BOARD PREPARATORY PART TEST-1

BPT-PT-1 (FOR SESSION 2012-13)

COURSE : VIJETA (JP)
DATE : 13-05-2012 DURATION : 1 HR. SUBJECT : CHEMISTRY MAX. MARKS : 55

GENERAL INSTRUCTIONS
All questions are compulsory.
The question paper consists of 17 questions divided into three sections A, B and C. Section A comprises
of 07 questions of one mark each, section B comprises of 06 questions of four marks each and section
C comprises of 04 questions of six marks each.
All questions in Section A are to be answered in one word, one sentence or as per the exact requirement
of the question.

There is step marking.

There is no overall choice. However, internal choice has been provided in 02 questions of four marks each
and 03 questions of six marks each. You have to attempt only one of the alternatives in all such questions.
Use of calculators is not permitted. You may ask for logarithmic tables, if required.

SECTION (A) : (1 Mark)

1. Define reverse osmosis process? [1 Mark]

2. A and B liquids on mixing produce a warm solution. Which type of deviation is shown by the given mixture
from Raoult's law ? [1 Mark]

3. Among Octahedral and Tetrahedral crystal fields, in which case the magnitude of crystal field splitting is
larger for same central metal ion and ligands? Write the relation between them ? [ + = 1 Mark]

4. (a) Give the electronic configuration of the d-orbitals of Ti in [Ti(H2O)6]3+ ion and explain why this complex
ion is coloured ? [At No. of Ti = 22].
(b) Write IUPAC name of [Cr(NH3)3(H2O)3]Cl3 [ + = 1 Mark]

5. Arrange the following carbocation in increasing order of their stability with reason.

[1 Mark]

6. Write all possible hyperconjugative structures of propene (CH3CH=CH2). [1 Mark]

7. Give reason why the following two structures I and II cannot be the major contributors to the real structure of
CH3COOCH3.

[1 Mark]

RESONANCE JPBPT1130512-1
SECTION (B) : (4 Marks)

8. (i) State Raoult's law for a solution containing volatile liquids.

(ii) Explain with suitable example the concept of maximum boiling azeotropes. [2 + 2 = 4 Marks]

9. On dissolving 19.5 g of CH2FCOOH in 500g of water, a depression of 1C is observed in freezing point of

water. Calculate the van't Hoff factor and degree of dissociation of fluoro acetic acid.
Given, Kf = 1.86 K kg mol1. [3 + 1 = 4 Marks]

10. (a) State the hybridization and magnetic behaviour of [Cr(CO)6].

(b) What are the two factors affecting crystal field splitting energy ?
(c) Write one example each of didentate ligand and ambidentate ligand. [1 + 2 + 1 = 4 Marks]

11. (A) Identify total no. of compounds which have correct direction of Inductive effect.

(i) CH3 CH2 K (ii) CH3 CH2 MgBr (iii)

(iv) (v) (vi)

(B) Define the following with an example :

(i) Enantiomers (ii) Optical diastereomers [1 + 3 = 4 Marks]

12. Determine the molarity and molality of an antifreeze solution containing 500g water mixed with 186g ethylene
glycol (C2H6O2). The density of this solution is 1.143 g/ml. [2 + 2 = 4 Marks]

OR
(a) What is meant by Chelate effect ? Give an example.
(b) Write any two Limitations (shortcomings) of valence bond theory for coordination compounds.
[2 + 2 = 4 Marks]

RESONANCE JPBPT1130512-2
13. (A) Write IUPAC name of the following compounds :

(i) CH3NHCH2 CHCH3 (ii)

|
NO2
(B) What is an electrophile. Arrange the following set of compounds in order of their decreasing relative
reactivity with an electrophile E.
(i) Toluene (ii) pCH3C6H4NO2 (iii) pNO2C6H4NO2 [1 + 1 + 1 + 1 = 4 Marks]

OR
(a) Identify in the following compounds, aromatic, non-aromatic and anti aromatic if present.

(1) (2) (3)

(4) (5) (6)

(b) Write resonance structures of CH2=CHCHO. Indicate relative stability of the contributing structures.
[ 6 + 1 = 4 Marks]

SECTION (C) : (6 Marks)

14. (i) Distinguish between the terms molality and molarity. Under what conditions are the molarity and molality
of a solution nearly the same for aqueous solutions ?
(ii) A solution of glycerol (C3H8O3 : molar mass = 92 mol1) in water was prepared by dissolving some
glycerol in 500 g of water. This solution has a boiling point of 100.42C. What mass of glycerol was
dissolved in it to make the solution ? Kb for water = 0.512 K kg mol1) [3 + 3 = 6 Marks]
15. Give one test each to distinguish between :
(i) Aqueous solution of acetaldehyde and acetone
(ii) Aqueous solution of phenol and benzoic acid.
(iii) Aqueous solution of formaldehyde and acetaldehyde.
(iv) Propan-1-ol and propan-2-ol. [1 4 = 6 Marks]

OR
(A) Identify total no. compound which contains equal CO bond length and Explain why

(i) (ii) (iii) (iv)

(B) Categorise the following molecules/ions as electrophile:

BF3, (CH3)3 N:, Cl+, CH3C+ = O, NO+2, CH+3, NH4+, H2O, H+, :CCl2
(C) Identify total no. of hyperconjugative structure of the following compound.

[2 + 3 + 1 = 6 Mark]

RESONANCE JPBPT1130512-3
16. (a) At 300 K the value of osmotic pressure of a 3.1% (w/v) solution of non-electrolyte compound is found
equal to for 4.832 atm. Determine the formula mass of compound.

(b) State Henry's Law and mention its two important applications.

(c) Which of the following solutions has higher boiling point and why ?

0.1M NaCl and 0.1 M Glucose. [3 + 2 + 1 = 6 Marks]

OR

(a) (i) Define relative lowering of vapour pressure.

(ii) Write its formula for a solution of non-volatile solute in a volatile solvent.

(b) The vapour pressures of pure liquids A and B are 450 mm and 700 mm of Hg respectively at 350K.
Calculate the composition of liquid mixture if total vapour pressure of mixture of A and B is 600 mm of
Hg. Also find the composition of the mixture in vapour phase. [1 + 1 + 2 + 2 = 6 Marks]

17. Write down the IUPAC name for each of the following complexes and indicate the oxidation state, and
coordination number of central atom, and magnetic moment of the complex :

(i) K [Cr(H2O)2(C2O4)2]

(ii) K4[Mn(CN)6]

(iii) [Co(NH3)5Cl]Cl2 [2+ 2 + 2 = 6 Marks]

OR

(A) Explain as to how the two complexes of nickel, [Ni(CN)4]2 and [Ni(CO)4] have different stuctures but do
not differ in their magnetic behaviour (Ni = 28).
(B) [Fe(bipy)3] (ClO4)3 complex has a magnetic moment of 1.7 BM. Is it an inner orbital or outer orbital
complex? Explain and also write the hybridization of central metal atom. (Using VBT)

[3 + 2 + 1 = 6 Marks]

RESONANCE JPBPT1130512-4