~'"'1 w,.),i,ilo.JJ unw11.i>.,;
J..>J>U~JL
'"'''-''''"II'! ""!""11"-1 ~~I _I<'"'" '1-'!'l\\
LJOI!nj<>'. jPU"~PW
'NI
'
I'"" ""4d '"~ ~"l '"" "!"
"!-
' -"I)
"'
Uo011Clj'" jOU"4PW
T
""''''""-'
I'"" .-..;u4J ''"' 41''-1 "! ., I .. u - .. J
' ,L\1'"
U!!Jll1i<" llUn4PUI U!
.; 1 '1"1" ~'"4J ,-r.1 <'!
U<IJlnj<>' IOU04PUI U!
' '"" ''' "
"
.I.)
' .,
,I '1"1" ;y;r.4J '"~ "!- I .1.1 ,..! UO I!~
~*
"-''!'"'
P->1-"
OLjl
ru~ u<l><~"i
.... ,

i-'""' 'fi'l"4 I" 11<"1"'-"

J" -'-'"'" P'-'"'" ~ill '' 1!1l Bu!-II"II"J ~41 .1"
"
'''"'-f'l "'' i~IV
,,'
OlEO 40!11 \\ -u<>!Hll"' I"""'IPLU U! P""
'"~ U! \j~IIUILJ"' f'~!rl\1,; '"" ""~ ''\''1"4
.l.i41" 41! II "f'!IU<lJ>j I (LjPll! J" li<>JPO>J ~11.1 'L I
"" '"'~IV
II ''-"'~IV
"
\U!l)~

' ' "'

;

l - I ""' w o"" '"~~IV "OUUW' "" <n

<U<WUJ .i~l Jnj <.illjn< I) IP J'l'l"
I f i:
l -- i>
"
" '~ll '! ~"!""11"1 1~1 .1 11 0!1!1 '1'!4 \\
z11
'-'~'1 r
-,1

'''''"' ,UJZ"il '

,w n

;:,j I -N I" J.'l" 11 J" ii~ >. t "!

.'" Y'>
f''"!~1UHO
''
'"l"'l)(IUI ~~ I'"JI1.>0<' Olllnj<l I '41 '! 1"4"
"~~l\0 4'!"" I 9~1"-j .IHJn;>.>jO\IU~lUf 041 Jl '(:1
~ ,,,;: p
"' :; ~~I ,-,
"t~ q
Hct -~
7i Lt -p

trtf r. ;.;.J </,;;: "' '-'1"""1""' uoil ho _1n tc<n

""''"'-!""'II "' p.>o.i' omnh' W->W 11~" "'""' ''il "-'"4
"'"'W '""!1~1 ~4111!" ;unJm><lu.m !U~" !\;
'!1!'1'~>''1'"" 'l''""''l
l"""l"''"'' ~"''""'"''r _~,. '~"~"h"
iuodoJd ,, "'"'I'' "" '! i1"'"'H p "
V! ~"""'11'~1 ~~~ 10 ~"" '11!4\1 Ut.>l< ;, "II.!'' '"""
011.111-l'O'- 't '~' un ru.>d,>r "-''l.l>tl,,J "''"'lUI .'
''"'dt>Jd
"""'''-0-o~
'-o-'"' T
' '''!'l!.'l'~ """ 1"!1"'1",1 ''I
iil.i\l,i
""I';, '4' .1" '"""' 141.1"
m>pu>J-'r"! .,~ '"!1-'-i<kuJ ''!'"'I' -1 .,
()lj_)- 'II''_) ']
:.pw1<>Jwno :. '''"'"'
" ''"'"''I"" ~"! ""11"1 ~41 I" '"" 'P!~ \\ nl
I'"''+'~' '""I ~"!""11 1 "'II '1P!""'.l
11
'fl
HI n '1\!'ZV 'I'
!0 -~.) 'fll't\o -,
" '
'"J ! --'1 r

~I '" ;
www.examrace.com
 ! "I l '
Wl11d> one of the l(olk>win!' " the C'<>!TCC'l
<latcmcm 0
1-ph~n;-1ethanol arid 2-phenyl cth"'wl
'"' ""'" 11\~) l>~.
prcpanoJ b) Ihe rcatll<JI\ ol ph~n) I
mogncgium bromi<le with
a HCilt land CII,CliO, '"f"'Cihdy
b_ I-JCIIOat>J6.rc>!"'ChVd)
c. Cfi3CIHlmtJ!:\,resreomd)
'
6 ""d1hc' ::;:
Jc"'"'J~r 111 .. ., ~::; ;;:,;~;~
,;
" "
).J,
',, '"
Which """
" ' ''
"' ,,
, ___
" _ j _ ""
l'hM~Br

"o--T''"
,. "ith Phl.i

,, ----,- .... " it I t

nilh l'hMgBr
"'"
'" ~"7 "
>---
proJuc.>< both ~Wte_ and
" .. "' in I: I ratio. while PhLi gies
_1,

' '::\,...- "

'"
.. --"';, ~~,

"'
:f.;., ul pn>Juet
Phi. i l""''d"'"' hoth ketone and alcohol
in 1-1 r.mo, nhik l'hMgAr gt\'c' the
~etone "'rho maJor pmduc-t
Which one of the t(>llo"inc "th~ '"'

and cl) thrn llllpuomd' .,

o.
b
t
I. _l
L4
~ fo!}thrn. 2. ~

1. ) . .j - f.!) thm :
J.2.Clff'fhru:l.+
l'omider the foil
e
Lrythrn: 2. 3 - I'
lhrW'"

'l
en

compound:
"

,'"
protons in th~

arnmticit~"
1 prmnn>
a I .md 2 oUI)
b. :! and :J olnl)
''""-'I ion ur acet;<nHJ " ith
mc!h)l ma~no,ium brnmidc li>llowcd b) c. I and 3 nnl)
a<!J hyJml) <ic ) icld ? d. 1.1and}
a. Acdon< A~er!lun (A): I he pho1phorc~ccnc"

h. r-\>t11;l oknhnl lr<-><:tnun ;, "h'c"c'd ol >h<lrt<r

"'avclonglh; than the tluorcseonce
c. !-butylamine
U_ N-meth) I acc-tamide 'I'''':! rum.
R~~""' {R): 1 1 >laic ha; a low~r cne,-!(__1
IIHtn '>t ,l,!lc.

www.examrace.com
 ---------------"----"""" ______ ______________________
" ..... ------~""' _______",,
I n( I:'
Both,\ and R arc rnd"iduall> true and Both A and Rare ind"tdually lttJe and
" R "tl1~ correct cxplonatwn or A ' K is the correct "-'l'l""""'m of.-\
Both A and R arc tml" iduall; tnJ~ hut Both A anJ R re mdO\tJuall; ln.lC hut
" R" n<>!thc COfH'<.'I '''planation nt- .\ " R "nm tht e<>rroc1 "'planation nt

' A" uuc IHH R 1< 1-alse

' A i< ltUt hut R" i;,L,e "'
" A" falw but R" tme
-\.,rrtinn H): f'res."on' of a gas " du~ w 10 " \ " !'aloe htn R i' to ue
A~'~tiun
the 1mpac1 of coll,.oon of WI' molecules th:tn
"gll'"" th~ \\all; "f 1hc contaiMr
Ruon IRI: The cnll.,ion> between to II>
ntol<etJie' depe"d on tho tempe.ature and a !'loth
are on dependent of""'""' of the g"' R "!he
" Bmh;, and R a1'ltH\cliiLdually ntJc ami ,,
R 15 the correct explonanon of\
b Both A ond R aro ind!\tduallv lrlle but
R,; "'"the curr~et ~'planaltun nf ,, '
c ,>.;,Into hut R" t"ob~
d \" f'al'e burR" mw
"
:n ,\.,.,rliuu 1.>.1: I .tlwlacctnaceuue ~~ ''"
rcdJ"h vl<licl colour wuh ten>< chl<1ndc
Rl'-11.on iR): It <"<ists predCimmantll 1n tho
l.~to fonn ~ and Rare indovodtrall~ true and
a l<oth ;, arnl Rare mJmduolt) true anti tit~ correct c.-..planatiun nf-\ 1
){ i, 1hc C<>rTO:<,:t L"<plana!lon of .\ <\ ond R "'" mdil'ldU.111\ U\l~ but ,j
b Both t\ and R ore mdi<tdtoJII) 1n1e but
R "nm the correct e'plan.1tH>n ,,f;, c \"uwhutRrdal'"
c >." uue but R "' tOI"" d A " 101 w bud!. 1>true
d A" false but R lS true A"ertion (A): PCI e'"t' but )o;('J, doe'
.\ss~rliun lA): .'\ "':?~'"'"".11: HOI "'l>t
nmbomyl brt,ntde Rtaoon (R): Pl""plwn" i; ntmc ~lw:lrn
d"plaoement P<>"'"'" thn mrrngen 1
"'
~
a Both A ar1J R are tndiv,dualll' lrue and 1
I I : (1! R" th~ cotrc'<t cxpl"""""'' of.'\
~'
b Bo1l1 >. on~ Rare md.-odU<tll\ lllJC but
rons m R L> ""'the cnrrect e'planat.on of A
be ti.wmeJ
~ -\ 1' true hut R " IOhe
d ,,i,fa!.ebutKitruc
" 11 As..,rtinn HI: Maltrbe" a reduc1ng 'ugar
"h1le >uct ose 1' not
Rt~sun (R): Su'"'"" It~, ketal linkage
whcroa< maiT<e ha< hcm1~et~llinkage
a Both A and R ar~ ondt>-odtralll true and
R "!Ito cnrrect "'PInalton or A
''''"'omo lA): l'hc ~mater th~ nwnbe1 of It lloth \ ond Rare mdHtJuall, lruo hut
alhl group' anched In 1he ;l'"'"l" bnrrJed
R '-'not th~ cnrroct explanalion nf ,\
carbon moms_ the more >table is lhe
all.eno c .>, t,<true but R " fal 'e
Rtnson (R): Deb;ali>al,lon <'f olecta>n1 J Ar>fl>cbutRitruc
thruugh merlap itrlfl\lng II atN.l a l>und l\h1ch nne of the followtng ts the c..>m,<1
<tfbllal> klitWd\ "' ~vper-conjogutiun. >tatement 0
OCCU1'< ILl a greater ~leNt "'the 1111mh~r of Micelle' f<>m: nnl1 ab<"e tl:e Cnlcal
,,IJ,)-1 ~'""I'''' increased Mtcelle wnce'ltmtH>n and abm<lhe i
www.examrace.com
J
 ; I I :
~ al:><o!utc tem['i.'t"turc \l.tmt '' the rndUil\e lmn"h"" thm t'l(~ur>
b t-:ral\ tcmn<'mt!irc li-nm th ltmc" tropkt ;tat~ 1 1 t,o tho
c I'""" t<1llp.:mune ground stole ""~leiS., no"n n{'
llu,m,""~"'~
J Nc-el tcmpem!ul'~
.15 Whodo <>11C uf llt<o 1<>11"1\<nl( >tU!fH\C!tb 1,; h 1~""'1'"""'"'""""
"''' """'"'!'' ,. tnt~mal '''""'''~'''"
" L,.,plonh<c collmJ.\ "'" thcrtn~ d lmor <;<tom <'<<><>ong
<h<lt!mi<"<Hh uo~>11lhk Wind> ,.,,.. "f 1hc t<'ll""'"~ >tatcm
l l <ophnhc colin!<!' "" <mhh,-ctl "' <'<If! h.'('

'""'U<alh h, od>oti"'J """ a l,.b""~'""" <>f pl1u1nn h1

c I "'"''"Hl' we l<orh.,hw c<>llnd,_ al"""' !cod~ to chemic
<ta~bud '"'"''""ll' n_,
the r'""''"''' h I tw ""'lar "'Hn~t"
"
"'an ~muh1t\ mg agent l!m!lle
d I "'rhnh colhHd_, ~rc Jc,tahl"cd ,. 1 he ~uantum 1
knchcult; b) the P'""""'" of 11 all\:" , ncarll "
"
pol\ 1tWt In the "llut~m
Wh~<h """or tl"' n:acu""" reprc,.,ntcd b;
tile follnwong <<JUal"''" " "" c\amrok or
'"""'*""""'" catah ,,.,
.c-"'-c_.l!,tgl :ulol''' hhxl v. loch
",, ' clmr~ru M>l "
~<>agulate> ~lnoJ llhch
' g"U>ol)- charged "''I "
d n cu~gulul~>hh>J llhld\
"
1'<""'"'11 d>.r~c'd '"'
lT ooogul~te whoch
_l l \1. oft I':';;;~;;,:;~:::::,;~
hd "'"' llw
'lat~;mcnt'
nc~ttl'el< dmrg"d "''I "'""" "
" faster th:tn n
\Ht<h """or 1tw tollo""l!- "1he n><recl
<tat~lneot'' ho~ ''an ~'"'"f'IC of c<>ll<>td"l
I"''""""
U '" ~<Iii
atu.n cnorg) " """' of
a IoqwJ <i~>p.:r.wd m !!-"
I> lb ili:to<at"m
~ i"'-' Josper'><'d m gas
' '><>11J J"I'''"..J "' ~"'
J "'ltd oh>!Wr'-><1 m h<juJd
,, ., "''" Wluch 0110: <>f 1!1< li>llo<<t"g ''"!l>l'<ltHld>
h'" ena"l oot.rc I'"''"' '
nr tiW \Ub;(mt<"
role t> liN tlfdc"< m fSI ' "' "' <'H,

h1gh <"<llll"<'nlmHon o>l' the ,, I'

'" ,. "'
S. the rc>a<tton rate "
~~,,~;tufiSI I'
rh>t nr the '""'~'""'ul nf tht '"'"''"'" 'd '"
<',to,
" C<~
mte agam<l the rc><:lpr<.,;;ol nr ttw
CnnJcr lite lilllmlln~ <UJtcme~l< al'<l!J!
'l!b<!l'O!O CO!\CCillm!!OH l> l>n<'3r

Select the '<' "'"' mt<wer U'lng the "',J"' '""nllltl< """"'"'
Awnmtt< """'"'' ""' l\ealer h"''''
g1wn '"''"" than "m"'"'""
I nnh-
',, : nnh
lloctt"""'dca;,ng 'ui"Hlu<llh
""''""-\" 1tw bu,~<>t; .. r '""'""' at.!
'd J ''"II
:and J
,lcc.,..,,_ " >Ihd a" mg
' ,t.,,rease the ba><c'\t\

www.examrace.com
-,-,
 '' "I I C
1, .\ _g1wn uhll>"-'rl! ;tree\> the ''"""''I ,)<) 1\'lud> ~>ne of the f<>!lou mg mdh<H6 "Ml
nf "" ammo nd the ocrdrl_\ <>f ;1 u;od for the C!ln<'~r<ron "! >n ld,.hc\'"'"
c~rbo~1 he ""iJ m ''l'l""ilc \\~\'' In ;n ,1J,.pcnli,.c''
Wiud! "f doc >L11'"'ncut- giwu .1h""" "'" " J'h~ Ruff \ kthml
""rr""!'' b. fhc \\'<!hi \kllwd
I ~ncll '"'I)' c f'h h'lli>on, '"~gc11l \!dh"J
",, :! ~n,l 1 ''"!)' J_ Thchilwni'<S)nlh""c'
1 anti '<>nl.l 50_ \\'hid> unc of th~ l'nllo" "'~-~"""'
,,' !.2and_1 procnl when a nluloOf! of
>

m-bromoamsok oncl c>bromo~n,.ol~ ;>r<

tr~al<>d '"'h 0.:.\ll, '" l"l'"d Slh
'""''"''
IBN r'}J;., 'CH: ll!
<~por<1td1 \\'l11"h on~ f the fo!lowmg" ',, TI 1N Gl, C<;<fo\
lh" re-.ul! of lh" trc.1bn~nl"
.1 HmJo l'ioiJ uano .. dtnc ,_ n,o.:-< rr ,.' ., "'H
h BNh .1idJ mn,odinc
m-brommniok ) wt.h n>-anBodmc
" "'.,._ ""' -
'.'PO

' "hi I~ u-b1<>m'""""k _l'ldd' 0

,, '"'"l<ln>o
mbton!OJ!Jii,<>k Held J~.lni>idmc
u loik Jlll'mnoom,,k ) 1dd' o mixlur"
n- and m-an<.,dm~
An al<k~ o. ""Ji<c..:l
"'
'" ,ln\>ni> ""'" "
i poml
flr, l!,O f('ont!ili<>n.\)
tC<>nd.l~<lnBI -h
~f <l,lkm~m; ~;~~~~ oho~
,, 1h
f<mnc,)" ' ' """eel''
lbc

).,td 2oml;
ate

a I 'ornhiiO!"' \ gn~ oldomc

l'<mdui"'o-B \'tdd' o!danc "''" ;
,,' Z >nd 3 nul)
b CoudiliM.\ gl\'o> oltl.r1c I and.\ on!)
'
~
(\mdilim>B ; idd, o!duni"
I 'nn<!ilion ,\ ~~-
" LI.1ndJ
,\n aldd!vdc '""'''' "rth " .,.,_,lUI'~ <f Jo.C'\
<'<m<htum-fl .ln<l :--:11,('1 to gi1c ,, l'f'"IIIOI tC 1J!,:-:,1.
uluch up"n h)dml\m yekl< >lal!lnc
\\ludo'" lhi< lddo)d~''
hJrm;klcbyJo
' .\ccloldcll\ J~
"ilh !-It''\. folhm"d " l't<o!""naiJdo v de
<<'<~ucti<>n "u!o I U '
"!' ll>e fol!<>lllllg " !Jctt.<ldd1\Jc
\1 'hoch <me ,r lhc folltm rng " an c"<.lmpk
,f pkCr<phn pnll~m'
a ,-.,~m

,, '' '""' b
C
(;!_l~"gon
I )X) lolc<n
Hrnanoio aood
J li>mon ~h>bulm
Whrdt ""~ nf the tOilo"rn~" Ihe ~atloc'!lc'! 1,\"Juch n! lh~ l(olk>~<in~ t"-1<.'11<>n> """
R,C'
' R;< ..,
m.inh !h\ oh cd ill Jrvillg of ool...'

"' R~
li;Jo "~""""""
ll)dr<>l)i
,, RN /'ol,m~ri .. lum
,, <hodahon

www.examrace.com
 7 d IC
Sdo.:t !he ,.,,.,.,~t an"'''' "-'"'g tho end"' c nrtrogen ga>
"""bel'"'" d hyd"'~"" g
lan.l2
h ! onh
,, ' 1\'h>l " 01o role ot' pho<phl<' EO
d"l~~g,1ll''
c lanJ1 a l'n O<>nlwl rH bd <I the dd<ogcm
J Ci~<\J~ .:unt;,nu1g I mer
Hn" onan; ~quil~11l )>l"lnn "'" b To '"m<Wc Co'' anJ \lg'' '"'" lh>m
conlaiMJ b; 1'\lS. a foon~o ~otnpounJ ">!<if lh~l OJU"; lh" h.11\IO'-"' In
!i>r P\ IR''
o To !""' i<k "'''"'':''""" >h< f
0 10 J l'o ;nhdr6 Jewr~enl
h II pho,.phal~. dct~r~~ul-<
c 12 MlUl'O

d ]_1 ''~- \\'ln~h amnn~

lr!ud1 ""~ nf tho li>llmng ;;om:cd~ 'l#hlc anJ <omP

n);j)OC!II d e
J"'""~:~<;'" r.r
l Ill 'I
4- bl; arc .:;~rl~; he ~.,.1,..-- Jc~i,oJ ITnn>
a in~ I~ J:,u} >ctcl_ nbc ociJ
h F"1' """ arhu:. he"'~~~" JotwoJ lfnm
l l'll ,,

,\ >m~k olcohnl. ~l;cer<>l
c ~" "'' oclmm .oll< nl ;lkyl-
bon>ononlfoow: o01J;
d Ft> ore mi~turc.,. of "'Jiuno ,,,It> Jf
lon2 d~>m tmnhu,\loJ bU) """i'
\\lli-:lo ono o!' !he li.>ll<>>\tng 'h'""
'Pf"OX!tnalc ohetmoAl ln!t< an.l ia~u!~
J'"U'''"' of< 'H ,< '0< 'IJ,n ~'II;' Which one of lhc follow mg ropn:cnl' the
" ~uyld U <>1. >~n~lo! !-1.1' )'dim ;ol>d h>rm~d on mc~ong d~.-l'f"d
12.5 0) l'tl'o 1aiM"' "olh an oqual omoMI ,,f Xo'.'
h Smgld !1 <>]. ""~kl a 1\d'l
I i_<> ;\) h l:\cFf IPlFd
.: :im~ld 12 ,i), c 1-"l.lf'IL,j
cl. j.\:dT lf'I,F,,j
Hom JflO Mlk ga' h\!lral<'< <>f .-\ognE~
1-:.rvpwn ond .\:enott fnrmcd"
J l',,,,,k"t\l hnnd J;><mal;~n
h Elo<!rodl'" ''*'o.;lwn
< ''horgo \lanl<"
d l'mrpmg of nnl>lc "' "'""'' m the
"'"''""' ,.r li"ovc-n \\ale
,-,~- \\-Ill ""' m~ndi~ mm11<:.-nl .,r !nkn!
lanllonide ;.,,._, nnl all'o~WJ h) lignd" in
CilmJ'>1"nn M 111"'" !>f :IJtr.n'lhnn
mdak.'

d Lil a LnlhJntJ<, "'" he"'"'"' than ,;,;..

H-n>tinll m~1al;
Winch """ <>f the li>li"" '"2 " d'" ""''""' h P">t>d'!i..,; of !Jnthll;cle Hn>O ;,-,
'"'1-nlonl" T11e blue "'>luli>~l> <>f ~!l.. al<
imil><
molal m hqu1<l Jniiii<)IIW de<<mtt><"" '""'
<lo"h "ilh hhcmlinn ,,f .; J-<b:!tcm oro""'"' .lcop c~kd lhon
,j.d"clr<m
,, ga"'"'" amm<>n1a
b hvdmg~n an<le

www.examrace.com
 d L1n!l;anO<k>< l><m htgh """"hnoti<m 2 <'r"ak~ot
ntunh."!" _, !"oordonlc
\tjUC~~" <t<m 1!!11 "'luti<m Jo\olup Scl<Xt lh< ~<><reel '"'"~" u"nH lho ood"'
u>t""'" <!fangcn'd c .. lnur '"' ddi11g gi> ""' bd<)\l"
lhiHC).100!C ">luli"'l \\ lwo ;, the colm" l.1ml :'<>nh
duo to J ",, 2 onJ;
a I 'h:u-g~ tr:mfcr tron"(wn 1 .,d _, <>nl)
b ti-d''""'~"'" ' 1. 2 anJ _t
c n-~''"""''"'" mrhc lig.,ml "
d ~-n"tron'llon tn th~ hgond
\\ h\ "!;,;tlc11Jd ncarl1 Hl"' llmo; more
''"Me thmo l'\il ~;ll,t,f -
1"-< II, '"' "I"""'"' oa<>h onol """'"'
inot.biM,I '" tho l'>i 1:--.1r,J,J'-
",,
c<rnopl"'
" l\1
h s.~ ,ll, hgon_d, "'"'"<ton.: hondron.:" d lO
armonJ th< )\'o' """'"' 7_,_ \\l1kh .,~
liltro""'~ ;, d"' cmr,d
en' " a .:hdati"f ltg.1nd .mtl
' thomwJmamo"-'UI no"'"
'later
hq!l
. ,, ""'P'" "'luwm <II '""
>ilmg r<ml low" th.1n
"'""l'k"<O> .then it
,1. l\1 I, " d1c "-cdk<"'l h!<Ontl ~n"""
,,, ll'lt<m con.:~nbo!cJ 11("1 " added In o
ne~alc M>'IOIWn from

<olmoon nf {I 'o< H,l lid'' mn. on >ntono "' "" JoHati<>n from R,,oul-. -, lo"
h1no ""I""' <k">dOJl' duo !1l the['""'"!""' -'h""' ,, f~"'"' c de> 10110n fro>n
<f wlu~h nn~ <!f !ho ](,IJo\\ mg; llooulr ),;\\
.1 jCoC! 0( d " ia!\U oh:<l
b rc .. n,J" -"-",wid H,,\ b., J~<,o~iol<>n coo<l,lnl.< ~'
.: {Co\'l.-(11,\liol 0 Ill and K, 1 ' 10 \11>,11 " tho
J [CoCkllofiJ,r cOfl<~nltoltun "f l! ,{_1- on o >Uiuti~n
Fm II itllo< I MJ". '"''"'""" prupar~d by Jiw>1nng H 2 molo-> of the
<Inc !< <1-d t"omi!i<>n ac!cl "' "ot...- k> 9"-~ I 1ur~ of <olullm('
~m' \\'hal " !)>o 1121>\1
"""'~) 0
" ',, fl It> \1
" 211.110(1 ~"' ' ll 1~\1
b_ J< '
' " 0 !7 \I
\\"h"l" th~ oppn>wnak pll '"Iuo n!' 11r'"
ll.! TIC! <nlutl<m'

"' ",,
'
""" "I' th~ 1"11nwm~ " tho ~<lrr~d
'"'
'
\\'hod> nne of U!O l(,lfowno~ " the "'"teet

'""''="''"
",_,., -'t>blo
'" '~quonO<: fnllrmcd h; m"lar "'""'
cunductancc' <>f1h" "'"' '-'
b dif"<>J><Htwn~tc tt1!<1 t 'u' autl r'o Rt>
'~' ' '.;a
;, nxidilcd I<> < 'u'' ",, 0,:;- r.;

'"'" ''
,,' i< rc<Juccd to I'u ~

IX Rl-
Wloi<i> of lho f"ll"" ins !)'!"'" .,f ~ .. noi> oro '
71
' "'" ' ' ' '"
~ ~

rr~<"ilt m ( "11\l 1, l! 1"

r> n ' ' ' g!\cn lcmporolurc and pr~"'"'"- 1\hJ.:h
I Hcotrrl\olent of the fol1momg quaul>h'-'' mm< tho
""
www.examrace.com
 '' of 1 -'

same ti.lf aqueous HO ond to,-

hCI''
aqu~"'~'

,,
!.!..:::.!'1
I Tmnspmt number at utfinl~ dilunon_ ___k_, __
of( 'I. 1' (CI) ~I ' ~,
l Molar condu<ll\lt; al mllnu~ d1lunnn.
of\ 'I_~- (CI 1
" ,, ~C~.l

3 lllnlc "10l11ht~ I lllfinllc Lhl!ltwl1. nl' ' ~-~~

<,
\T n' ((T)
Selo~1 the <one<:t answer usmg: lhe coJes "
I'm chem1cal renwon_ ,,
~"""below '
t(lUml thm th~ rate <>f '""''<
I and :' Ml} when th~ cmwentr>Dwn
'
b and :1 <>nl}
1 1'-'"' ttme' \1/llm 1s

'
"
2 and :1 onl~
L hnd :1
\n dectn;;h~'n1JCal '"II 1> tm1de limn
alummium and SJiver clecnode,, Tho
." '
reaction''

smndanl d;x;trode potennals uf' alummmm

and "I""' are -16(> \' and I) 81! \'
lt:<f'l'<:lnoly wt .. cb """ of the follo"mg
ro;odUlll' ""'"' placo '" the aliOde'
a A).(;) .... ';\ (nq) ' c
b A~ (aq) ' e ----> .-\g(>;)
c "1(,)----> .\t' (J>i.jl 3e
d \1' (aqJ - -'e ---.. Al(g)
for the reaction A ' B - C.
d 101!'
Om"dcr lbo fott"""'~ stale~"~"''''
~"""!'~ ne'<'f nogallvc
11f actl\ "''"" IS
" Z n1e ne~ome
enerf!} <f act!'al!on
,, mean' mk of roactt<t mae'"''" '"th
~1111't"a!UH,_

Zern acl!\'a!ocm c~""l')' means the nw

' <If re<JCMO " mdef"'ndent of

., ~!;,::::':~~'
~ '
bcha\es hke
the p<escnc o(
temp"'"'"""
Wind! of the 't"tl~nent< ~" ~n
COYT<"<Ot'1
,, 1 onl;-
e ~are "be"

the reactan~<. \\hal b 1and'l

c I and3
<I J only
" If the reaction I litO F,lf!J ... , 11Ft~) '
order >-eael""' l'(g) """e to twnceed ll} the IOrmntam of
P<<tl<l<> ti"l ordcr FCOCil(ln non.linear nct""t.,.] c<n~rleo.. wlw" lhc
II' 1hc )..Jodmehs\km~n n~ech"'""" lir "" numi!CI nf 'obmt1nnal degree< of !fccdnn1
en~me cm"ly>ed rca~1101'- lOr the acmmeil comple''

__b_, p E
'b '
1
What os lh~ \Jiue Ctf the ~lchaelos c 3
C<llbtant''
"'
www.examrace.com
 .,"'1 .,u ,.J ,'ll. I
'~'"'I "" 1.11'~" .o ll I'
.,"'1 IJ ,.J .,'ll "
,.,. 111 I'"'"",. I .,. l .I I J"
'P'"""'"-O'I!PUUJ,)f[ '
r~ "" o'H puq,JH q "I"'' -'""" J" '"I'''' ~"""~"'~"I' oq1 " 1"4. \1 {{t

I< I'
'1"' "" 1.11'"" I. !II "
dhJ.U,<J'l! l!lo'll -lhJU!I 01 "
uo~~""' "'.!'-~'"'I pu. 'P'~"
yt iJ"~'Il P'l"><o"H <>I fiu!pJo""" JU.>U<-'11'1"
"
p~uoo NJ! >1 iiuo "''11".1 oq1 j<> ouo 1p0ij \'\
ti:I'I,>'ZH'f\' I' "' Uln!~"-'' ""' l
OJ<>IU \UOW 1\1>11
w u ~u -~v ~
J<> p<a;."><i ~IL O!U ~~
;n -,.> -~H 't'Y 4
to.,._ I 'ZH 'IY "
,l',d' >

,.
p,d' !'
ds f
d; t
'
J.r
'
1
(U0!),-10pU4 \j!) IJ 1'!'1
'I. k! '(!
'.-Ill ',)
1H U (,I O<O>~t~f,'
'JS '\'
"'"" J" Jlml '"l"~uo OIJ1
1]!10<>1!~) 11'!"1
'IYIIqJ<t ~"!""11"'.1 "'-II_!<> """ 'l"'l,\1
11"1 ~!{) ""P'l
,,rt I' "'
""'~ "'I"" "'II ~'"'"
'"'""'"
~41 P~l~' pu~ II l""l 41"' ! '"'1
!"'-'"" ,"Pt "
;J~ '1
P"""l"!' 'JU"!d
1~'1'''!'"1"" .......
' 1,!~l<qn< ""'" 011".1 ,'Jl .1 ;uo 401 4"
'I' "

I"'P"'I"P" POI--'OI"P ,, 01 'l'"'><l"'-'"'" 0 '"' puo 7 1 't u

-""'-1 umu '"'""'~'b 'I'' " I"'"I'" """"'" "'l.l "'
jU'!"~"I"'l -, .
' '"""""' I''""I""
~"'"I.F'
om "II '"'""-'""P po uoop~ "'~I
"'.-P'\ ''-P\ >ft JD "1"-' "'fl so>truom 1'\1'1"" "'LI. P
'n 11.1 r '""'~" ""'"' Oljl <'I''"'''"""'"'-'"'"' "41
,'II.> IU 0 puo P~-"P o~1 "'"'""ll"' lil' ~u. -o
-n> 01>.! 'I U!>!POOI
'0.1 ,'O,l It P'""'"''l "4' .>>\)"1"" 1'-iiUJOO "'U. q
I'"" -'i>.l"luiluc"""
,) i!u!~"-~""' JO "P"' P'""-'".1 41 '"'-'1"'"' 1''1"1"' "'1.1.
""'"""' "
""'11".1 ~11 I" "'" 'P"L\\ 't(,
"'"1"''' ~lq!"-' '"' ~_I" pod"" "' P"'-'''-'
-n'.-1<~ r " >11~~UI01<"1' ~"!"''lJOJ ~tll J" -'U<' tpltl\l.
'1-~J"'_!\1
'I 1.' .,,_1"\: 'I
"!''1"1"""1"\' r "
'""1"'1'""-'"'''~k! 0
'.-IS ''-!.l " """"""-WUI J ~
;.>"Jtl(>
I<'!I"''P! "-"'q '"1'""1""' Jo Jo"J 'l~<q,\1
""''""'"""" u l"""'ll ,.
"''ll'!J "!I )" OU<t IJ'I<j" _In ~[dUiu\0
.,.1 It .,"'1 .,'1.1 P '" ,,am
"'""'II '1"-"lSOl<l " " "'"J<I"' ~II "-'4"
\jut> tJH!I J'' oou~s:nd "' ""l""'""'P 'H
ZIP rtl
r"-1 _,n ,,'''1 .u. '
'"
www.examrace.com
 Winch nne <:>f lho fnlhm ong " th~ ,not~'<:l d. I'm'' La'' Co'" Yb''
'lal~-mcnr Ill~ .\n acrkd Jtlut<> ,.,Jutton of '\JI':-, " '""'I
n,~ ~""J"g"k aci<l> "f :\11, anJ \;II, ar~ "" !he ""''""'"'" of "h'd' '"'" ,.r lh~
o :\1!, <~nd :\l!,.!"'"""h'd)' h;l]o" ing mcLll; 0
h :\II; ami '>lh '""V""'"~I' a '-..:i-cld
" :-:11, ,,J ~H;. ""V""h'~h (, h'"'
,t l\"11; anJ '';,!{,, '"'l'""tj,-d) c : "1'1'"'
')'!, { ".>!t<!dcr llw full,,.,.'"~ ;Wtomo<ll> d. (iniJ
!! )JH!g<:n " c\ <th ;.,! 1\ th<; dwn <>f ""!d liJ5 n, ohar~<' of !be bbt I
Jilut~ II'\! 1_, "" c'''"""<m of <mn " m"iuro
rc C<>~C oll>d \, II hat''.\''

1 .\lg a Sih.:a
1 Mn b ]),,]<>nuk
I .\1
Wh1ch <>f th< <t1tc-mcnt> gou-n "h"'~ ""
"""""'! I !16
ol I o1nd ~
h 1anJ .1 ""I)'
c t. 2 .1nd _'<
d_ 2 .,d ~
1\il 1\'lti..:b Jfic of tho fnll"wm~ l.>lom"''l "
not c-.,r.-.xl fot ho.-) 11 alc>t''
,, lkmil) ;, gno>l IIIMl th.11 "f"''"'
h Didcchic cm"~1n1" ~'""'""' thon tho!
"~'"''"' b. I .1ncl _; onl,-
<. I. :1 .1nd .]
d 2..1an<l~
107 \\'hat i lh~ hlndong onc-;g,1 (U m<ol 'I <of
]{)] ")'.:, if !he "''"' ddi."<l " II ~I omu'.'
l.~'h tn"
b I ~\>x !H"
1 8'/x 10"
,,' 1 WJ '. !0 1'
lllN \\"hal <1<1<.-'' C<>mpk'. tn (~lh\ !""" d>amm~l
102 !'~. "'""' ,wal~ nlubl"
).JO "l11ch
<:oholt tlll) ohl,ndc
a .fMISol!f' '"'"'""'"'
o:.xluhu~

!lvJO<>\!dc h. OptoOJI '-"'"'""""'

,,.Jnhk
" "'"""'Jfli'""'"'""'
;] Lmka~c IHmmm
l><>lrl JIJ lhmmakak co u<<'ila< a m<"<l!omc
l<>r 1tc.1Uncn! of whd """ of tho
f<Jllol'mg.
a \!alai
1\'hioh 0110 uf the folio\\ ing " rl>c """""' ],_ :\rlhnli.<
.oqncnc~ of r'~ ' l.o" I'm';_ aml \'~' m c. Dl.:lhciC>
'""'""' mg ordor nr ~~~~" wnte rodu~ J l"l.:o
.1 Yh'' I'm'' Co' 1.0'
110 \\luch '-"'~ .,r
lhc IO,n""in& "'""PI<~
Yb ' I'm' La ' <pce~c J<><> 11<>1 <~!>C) lh< f c\C>: ru]el
Pm'' La ( 'c' ' a ll'u{l'~ld'
www.examrace.com
"'

\IJ_

( '!,('('
"

'
II~.

'
115. the correct (J
nr moth; 1 " ;(""]
y
" (),_'
0
' "
I 16_

"
0 A

www.examrace.com