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2 iZ
3.85x lO 24 2010 (99.999999%)
l o ;
()
Il Daryl Chapin ;
6%)
;:<\: (generation) :
(band
; gap) 1. 0- 1. 7eV'
(two-step dip-coating) crGS( copper indium gallium
f 11& ;
(photoelectrochemical)
() ;
l o ;
()
Il Daryl Chapin ;
6%)
;:<\: (generation) :
(band
; gap) 1. 0- 1. 7eV'
(two-step dip-coating) crGS( copper indium gallium
f 11& ;
(photoelectrochemical)
() ;
,
( )DSSC
(1)
(2)
TiO (5)
1 DSSC
(extinction coefficient)
eTi02 ~ ecathode {
@ S+ + eii0 2 S
,
( )DSSC
(1)
(2)
TiO (5)
1 DSSC
(extinction coefficient)
eTi02 ~ ecathode {
@ S+ + eii0 2 S
3.
gm \R
@ V
A @
DSSC N. Papageorgiou
@
(Pt)
-u JX
/
(H , PtCI 6 HO) (isopropanol)
5mM j9I (spin
(
0
385 C 15
(4J ~ f
2 DSSC(' \l )
!J) ( U
I ) S. S. Kim
()
1:; + 2e2 3r
1:; + 2e;ubstrate 3r :
10nm /
i (charge transfer
DSSC resistance , Rc
1. PVP-Pt PVP-Pt
( 1 - ) (colloidal)
3.
gm \R
@ V
A @
DSSC N. Papageorgiou
@
(Pt)
-u JX
/
(H , PtCI 6 HO) (isopropanol)
5mM j9I (spin
(
0
385 C 15
(4J ~ f
2 DSSC(' \l )
!J) ( U
I ) S. S. Kim
()
1:; + 2e2 3r
1:; + 2e;ubstrate 3r :
10nm /
i (charge transfer
DSSC resistance , Rc
1. PVP-Pt PVP-Pt
( 1 - ) (colloidal)
pvpftiJ (
FTO)
[1 01 0 (roll-to-roll)
PVP-Pt
181 4 150'C ;
()
(conditioner)
PVP PVP
() DSSC
Pt PVP-Pt
Pilx() . G. Wang
XPS
PVP {
l' DSSC1
DSSC
c:::a ITO grain
Naked ITO I ( ~~ Conditioner PtI4
; .. PVP pped Pt
'~h~ >UHhUHh
MPN *ff
Conditioned ITO | )
AES
;
pvp- pped Pt pi\ v. Ztt .lt4.
n ITO I (c) DSSC PVP
[ PVP-Pt FTO
;
Heating treatment 4 ) 4l6)Q, 9;l.Qn
(300'C 5min Twice) I () ()
DSSC [
pvpftiJ (
FTO)
[1 01 0 (roll-to-roll)
PVP-Pt
181 4 150'C ;
()
(conditioner)
PVP PVP
() DSSC
Pt PVP-Pt
Pilx() . G. Wang
XPS
PVP {
l' DSSC1
DSSC
c:::a ITO grain
Naked ITO I ( ~~ Conditioner PtI4
; .. PVP pped Pt
'~h~ >UHhUHh
MPN *ff
Conditioned ITO | )
AES
;
pvp- pped Pt pi\ v. Ztt .lt4.
n ITO I (c) DSSC PVP
[ PVP-Pt FTO
;
Heating treatment 4 ) 4l6)Q, 9;l.Qn
(300'C 5min Twice) I () ()
DSSC [
PVP( 8000) 5
PtC/~-+ BH4 + 3H2 0
Pt + B01- + 6C/- + 2H 2 + 6H+I I-V
H '
pvP-Pt ITO-PEN
ITO i
CO Ho IV
i - J-V
i!lq 6 J
(
ITO-PEN
.. ITO
20
JU
PVP-Pt
E 15
<
1 _J-Vcurve
i P
e
w
PVp.Pt ITO-PEN
3
55
E
V I
-
0.0 0.2 0 .4
-0.64 Voc 0.8
Voltage (V)
5 6 DSSCJ-V()()
PVP( 8000) 5
PtC/~-+ BH4 + 3H2 0
Pt + B01- + 6C/- + 2H 2 + 6H+I I-V
H '
pvP-Pt ITO-PEN
ITO i
CO Ho IV
i - J-V
i!lq 6 J
(
ITO-PEN
.. ITO
20
JU
PVP-Pt
E 15
<
1 _J-Vcurve
i P
e
w
PVp.Pt ITO-PEN
3
55
E
V I
-
0.0 0.2 0 .4
-0.64 Voc 0.8
Voltage (V)
5 6 DSSCJ-V()()
(; 1
(9)
(resistan )
; FF D
( citance) +12
pmax
(inductance) -12
JJVOC;
() (a) (b)
{
.7 (a) (b)
Pm Jm"Vm Jsc"1 r"FF
(i mpedance) (B)
==- =--"'=- (A)
Pin Pin
Ro
() (symmetric cell) (Nernst diffusion
(EIS) (C) ( )PVP-Pt
resistance)
(AC) (DC)j
e rna Ro
[16]
EIS fH 7(a)
( )PVP-Pt ITO-PEN
/2 SEM 10
7(b) R
20-100nm InO;
resistance) ; CPE Z' (ohm-cm') PVP-Pt
Rs : series resistance
(9) charge transfer resistance
IOnm'
Ro : Nernst diffusion resislance
(constant phase element) R"
128 22 2 2 142 29
41
(; 1
(9)
(resistan )
; FF D
( citance) +12
pmax
(inductance) -12
JJVOC;
() (a) (b)
{
.7 (a) (b)
Pm Jm"Vm Jsc"1 r"FF
(i mpedance) (B)
==- =--"'=- (A)
Pin Pin
Ro
() (symmetric cell) (Nernst diffusion
(EIS) (C) ( )PVP-Pt
resistance)
(AC) (DC)j
e rna Ro
[16]
EIS fH 7(a)
( )PVP-Pt ITO-PEN
/2 SEM 10
7(b) R
20-100nm InO;
resistance) ; CPE Z' (ohm-cm') PVP-Pt
Rs : series resistance
(9) charge transfer resistance
IOnm'
Ro : Nernst diffusion resislance
(constant phase element) R"
128 22 2 2 142 29
F;
l.
- bare ITO-PEN
- PVP-Pton ITO-PEN 13
100
14
14 3400
-
4 600 800 1000
wavelength (nm)
-OH
11 PVP-Pt ITO-PENIIUV-Vi sibie:
iTO-PEN: PVP-Pt iTO-PEN
( )PVP-Pt ITO-PEN
() PVP-Pt ITO-PEN
j ITO -PVP-
PVP-Pt:
PVP-Pt OH
12
10 iTO-PEN (a)(b)SEM
-OH
JltpvP-Pt
PVP-Pt {l
60% -
IRIl PVP-Pt ITO-PEN 550nm 75.3% ' !'IIJ
ITO-PEN 85.1% '
4.25 f.lg/ -
- 11 ' cm' (I CP-AES) FT-IR mq ~ 12
l.
- bare ITO-PEN
- PVP-Pton ITO-PEN 13
100
14
14 3400
-
4 600 800 1000
wavelength (nm)
-OH
11 PVP-Pt ITO-PENIIUV-Vi sibie:
iTO-PEN: PVP-Pt iTO-PEN
( )PVP-Pt ITO-PEN
() PVP-Pt ITO-PEN
j ITO -PVP-
PVP-Pt:
PVP-Pt OH
12
10 iTO-PEN (a)(b)SEM
-OH
JltpvP-Pt
PVP-Pt {l
60% -
IRIl PVP-Pt ITO-PEN 550nm 75.3% ' !'IIJ
ITO-PEN 85.1% '
4.25 f.lg/ -
- 11 ' cm' (I CP-AES) FT-IR mq ~ 12
16 2
-6 0
1 L
~ -40
E . ...
-20 ;;: -20 ..
.0 min
. 3 min
. 20 40 60
L80 8.09 % .
20
-0 H c-O 20 ITO-PEN
4000
\
3000 20 o 1000
wavelength (nm) E 15
SEM
2
14 - F IR 10nm;
~ 10 A PVP-Pt on ITO-PEN A
g PVP-Pt on FTO
A .. (4.2S g/cm')
E 5 A
60% ;
A
Pt FTO PVP-Pt ITO-PEN E 4
/PVP-Pt
4 -F IR
0.0 2 0.4 0.6 0.8
5
voltage (V)
5
10 Rct{ 3_70cm'
16 J-V: PVP-Pl FTO Rctf 3.70cm' ;
6_S0cm' .
PVP-Pl ITO-PEN 8.09%
EIS
15 -
16 2
-6 0
1 L
~ -40
E . ...
-20 ;;: -20 ..
.0 min
. 3 min
. 20 40 60
L80 8.09 % .
20
-0 H c-O 20 ITO-PEN
4000
\
3000 20 o 1000
wavelength (nm) E 15
SEM
2
14 - F IR 10nm;
~ 10 A PVP-Pt on ITO-PEN A
g PVP-Pt on FTO
A .. (4.2S g/cm')
E 5 A
60% ;
A
Pt FTO PVP-Pt ITO-PEN E 4
/PVP-Pt
4 -F IR
0.0 2 0.4 0.6 0.8
5
voltage (V)
5
10 Rct{ 3_70cm'
16 J-V: PVP-Pl FTO Rctf 3.70cm' ;
6_S0cm' .
PVP-Pl ITO-PEN 8.09%
EIS
15 -
Electrochemical Society 1997 , 144 (3) , 4847-4853 Hsu , w. -C.; Char Y. -H. , Durability
83% 876. [1O ]Lan, J.- L.; Wan , C.-C.; Wei , T.-C.; Hsu , test of PVP-capped Pt nanoclusters
ITO-PEN [5]Kim, S.-; Nah , Y.-c.; Noh , Y.-Y.; Jo , w. -C.; Peng, c.; Chang, Y.-H.; Ch counter electrode for highly efficiency
J.; Kim , D.- Electrodeposited Pt for C.-M. , Improvement of Photovoltaic dye-sensitized solar cel l. Progress
PVP cost-efficient and flexible dye-sensitized Performance of Dye-Sensitized in Photovoltaics: Research and
solar cells. Electrochimica Acta 2006 , Solar Cell by Post Heat Treatment Applications 2012 , 20 (1), 44-50.
51 (1 8), 3814-3819 of Polymer-Capped Nano-Platinum [1 5] Chen, L.; Tan , w.; Zhang , J.; Zh X.;
[6] Yang , C.-C.; Zhang , H. Q.; Zheng , Y. R. , Counterelectrode. In t. J. El ectrochem Zhang , X.; Li n, Y. , Fabrication of high
DSSC with a novel Pt counter electrodes Sci. 2011 , 6. performance Pt counter electrodes
using pulsed electroplating techniques. [11]Wang , G.; Lin , Xi X.; Li , X.; on conductive plastic substrate for
[1] O'Regan , 8.; Gratzel , M. , A lowcost Current Applied Physics 20 11 (1) , Wang , W. , X-ray photoelectron flexible dye-sensitized solar cells.
high-efficiency solar cell based on dye- SI47-S153. spectroscopy analysis of the stability Electrochirnica Acta 2010 , 55 (1 1) ,
sensitized colloidal Ti0 2 films. Nature [7] Li n , C.-Y.; Lin , J.-Y.; Wan , C.-C.; of platinized catalytic electrodes in 3721-3726.
1991 , 353. Wei , T. -C. , High-performance and low dye-sensitized solar cells. Surface [16] Hossain , M. J.; Tsunoyama , H.;
[2] Fang, X.; ~ T.; Guan , G.; Akiyama , platinum loading electrodeposited-Pt and Interface Analysis 2004, 36 (11) , Yamauchi , M.; Ic hikuni , N.; Tsukuda ,
M.; Kida , T.; Abe , E. , Effect of the counter electrodes for dye-sensitized 1437-1440. T. , High-yield synthesis of PVP-
thickness of the Pt film coated on a solar cells. Electrochimica Acta 20 11 , [12] Olsen, E.; Hagen , G.; Lindqui S. stabilized small Pt clusters by
counter electrode on the performance 56 (5) , 1941-1946. Dissolution of platinum in methoxy microfluidic method. Catalysis Today
of a dye-sensitized solar cell. Journal of [8]Wei , T. C.; Wan , C. C.; Wang propionitrile containing LiI1 2. solar 2012 , 183 (1) , 101-107
Electroanalytical Chemistry 2004 , 570 Poly(N -vinyl-2-pyrrolidone )-capped Energy Materials and Solar Cells
(2) , 257-263. platinum nano c1 usters on indium-tin 2000, 63 (3) , 267-273
[3] Fang , X.; Ma , T.; Guan , G.; oxide glass as counterelectrode for dye- [13] Li n , L.-Y.; Nien , P.-C.; Lee , C.-
Akiyama , M.; Abe , E. , Performances sensitized solar cells. Applied Physics P.; Tsai , K.- W.; Yeh , M.-H.; Vittal ,
characteristics of dye-sensitized solar Letlers 2006, 88 (1 0) , 103122. R.; Ho , K.-C. , Low- Temperature
cells based on counter electrodes with [9]Wei , T.-C.; Wan , C.-C.; Wang , Y.- Y.; Flexible Photoanode and Net-Like :
:
Pt films of different thickness. Journal Chen , c. -m.; Shiu, H. -s. , Immobilization Pt Counter Electrode for Improving
:
of Photochemistry and Photobiology A: of Poly(Nly 1-2-pyrrol idone )-Capped the Performance of Dye-Sensitized
Chemistry 2004 , 164 (1-3) , 179-182. Platinum Nano c1 usters on Indium-Tin Solar Cells. The Journal of Physical
[4] Papageorgiou , N. , An Iodine/Triiodide Oxide Glass and Its Application in Dye- Chemistry C 2010 , 114 (49) , 21808-
Reduction El ectrocatalyst for Aqueous Sensitized Solar Cells. The Journal of 21815.
and Organic Media. Journal of The Physical Chemistry C 2007 , 111 (12) , [14] Lan , J.-L.; Wan , C.-C.; W T.-C.;
Electrochemical Society 1997 , 144 (3) , 4847-4853 Hsu , w. -C.; Char Y. -H. , Durability
83% 876. [1O ]Lan, J.- L.; Wan , C.-C.; Wei , T.-C.; Hsu , test of PVP-capped Pt nanoclusters
ITO-PEN [5]Kim, S.-; Nah , Y.-c.; Noh , Y.-Y.; Jo , w. -C.; Peng, c.; Chang, Y.-H.; Ch counter electrode for highly efficiency
J.; Kim , D.- Electrodeposited Pt for C.-M. , Improvement of Photovoltaic dye-sensitized solar cel l. Progress
PVP cost-efficient and flexible dye-sensitized Performance of Dye-Sensitized in Photovoltaics: Research and
solar cells. Electrochimica Acta 2006 , Solar Cell by Post Heat Treatment Applications 2012 , 20 (1), 44-50.
51 (1 8), 3814-3819 of Polymer-Capped Nano-Platinum [1 5] Chen, L.; Tan , w.; Zhang , J.; Zh X.;
[6] Yang , C.-C.; Zhang , H. Q.; Zheng , Y. R. , Counterelectrode. In t. J. El ectrochem Zhang , X.; Li n, Y. , Fabrication of high
DSSC with a novel Pt counter electrodes Sci. 2011 , 6. performance Pt counter electrodes
using pulsed electroplating techniques. [11]Wang , G.; Lin , Xi X.; Li , X.; on conductive plastic substrate for
[1] O'Regan , 8.; Gratzel , M. , A lowcost Current Applied Physics 20 11 (1) , Wang , W. , X-ray photoelectron flexible dye-sensitized solar cells.
high-efficiency solar cell based on dye- SI47-S153. spectroscopy analysis of the stability Electrochirnica Acta 2010 , 55 (1 1) ,
sensitized colloidal Ti0 2 films. Nature [7] Li n , C.-Y.; Lin , J.-Y.; Wan , C.-C.; of platinized catalytic electrodes in 3721-3726.
1991 , 353. Wei , T. -C. , High-performance and low dye-sensitized solar cells. Surface [16] Hossain , M. J.; Tsunoyama , H.;
[2] Fang, X.; ~ T.; Guan , G.; Akiyama , platinum loading electrodeposited-Pt and Interface Analysis 2004, 36 (11) , Yamauchi , M.; Ic hikuni , N.; Tsukuda ,
M.; Kida , T.; Abe , E. , Effect of the counter electrodes for dye-sensitized 1437-1440. T. , High-yield synthesis of PVP-
thickness of the Pt film coated on a solar cells. Electrochimica Acta 20 11 , [12] Olsen, E.; Hagen , G.; Lindqui S. stabilized small Pt clusters by
counter electrode on the performance 56 (5) , 1941-1946. Dissolution of platinum in methoxy microfluidic method. Catalysis Today
of a dye-sensitized solar cell. Journal of [8]Wei , T. C.; Wan , C. C.; Wang propionitrile containing LiI1 2. solar 2012 , 183 (1) , 101-107
Electroanalytical Chemistry 2004 , 570 Poly(N -vinyl-2-pyrrolidone )-capped Energy Materials and Solar Cells
(2) , 257-263. platinum nano c1 usters on indium-tin 2000, 63 (3) , 267-273
[3] Fang , X.; Ma , T.; Guan , G.; oxide glass as counterelectrode for dye- [13] Li n , L.-Y.; Nien , P.-C.; Lee , C.-
Akiyama , M.; Abe , E. , Performances sensitized solar cells. Applied Physics P.; Tsai , K.- W.; Yeh , M.-H.; Vittal ,
characteristics of dye-sensitized solar Letlers 2006, 88 (1 0) , 103122. R.; Ho , K.-C. , Low- Temperature
cells based on counter electrodes with [9]Wei , T.-C.; Wan , C.-C.; Wang , Y.- Y.; Flexible Photoanode and Net-Like :
:
Pt films of different thickness. Journal Chen , c. -m.; Shiu, H. -s. , Immobilization Pt Counter Electrode for Improving
:
of Photochemistry and Photobiology A: of Poly(Nly 1-2-pyrrol idone )-Capped the Performance of Dye-Sensitized
Chemistry 2004 , 164 (1-3) , 179-182. Platinum Nano c1 usters on Indium-Tin Solar Cells. The Journal of Physical
[4] Papageorgiou , N. , An Iodine/Triiodide Oxide Glass and Its Application in Dye- Chemistry C 2010 , 114 (49) , 21808-
Reduction El ectrocatalyst for Aqueous Sensitized Solar Cells. The Journal of 21815.
and Organic Media. Journal of The Physical Chemistry C 2007 , 111 (12) , [14] Lan , J.-L.; Wan , C.-C.; W T.-C.;