CONFIDENTIAL

LECTURERS NAME : NUR KHAIRANI KHALID

PROGRAM : DIPLOMA IN PHARMACY
COHORT : 28
COURSE CODE : PABC 111.3
SUBJECT : PHYSICAL CHEMISTRY
DATE (EXAM) : 11/7//2017
YEAR : 1
SEMESTER : 1
TOTAL NO. OF QUESTIONS : 30
SET : 1 (ONE)
TYPES QUESTION : MEQ SUMMATIVE

DATE SUBMISSION TO EXAM PHARMACY COMMITTEE :

FIRST REPEAT CODE STATUS LEVEL

DPH-NKK NEW

PART B Total 60 Marks

Answer ALL the questions in the answer sheet provided.

QUESTION 1:
i. The element boron and sulfur combine with fluorine to form the compounds BF3 and SF6
that do not obey the Octet Rule.
a) Draw the Lewis Structure for both BF3 and SF6 (6 marks)
b) State how many bond pair and lone pair in both BF3 and SF6 (2 marks)
c) Predict the shape for both BF3 and SF6 (2 marks)

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ii.

Refere to the diagram above to answer question a to g

a) What is the normal melting point of this substance? ______

b) What is the phase of a substances at 2.0 atm and 100 oC ? _________
c) What is the phase of a substances at 0.75 atm and 100 oC ? _________
d) What is the phase of a substances at 0.5 atm and 100 oC ? _________
e) What is the condition of the triple point of this substance?
T = ______, P = _______
f) If this substance was at a pressure of 2.0 atm, at what temperature would it melt
? _______
g) Sketch the diagram and label which part is solid, liquid and gas?
(10 marks)

Question 2

i. a) Whats the empirical formula of a compound containing 18.7% lithium, 16.3%

carbon, and 65.0% oxygen? (7 marks)

b) If the molar mass of the compound in problem is 73.8 g/mol, whats the chemical
formula? (3 marks)

ii. a) Calculate the pOH of 0.02 M HCl (3 marks)

b) Calculate the pH of 0.05 M NaOH (3 marks)
c) Define acid and base using the Arrhenius definition. (2 marks)
d) Give the example of strong acid and strong base (2 marks)
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Question 3
i.
Calculate
a) The molarity of a solution containing 11.7 g of NaCl in 250 cm3 solution
(3marks)

b) The molality of a solution containing 159.0 g of K2Cr2O7 (3 marks)

c) The mole fractions of C2H5OH and H2O in a solution prepared 1.70 g of C2H5OH
in 16.0 g of water (4 marks)

ii An voltaic cell is constructed by combining magnesium (Ferum II) and copper (Al)

a) Draw the Voltaic cell and label the anode and cathode. (5 marks)
b) Indicate the direction of electron flow on the diagram. (1 mark)
c) Write the half reactions that occur in the two electrode compartments. (2 marks)
d) Write the overall equation of the cell. (2 marks)

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