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Article history: Drying biomass as fuel in a combustion process can increase the combustion efciency, reduce pollution
Received 21 August 2012 and improve operation. On the other hand, drying biomass is an expensive process that requires huge
Received in revised form capital investment and energy input. The difculty of removing moisture from biomass is affected by
27 February 2013
many factors such as the moisture content and the size of the solid particles. The level of drying is
Accepted 2 March 2013
Available online 27 March 2013
therefore a very important parameter, which strongly inuences the economies of the utilization of
biofuel. This study utilizes a mathematical model that incorporates material and energy balances, heat
transfer and drying kinetics to determine the optimum drying level of biomass. Drying kinetic based
Keywords:
Biomass drying
upon the Ficks second law of diffusion is used in the model to determine the energy and capital ex-
Combustion penditures for the drying process. Case studies of wood chips drying are presented to demonstrate how
Drying kinetics the thickness of wood chips affects the optimal drying intensity and the overall economics of the process.
Modeling 2013 Elsevier Ltd. All rights reserved.
Optimization
1. Introduction Most of the latest biomass power plants are integrated with
drying facilities. Depending on the drying technology and the
Using biomass as a renewable energy source is attracting more properties of the biomass, the drying time could be as long as a
and more attention nowadays due to the concerns of global month [4] by using hot air or as short as a couple minutes with high
warming and the worry of fossil fuel depletion. However, not all the temperature ue gas [5]. While biomass with moisture levels of
biomass is suitable for direct combustion except when properly 55e65 wt% can sustain combustion, the optimum moisture content
dried. is 10e15 wt% [6]. Brammer et al. showed the importance of drying
In the old days, biomass such as woods or rice straws was dried of biomass for small-to-medium scale biomass gasication plants
naturally before they were burned. Recently, due to the high- for the production of heat and power, and veried that high levels
energy cost and environmental concerns, some organic wastes of moisture content within feedstock not only lowers the perfor-
with high moisture contents such as empty fruit brunch (EFB), mance of the system but also deteriorates the quality of the product
sludge or microalgae are being used as fuel. These highly moist gas [7].
biomasses have to be mechanically and/or thermally dried before The performance of a combustion process can be enhanced by
they can be burnt. Evidence has shown, drying biofuel prior to the removal of moisture from the feedstock. Three different drying
combustion can increase boiler efciency, lower air emissions and methods namely steam drying, ue gas drying and vacuum drying
improve boiler operation [1]. were studied by Andersson et al. [8] in a process where the drying
High moisture content reduces the combustion temperature and pelletizing of biofuel is integrated to pulp mill. Their study
causing incomplete combustion and undesirable reaction products. showed the possibility of energy recovery and reduction in CO2
In addition, a biofuel with high moisture content requires a large emissions compared to stand-alone pellets production. So far the
amount of auxiliary fuel to make it combustible [2]. Some data on drying of biomass feedstock before combustion processes offers a
how moisture content affects the boiler efciency and other key lot of potential benets related to increased boiler efciency and
combustion parameters such as ame temperature were reported lower ue gas emissions. The potential benets of the drying
by Voima et al. [3]. operation are achieved at a cost as drying is an energy and capital
intensive process. The energy cost of the drying process can be
reduced by utilizing low-grade waste heat [9] but at the same time
increasing the size of dryer makes it too bulky and expensive. Le
* Corresponding author. Tel.: 852 2358 7137; fax: 852 2358 0054.
E-mail addresses: tgaa@ust.hk (T. Gebreegziabher), keoyedun@ust.hk
Lostec et al. suggested that heat recovery systems are the most
(A.O. Oyedun), kehui@ust.hk (C.W. Hui). energy efcient and economical solutions for drying wood chips,
0360-5442/$ e see front matter 2013 Elsevier Ltd. All rights reserved.
http://dx.doi.org/10.1016/j.energy.2013.03.004
68 T. Gebreegziabher et al. / Energy 53 (2013) 67e73
and absorption heat pumps can be used economically when the set LHVs 18; 648 210X3 (2)
point temperature of the drying air is below 60 C [10].
In the literature, discussions on how the optimum level can be where LHVs: is the lower heating value of moist wood (kJ/kg) and
achieved are rare. The trade-off between the drying level, dryer X3: is the moisture content of dried wood (wt%)
costs, energy inputs and boiler efciency is seldom explicitly This estimation is very close to the data provided by EUBIA [11].
studied. The purpose of this paper is to perform this trade-off using In Fig. 2, when moisture content is as high as 90%, the combustion
a mathematical model. The model can determine the operating of wood in theory will not generate any heat value because the high
conditions such as the drying temperature, with the consideration moisture content makes the wood non-combustible. Some indus-
of the size of the biomass feedstock. trial boilers restrict the minimum heating value of biofuel to be
In this work, a simplied biomass drying plant, as shown in above 15,000 kJ/kg (which is around 17 wt% of moisture content in
Fig. 1, is used to illustrate how the drying level of biomass can be Fig. 2) to guarantee the quality (e.g. ame temperature) of the
optimized and how it affect the protability of the overall process. combustion [12]. However, if auxiliary fuel such as coal is added to
In this process, steam is used to heat up the air stream to a tem- the combustion, burning biofuel at higher moisture content is
perature Ta,2 before entering a hot air dryer (HAD). Wood chips or feasible.
sawdust and hot air are mixed and leave the dryer at temperature
Ta,3. The objective is to design and optimize the drying process, by 3. Process models
taking into account the product value (reected by the lower
heating value of the dried wood chips), operating cost (the steam The process shown in Fig. 1 consists of two processing units,
cost used for preheating the air) and capital investment of the HAD namely an air heater and a hot air dryer. Material and energy bal-
and the steam heater. To do this, material and energy balance ance models of these units are discussed below.
models of the air heater and the dryer are developed. The sizes and
costs of these two processing units are also estimated. 3.1. Air heater
Ws X2 X3 WG Y3 Y2 (12)
Ws Hs;3 Hs;2 Ws X3 Hw;3 X2 Hw;2
WG Hda;2 Hda;3 WG Y3 Hv;3 Y2 Hv;2 (13)
Hs;3 Hs;2 Cpdw Ts;3 Ts;2 (14)
Hw;3 Cpw Ts;3 Tref (15)
Hw;2 Cpw Ts;2 Tref (16)
Hda;2 Hda;3 Cpda Ta;2 Ta;3 (17)
X Xe
3.2. Dryer model MR (21)
Xo Xe
In the hot air dryer, the solid contacts hot air directly. Heat is The diffusion equation for which the diffusion potential is the
transferred from the hot air to the solid and moisture that is carried moisture content, MR and under the assumption of negligible
by the solid is vaporized. The evaporation takes away a signicant shrinkage can be expressed using Ficks second law as in Eq. (22).
amount of heat that is transferred to the solid. The dryer is
continuously fed and is assumed to be in steady state. Eqs. (12)e vMR h i
V Deff VMR (22)
(20) describe material and energy balances of the hot air dryer. vt
70 T. Gebreegziabher et al. / Energy 53 (2013) 67e73
The general solution of the above equation is in the form of The equilibrium moisture contents Xe at different drying tem-
Eq. (23). peratures are regressed from the drying data as in Eq. (29).
!
Xe 60:92 0:165 T (29)
8 X
N
1 2n 12 p2 Deff
MR exp t (23)
p2 n1 2n 1 2 4L2 A zero or a very small value of MR could cause numerical error
when logarithmic value of MR is calculated. To avoid MR from
where n is a positive integer, t is the drying time (s) and L is the half acquiring a value of zero at the end of the experiment, a small
thickness of the sample (m) and Deff is the effective moisture number is added to the numerator. Eq. (21) is modied to Eq. (30) to
diffusivity (m2 s1). For a very long drying time the rst term of the make it more suitable for an optimization problem.
expansion can be used to predict MR. Hence,
X Xe 0:0000001
" # MR (30)
Xo Xe
8 p2 D eff t
MR exp (24)
p2 4L2 The dependent variable in the simplied Ficks equation, i.e the
moisture ratio, MR, was extracted from the drying data of Fig. 3 and
And it follows that, is plotted in Fig. 4.
To obtain the slope (k) of Eq. (26), ln (MR) is plotted against the
8 drying time (t) and is shown in Fig. 5. The curves at different drying
ln MR ln kt (25)
p2 temperatures show constant slope except when the maximum
temperature is reached (i.e., equilibrium is approached). The nal
p2 Deff point was not included in the regression because in a practical
k (26) design the nal moisture content should not be too close to its
4L2
equilibrium value to avoid high energy and capital investment.
The effective diffusion coefcient is typically determined from With the k values (the slopes) regressed from Fig. 5, the Deff
the slope (k) of the experimental data plot of ln (MR) versus drying values can be calculated using Eq. (26). To do this, the value of L in
time (t) as in Eq. (25). The temperature dependency of the diffu- meters has to be known. For the optimization problem a linear
sivity can be represented by an Arrhenius model as in Eq. (27). equation of Deff as function of temperature, T (K), was obtained as
shown in Eq. (31) from the set of drying data provided by Chen et al.
Ea [15].
Deff Do exp (27)
RT
1 1
ln Deff 14:716 2045:41=T (31)
where R is the universal gas constant (8.314 J mol K ), Ea is the
activation energy (kJ mol1), Do is the Arrhenius factor (m2 s1) and Based on the dryer model, once the drying temperature is given,
T is the absolute temperature in Kelvin. Both kinetic parameters Ea the corresponding Deff value can be estimated by Eq. (31). If we
and Do can be estimated from the curve of Deff versus 1/T of the assume the solid and air are well mixed inside the dryer, the drying
natural logarithmic form of Eq. (28). temperature will be equal to the outlet temperature of the solid
(Ts,3). With the Deff together with the thickness of the solid (L) and a
Ea 1 drying time, the moisture ratio (MR) at the outlet of the dryer can
ln Deff ln Do (28)
R T be determined using Eq. (24).
One possible method of determining the parameters in Eqs.
(24)e(28) is by making use of experimental drying data. A set of 3.3. The air heater cost
drying data of poplar sawdust obtained by Chen et al. [15] is used in
this study. The moisture content data of the sample as function of Once the area of the heat exchanger is known, Eq. (32) is used to
time at various drying temperature is given in Fig. 3. estimate the heat exchanger cost, Chtr ($/yr).
1
0.9
0.8
0.7
Moisture Ratio
0.6 60C
0.5 70C
0.4 80C
0.3 90C
0.2
0.1
0
0 100 200 300 400 500 600
Drying Time (sec)
Fig. 3. Drying curves of poplar sawdust at different drying temperatures [15]. Fig. 4. Moisture ratio versus time of poplar sawdust.
T. Gebreegziabher et al. / Energy 53 (2013) 67e73 71
Table 1
Design parameters.
Parameters Value
Feed rate of wood chips, Ws,1 (kg/h) 5000
Moisture ratio of the wood feed, X1 1
Temperature of the wood feed, Ts,2 ( C) 25
Pressure of the air feed, Pa,1 1 atm or 101,325 Pa
Temperature of the air feed, Ta,1 ( C) 25
Relative humidity of the air feed, RH1 (%) 50
Temperature difference of air and solid 5
at the dryer outlet, DT ( C)
Air heater cost, Chtr ($/yr) 500 100 A0.8
Dryer cost , Cdyr ($/yr) 5000 5000 V0.6
Steam cost, CLP ($/kW) 0.1
Heat value of wood ($/kW) 0.05
Specic heat of air, Cpda (kJ/kg-C) 1.006
Specic heat of wood, Cpds (kJ/kg) 1.2566
Fig. 5. ln (MR) vs drying time of poplar sawdust. Specic heat of water vapor, Cpv (kJ/kg-C) 1.89
Specic heat of water, Cpw (kJ/kg-C) 4.186
Latent heat of water, LHw (kJ/kg-C) 2270
Latent heat of LP steam, LHLP (kJ/kg) 1999
Chtr ahtr bhtr Achtr (32) Size of the wood, L (m) 0.0005
Annual operation time, top (h) 2000
Assuming the density of the moist wood (rs) is 500 kg/m3, and no Wood feed Dried wood
shrinkage of the wood occurs during the drying process, the vol- Wood temperature, Ts ( C) 25 37
ume of the wood inside the dryer Vs (m3) for the feed rate of wood Flow rate of wood, Ws (kg/h) 5000 3025
at 5000 kg/h is given as Moisture content, x (wt%) 50 17
Moisture ratio, MR 1 0.21
Flow rate of dry wood, Wds (kg/h) 2500 2500
5000
Vs t 3600 (33) Flow rate of moisture, Ww (kg/h) 2500 525
500 Enthalpy of dry wood (kJ/h) 78,538 95,042
Enthalpy of moisture (kJ/h) 261,625 66,498
Assuming the dryer has 85% space for the air ow and 15% for Enthalpy of moist wood (kJ/h) 340,163 161,540
the solid ow, the volume of the dryer becomes:
Vs
Vdyr (34)
0:15
Accordingly, the dryer cost was calculated by Eq. (35).
Table 3
cdyr
Results of costs and annual prot.
Cdyr adyr bdyr Vdyr (35)
Heat exchanger
Air temperature, Ta,2 ( C) 62
3.5. Operating cost (steam cost) Log mean DT 75
U (W/m2 K) 10
In this study, we consider steam cost as the only operating cost. Q (kJ/h) 6,436,135
Other operating costs such as powering the blower, pumps, etc., are Q (kW) 1788
Area (m2) 2383
neglected. Hence the operating cost related with steam consump- Heat exchanger cost ($/yr) 50,821
tion for yearly operation time (top) in hours can be calculated as in Energy requirement for drying
Eq. (36). Annual operation hours (h/yr) 2000
Steam cost ($/kW) 0.1
Cop CLP Qhtr top =3600 (36) Operating cost for drying ($/yr) 357,563
Dryer
Air temperature, Ta,3 ( C) 42
3.6. The product value Air relative humidity, RH3 (%) 60
Residence time (h) 0.11
% of free volume for air 0.850
When wood is subjected to drying the caloric value of the wet Size of dryer (m3) 6.2
wood chips is expected to increase with decreasing moisture con- Cost of dryer ($/yr) 19,891
tent based on Eq. (2). It is evident that wood chips having high Heat value of dried wood
LHV of dried wood (kJ/kg) 15,000
caloric value will have high cost. Assuming the value of dried
Total heat value of dried wood (kJ/h) 45,376,316
product is a function of the LHV, the moisture content and a cost Total heat value of dried wood (kW) 12,604.53
factor Cs ($/kW), the corresponding monetary gain upon caloric Heat value of wood ($/kW) 0.05
value enhancement of wood is calculated using Eq. (37). Heat value of wood ($/yr) 1,260,453
Total equipment cost ($/yr) 70,713
Total operating cost ($/yr) 357,563
Cs Ws 1 X3 LHV
Cs top (37) Total prot, AP ($/yr) 832,178
3600
72 T. Gebreegziabher et al. / Energy 53 (2013) 67e73
Table 4
Case study results.
4. Objective function optimum solution. Results of these cases are shown in Table 4. The
annual prot reduces to 616,489 $/yr when the size increased to
Maximizing the net annual prot (AP) of the process was set as 0.005 m mainly due to the increase of the dryer cost. When L is
the objective function of the cost optimization problem which is getting larger (0.05 m), the process generates negative benet
calculated by Eq. (38). of 1,367,214 $/yr. This was due to the signicant increases of
dryer and energy costs. We also noticed that in these three cases,
AP Cs Chtr Cdyr Cop (38) the LHVs remains at the minimum required value of 15,000 kJ/kg.
This indicates that the protability of the process may be
5. The base case improved by relaxing LHV value. The results of Case 4 shown in
Table 4 agree with this expectation and the annual prot increases
The base case of this study is to design a drying process to to 1,019,908 $/yr at an LHVs of 9698 kJ/kg. These results give us an
process 5000 kg/h of moist wood chips with moisture content of indication that if we could accept lower LHVs of the fuel, we may
1 kg/kg (dB) using a hot air dryer. Air to the dryer is preheated by a obtain higher heat value from its combustion. However, as earlier
LP steam at 120 C using an air heater. The design parameters used discussed, burning low LHV biofuel could cause environmental
for the base case are summarized in Table 1 while the process and or operational problems. In fact, this is being done in quite a
constraints applied to the base case include; few developing countries that allow small scale biofuel power
plant with direct combustion of biofuel with high moisture con-
1. Air preheated temperature, 60 C Ta,2 110 C tent. Nevertheless, moist biofuels can be blended with another
2. Relative humidity of the exhaust air, RH3 60% auxiliary fuel such as coal or other high heat value solid wastes
3. The LHV of the nal product, LHV 15 MJ/kg such as plastics for avoiding operational problems during
4. Residence time > 100 s combustion.
The overall annual prot dened in Eq. (38) was maximized by 8. Conclusions
changing the feed rate of air (Wa,1), the air preheat temperature (Ta,2),
the drying time of the solid (t) and the temperature and relative A mathematical model of a drying process of wood chips is used
humidity of the exhaust air (Ta,3 and RH3). Excel 2010 Standard GRG to optimize the design and operation of the process. The model
Non-linear Solver was used to solve the optimization problem. took into account material and energy balances of individual pro-
cessing units. With the integration of drying kinetics, the model
6. Result of the base case allowed a proper trade-off among the operating cost, capital in-
vestment and product value. The optimum solutions indicated that
The results of calculations for the base case are presented in the size of the wood chips strongly affects the economy. When the
Tables 2 and 3. size of the wood chips become too large, the drying time becomes
In the optimum design, air is preheated to 62 C before con- too long thus signicantly increases the dryer size and energy cost.
tacting the solid inside the dryer. The outlet temperatures of the air Up to a certain size, the drying plant becomes unprotable. Another
and solid stream are 42 C and 37 C with the relative humidity of observation is that if a lower heating value of the dried wood chips
the exhaust gas at 60% (at the maximum value). The optimization is acceptable, the process will be protable. Therefore, in order to
tends to push the RH value of the exhaust gas to the highest to satisfy the constraint of minimum heating value without upsetting
reduce the ow rate of the feed air. So that the moisture content of the environment and/or operation of the combustion process when
the exhaust air does not become too high or over saturated, setting drying too large or too wet biomass, auxiliary fuel is one of the
a maximum limit of RH3 is necessary. In an actual plant, the outlet options to be considered.
air humidity can be controlled by recycling parts of the process air.
The optimum solution of the base case indicated that the plant is Acknowledgment
protable with the moisture level of the dried wood at 17 wt% the
LHVs is at the minimum level 15,000 kJ/kg. The residence time is The authors would acknowledge the nancial support from the
0.11 h. The low operating temperature of the dryer was due to the UGC-Infra-Structure Grt. (FSGRF13EG03), the Studentship from
small value of L (0.0005 m). EVNG program and the International Studentship from the School
of Engineering at HKUST.
7. Case studies
Nomenclature
The value of L is set to 0.005 m and 0.05 m (Case 2 and Case 3)
to examine on how the thickness of the wood would affect the a capital cost parameter
T. Gebreegziabher et al. / Energy 53 (2013) 67e73 73