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OP OQ
(i)
PU QR R
In PUT = STQ (vertically opposite angle)
U
P = Q = 90
1 T
AA similarity O 2
Q
P
PUT ~ QST
PU QS
(ii)
PT QT S
From equation (i) and (ii),
QS = QR (given)
PU QT PU OQ
PT OP
OQ OT OQ
OT OP OP
OP OQ OP OT = OQ OT OP OQ
2OP OQ = OT (OP + OQ)
2 1 1
OT OQ OP
2. Answer (1)
In XAB, XDC and XYZ 5 Z
XAB ~ XDC ~XYZ 3
2
1 2.5 1 C 5
AB CD YZ 5 B
XA 2 XD 5 XY 10 2
Area of rectangle ABCD = Area of XDC Area of XAB X 2 A 3 D 5 Y
1 5 1 21
= 2 5 2 2 1 =
2 4
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2 Hints & Solutions KVPY(SA)
3. Answer (3)
A
MLKJINM Hexagon
1 + 2 + 3 + 4 + 5 + 6 M L
6 (sides) D E
1 2
= (n 2) 180
N 5 3 K
x + 28 + 2x 10 + 2x 5 + x + 50 + 2x 30 + x + 30 = 720
6 4
9x + 63 = 720 B C
I J
x = 73
3 + 5 F
2x 5 + 2x 30 = 4x 35
= 4(73) 35
= 292 35
= 257
ANFK Quadrilateral
A + F + 3 + 5 = 360
A + F = 360 257 = 103
4. Answer (3)
BA | | ED | | GF and DC | | EF B A
ABC : EFG = 3 : 2 E D y
BCD : DEF = ? x
x z
Correspondence
angle x
C
Z X x Correspondence
=1:2 G F angle
1 3 3 = 3
6. Answer (3)
x2 + y2 = 4y2
60 2y
x 3y y
Now, perimeter equal to
30
x + y + 2y = 15 + 5 3 x
3y y 2y 15 5 3
y = 5 cm
Hypotenuse = 10 cm
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KVPY(SA) Hints & Solutions 3
7. Answer (4)
OD AD, OC AC, OC = OD and OA is common
D
D and C = 90
r
OAD OAC (R-H-S)
O
A is bisect
r
OAD
OD C
sin
2 OA
A B
OA = r cosec
2
OAB
OB
sin =
OA
OB = r cosec sin
2
8. Answer (1)
3
n 2
n 1
9 2 27n 1
m 3
(3 2) 729
n 2
33
(32 )n1 3n 33n 1
3 3m 8 36
3 2 n n 3 2 33 n 1
3m
3 8 36
3 3n (3 1)
2
1
3 3m
8 36
1 1
3m 3n
3 36
3m 3n = 6
2
6
mn=
3
mn=2
9. Answer (3)
1 50
If x
x 7
1
Put x = 7 or
7
1
x=7 x=
7
700
1
7700 > 700 7 700
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4 Hints & Solutions KVPY(SA)
f ( x ) { x } x 1 x 2 16
3 3
1
Now we see f x f ( x ) x R
3
1
f(x) is periodic function with period .
3
12. Answer (2)
dh
100 km/hr (constant)
dt
3
Height of the plane after 3 min = 100 = 5 km
60
h
A 2r 2
h r
dA d h
2r 2
dt dt h r
dh dh
(r h ) h
dt dt
2 r 2 2
(r h )
2r 3 dh
2
(r h ) dt
200r 3
(r h )2
13. Answer (3)
a
a a 2
BD = OM =
2 2 m B
a
= 2a a
2
OB2 = OD2 + (BD)2
A R C
a2
R2 = 2a2 a
2 a
a
2
5
R = a O a D
2
2
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KVPY(SA) Hints & Solutions 5
14. Answer (1)
A B C
800m 760m
500m 495
2000m 1900m 1881
119
= = 11.9 metres
10
15. Answer (2)
1 1
1 h(2 x h )
(1 2 xh h 2 ) 2 2
1 3
h 1 3 5 3
2 2 2
1 (2 x h ) h (2 x h )2 h (2 x h )3
2 2 1 246
1 1
1 xh (3 x 2 1)h 2 (5 x 3 3 x )h3
2 2
1
3 2
P3(x) = coefficient of h in (1 2hx h ) 2
1
= (5 x 3 3 x )
2
1
P3(10) = (5000 30) 2485
2
16. Answer (2)
d2x x
Dimension 2 M1L1T 4
dy 2 y
17. Answer (1)
18. Answer (4)
dk 1
As constant means P = F.v constant so F
dt v
19. Answer (1)
Using conservation of mechanical energy
(KE + PE) At earth surface = (KE + PE) At maximum height
1 GMm0 GMm0
mu 2
2 R R H
Ve 2GM
u , Ve =
2 R
H = Maximum height, m = Mass of particle
R
H
3
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6 Hints & Solutions KVPY(SA)
Fall in temperature 1 2
0
Time 2
1 2 1 2 1 2
2 1 2 2 2 3
T1 < T2 < T3
28. Answer (4)
29. Answer (1)
Momentum change vertically downward (MgT).
30. Answer (1)
31. Answer (1)
Charge, Q = It
= 4.825 2000
= 9650 C
Amount of NaOH formed by 1 F (96500 C) = 40 g (1 mole)
Amount of NaOH formed by 96500 C = 4 g
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KVPY(SA) Hints & Solutions 7
32. Answer (2)
PbI2
Pb
2
2I
s 2s
Pb2 2NO3
Pb(NO3 )2
0.2 M 0.2 0.4
Ksp = (s + 0.2)(2s)2
Ksp = 0.2 4s2
K sp
s
0.8
33. Answer (2)
N(SiH3)3 Planar (Due to back bonding)
Me3N Pyramidal
(SiH3)3P Pyramidal
34. Answer (2)
Due to inert pair effect, Pb(IV) is oxidising
35. Answer (3)
Due to high acidic strength of Ph-SO3H, its Ka value is large. So, pKa value is small.
36. Answer (3)
37. Answer (1)
38. Answer (3)
Molarity = 3 M
density = 1.25 g/ml of solution
Let V = 1 L
mass of solution = 1250 g
nsolute
Now 3 M =
1L
nNa2S2O3 = 3; msolute = 474g
nNa+ = 6; nS 2 = 3; msolvent = 0.776kg
2 O3
6 mol 3 mol
mNa+ = = 7.73 m; mS O2 = = 3.86 m
0.776 kg 2 3 0.776kg
39. Answer (2)
8
Light energy emitted per second = 150 = 12J
100
hc
Energy of 1 photon = = 44.13333 1020 J
12
Number of photons emitted per second = = 27.191018
44.13333 1020
40. Answer (4)
2 3 4 6 7
MnCl2 < Mn(OH)3 < MnO2 < K 2MnO4 < KMnO4
41. Answer (2)
Order of IE1 in second period
Li < B < Be < C
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8 Hints & Solutions KVPY(SA)
In case of O2
2
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KVPY(SA) Hints & Solutions 9
62. Answer (1)
x+y=4z
x2 + y2 = 6 z2
2xy = (x + y)2 (x2 + y2)
= (4 z)2 (6 z2)
= 2z2 8z + 10
xy = z2 4z + 5
Quadratic equation whose roots are x, y
t2 (x + y)t + xy = 0
t2 (4 z)t + z2 4z + 5 = 0
as x, y are real
(4 z)2 4(z2 4z + 5) 0
3z2 8z + 4 0
(3z 2) (z 2) 0
2
z2
3
2
Similarly, x, y ,2
3
63. Answer (3)
R 2 R 2 ( A1A4 )2
cos108 = y
2R 2
(A1A4)2 = 2R2 (1 cos108) A4 A3
2
= 4R2 sin254 A2 Rei where, =
10
A1A4 = 2R sin54
x
Similarly, A1 (R,0)
A1A2 = 2R sin18
A1A4 A1A2 = 2R[sin54 sin18]
= 2R 2 cos36 sin18
5 1 5 1
= 4R
4 4
=R
64. Answer (4)
Let,
f(x) = x 1 9 x
Domain x [1, 9]
f(1) = 2 2 f(x) = 0 x=5
f(9) = 2 2
f(x) x for x = 5, 6, 7, 8, 9
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10 Hints & Solutions KVPY(SA)
= 14580
66. Answer (1)
The range of one bounce is
2 u cos u sin
R
g
After impact vertical component becomes V = eusin then range of second bounce is
2 u cos eu sin
R
g
R eR
V = 45 ml
72. Answer (2)
m. eq. of NaOH = 0.11225.6 = 2.8672
eq. of NaOH = 2.867210-3
eq of KH2PO4 = 2.867210-3
mol. of KH2PO4 = 2.867210-3
Mass of KH2PO4 = 2.867210-3136
= 0.38993
0.38993
% purity = 100
0.492
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KVPY(SA) Hints & Solutions 11
73. Answer (2)
SO2Cl2 (g)
SO2 (g) Cl2 (g)
Initial P 0 0
At t = 90 min P P P P
P Kt
log
P P 2.303
1 2.2 10 5 90 60
log
1 2.303
1
1.126
1
= 0.1119
% dissociation of SO2Cl2 = 11.2%
74. Answer (2)
0.42 = a T3
a = 0.42/(20)3
20
Cp,m
Sm =
0
T
dT
20
aT3
=
0
T
dT
a 3 20
= (T )0
3
a
= (203 0)
3
Sm = 0.14
75. Answer (1)
1, 2 and 1,4 addition of conjugated diene.
76. Answer (4)
77. Answer (1)
Per molecule of acetyl CoA yields 12 ATP molecules through Kreb cycle.
78. Answer (4)
Initiation of sprouting in potato tuber occurs by ethylene.
79. Answer (4)
The amount of carebrospinal fluid in the cranial cavity is 140 mL, dopamine cure parkinsons disease. The reflex
arch which is made up of two neurons is known as monosynaptic reflex arc.
80. Answer (2)
Mullers cells occur in Retina.
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12 Hints & Solutions KVPY(SA)
4 5 ;
8 2 5
5 2 5 2
(GM )2 2
= = -4
AM
2. Answer (1)
bx2 + 2ax + c = 0 c a
bx2 + 2cx + a = 0
let be common root
2b + 2 a+ c = 0 ...(i)
2b 2c a = 0 ...(ii)
Subtract equation (ii) from (i), we have
2(a c) + c a = 0
(2 1)(a c) = 0 = 1/2
1
Now , put in (i) we have
2
b
ac 0 b + 4a + 4c = 0
4
3. Answer (1)
g(x) = 1 {x}
1 x 0
f (x) 0 x 0
1 x0 V x
0 {x} < 1 0 < g(x) 1
f(g(x)) = 1
4. Answer (2)
3 B
tan1
5
3
tan() = 4h
5
tan tan 3
A
1 tan tan 5
h
4h h
0 P
40 40 3 40 m
4h h 5
1
40 40
h = 10, 40
4h = 40, 160
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KVPY(SA) Hints & Solutions 13
5. Answer (3)
A B C D 360
So, all small four sections of circle will combine and give complete circle.
22
So, area of unshaded part = r 2 = 72 = 154 cm2
7
1
area of ABCD = AB CD height
2
1
= 18 32 14
2
= 50 7
= 350 cm2
So, area of shaded part = 350 154 = 196 cm2
6. Answer (3)
Points of intersection of y2 = x and x2 = y are (0, 0) and (1, 1).
Equation of line passes through (0, 0) and (1, 1) is y = x or x y = 0. On comparing with lx + my + n = 0
we have l =1, m = 1, n = 0
l+m+n=0
7. Answer (1)
f(x) = x3 + sinx
f'(x) = 3x2 + cosx 0
f(x) is one-one onto function
8. Answer (4)
(3C3 + 4C3 + 5C3 + 6C3 + 7C3) 4 + 8C3 2 = 392
9. Answer (1)
Median divides triangle in two equal area of triangles. If AD is median.
ar(ADB) = ar (ADC) (I)
Let X be any point of AD A
from BXC, XD is also median.
So, ar(BDX) = ar(CDX) (II)
from (I), ar (ADB) = ar(ADC) X
ar(BDX) + ar(AXB) = ar(CDX) + ar(AXC)
ar(AXB) = ar(AXC) B D C
So, X will lie on the median.
10. Answer (1)
f (x) 6 x2 f (x) 4 x2 2
| f x 8 x | | f x | | 8 x |
Then f(x)8(x) 0
As we can see that 4-x2 0 and f(x) 0
f(x) 0
8(x) 0
4 x2 0
x2 4 0
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14 Hints & Solutions KVPY(SA)
N M
B C
D
N M 90 , BD=DC and DN=DM
So, DNB DMC by RHS congruence criteria
So, B C (By C.P.C.T.)
So, ABC is an isosceles triangle.
12. Answer (2)
a2 a 2 = 0 a = 2, 1
a2 4=0 a= 2
a2
3a + 2 = 0 a = 1, 2
For a = 2 this is identity become equation in x.
13. Answer (4)
2
x 1 32 2.3. x 1
2
x 1 22 2.2. x 1 1
2 2
x 1 3 x 1 2 1
x 1 3 x 1 2 1
x 1 3 x 1 2 1
1 = 1, but for x 1 , x 1
i.e., x [1, )
14. Answer (4)
15. Answer (4)
12 sin 2 x sin 2 x 6 sin 2 x sin 4 x 1 4 cos 2 2 x
1 cos 2 x
2 cos 2 x 2 sin 2 2 x 4 1
2
=
6 sin 2 x 2 sin2 x 1 sin 4 x 1 4 cos2 2 x
2cos 2 x 2 sin 2 x 2 2cos x 1
2 2
=
6 sin 2 x cos 2 x sin 4 x 1 4 cos2 2 x
1 2 sin 2 x 2
=
sin 4 x 3 1 4 cos2 2 x
cos 4 x
2sin 4 x cos 4 x
=
cos 4 x
= 2sin4x
16. Answer (4)
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KVPY(SA) Hints & Solutions 15
17. Answer (4)
Oil h
(h 2)
1 2
Water
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16 Hints & Solutions KVPY(SA)
1
F= i j
2
29. Answer (3)
30. Answer (1)
31. Answer (3)
Ca(H2PO2)2
+2 + [2 + x + (2) 2] 2 = 0
+2 + [4 + 2x + (8)] = 0
+2 + 2x 4 = 0
2x + (2) = 0
2
x 1
2
32. Answer (2)
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KVPY(SA) Hints & Solutions 17
33. Answer (3)
NH2 NH2 NH2
+I
M
(I) (II) NO2
(III)
Increased electron Decreased electron Decreased electron
density due to density by density by M effect
+I effect delocalisation of
lone pair
34. Answer (4)
1
Mobility
Size of cation
Cs+ is least hydrated, so has the smallest size in aqueous solution.
35. Answer (4)
16 2
Mass percentage of oxygen = 100 53.4%
60
36. Answer (4)
Fact.
37. Answer (3)
H E ngRT
2SO2(g) O2(g)
2SO3(g)
ng 2 (1 2) 1
Hence H E ( 1)RT
H E
For solids and liquids
ng = 0
38. Answer (3)
Fe3+ = [Ar]3d54s0 is half-filled configuration which is exceptionally stable.
39. Answer (2)
Valency = Number of valence electrons
ns2np1 3 valence electrons, so formula is MCl3
40. Answer (2)
CH2 CH CH2 is most stable due to resonance.
41. Answer (4)
42. Answer (1)
O
C6H5CH = O does not contain CH3 C group , which is necessary condition for haloform reaction.
43. Answer (1)
R 0 then molecule is unsymmetrical.
S
O O
R 0
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18 Hints & Solutions KVPY(SA)
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KVPY(SA) Hints & Solutions 19
62. Answer (2)
0
=
1
y
y+
C
2
x
=
y
x
2)
1,
B
A(
O x
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20 Hints & Solutions KVPY(SA)
2 2 72
2 2 8 52
3 2 18 32
4 2 32 12
Total number of squares are 288.
66. Answer (2)
67. Answer (4)
2 x3
Given, z x (1) say
y
(2)3
z (2)2 48 4
(1)
Now differentiating equation (1), we get
y (3 x 2 ) (dx ) x 3 (dy )
dz 2 x dx
y2
3x2 x3
2x dx 2 dy
y y
3(2)2 (2)3
2(2) ( 0.1) 2 ( 0.1)
(1) (1)
8 ( 0.1) 8 ( 0.1)
0.8 0.8
1.6
z 4 1.6
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KVPY(SA) Hints & Solutions 21
68. Answer (3)
Force exerted by sphere on ring = Force exerted by ring on sphere.
Divide the ring into elements, each of mass [dM]
G(m ) (dM )
Each element of Ring exerts a force of magnitude 2 2 on the sphere.
[a x ]
G(m ) (dM ) x
The X-Component of this force is 2 2
[a x ] a x2
2
Gm M x
The Net force acting on the sphere is
[a 2 x 2 ]3/2
69. Answer (2)
dT = dm( x)2
m
dT = . dx ( x ) 2
/2 T + dT T
T
m 2
dT =
( x) dx dx
0 0 x
2 /2 2 2
m 2 x x m 2
= =
2
0 2 8
Tension at mid point is :
3 3m 2
T= m 2 stress =
8 8A
3m 2
strain =
8 AY
70. Answer (2)
PQR = AOB + M.(ON)2;
y = x+C
2
R
B
1 C N Q
PQR = MR2 + M.
4 2
O
P
1 A
But PQR = MR2
2
R
C =
2
71. Answer (1)
Number of molecules = n NA
1g
(i) Weight of H2O = 500 mL 500 g
1 mL
500
NA 27.8 NA
18
44.8
(ii) NA 2 NA
22.4
32
(iii) NA 2 NA
16
10
(iv) NA 5 NA
2
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22 Hints & Solutions KVPY(SA)
3a
2
4
3a
2
73. Answer (3)
2
sp
CH = O CH3 CH = CH2
sp
3
sp2
2
sp all atoms
3
sp
sp2 sp sp2 sp
2
H+
Aromatic
(highly stable)
76 Answer (3)
77. Answer (4)
78. Answer (2)
79. Answer (2)
i - incorrect because - Inspiratory capacity (IC) = Tidal volume (TV) + Inspiratory reserve volume (IRV) but not TV
+ RV.
ii - correct because VC = TV + IRV + ERV.
iii - incorrect FRC = ERV + RV but not RV + TV.
iv - correct TV = IC - IRV
80. Answer (2)
a-iv - Biomacromolecules get catabolised and converted into simple substance.
b-i - Human digestive system - Alimentary canal and associated glands
c-v - Stomach - J - shaped bag like structure has pepsin, Rennin, HCl and mucus secreting glandular cells
d-ii Thecodont - The condition when teeth are deeply embedded in jaw bones e.g. human teeth.
e-iii - Serosa outer wall of visceral organs made up of simple squamous epithelium attached to the underlying
muscular coat by a thin sheet of connective tissue.
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KVPY(SA) Hints & Solutions 23
While ( 2) ( 2) = b and ( 2) ( 2) =a a b 4
2. Answer (4)
Let f(x) = x3 3x + [a]
f'(x) = 3x2 3
Let f'(x) = 0 x = 1
For three distinct real roots
f(1) f(1) < 0
(1 3 + [a]) (1 + 3 + [a]) < 0
([a] 2) ([a] + 2) < 0
2 < [a] < 2 a [1, 2)
3. Answer (1)
5 points
7 points
Number of quadrilaterals
= 7C4 + 7C3 5C1 + 7C2 5C2
= 35 + 175 + 210
= 420
4. Answer (2)
a 3 1 1 1 9
(a b c )
bc 2 bc c a ab 2
(a b ) (c a ) ( b c ) 3
3 1 1 1 (Using AM HM)
ab ac c a
1 1 1 9
(a b c )
bc c a ab 2
1 17
a b c abc
abc 4
a = b = c = 41/3
then abc = 4
5. Answer (3)
Using AM GM, each root is 1.
a 6
b 4
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24 Hints & Solutions KVPY(SA)
6. Answer (2)
2x x 1
2
y 2y 2
2 4 252
2x x 1
y 2y
2 2 4 4 2 252
2
x x
1
2 2 y 2 y . 252
2
2
x x
y
4 2 2 y 504 0
4t2 t 504 = 0
1 127
t
16
x x
63
2y 8 and 2 y (Reject)
8
x
2 y
23
x
3
y
x
1
xy y 3 1 4
Now, 2
xy x 3 1 2
1
y
7. Answer (4)
3600 = 24 32 52
There are (4 + 1) (2 + 1) (2 + 1) = 45 divisors of 3600.
45
2 90 45 45
Product of divisors = (3600) 2 3 5
.
8. Answer (1)
543 173 373 = (17 + 37)3 173 373
= 173 + 373 + 3 17 37 (17 + 37) 173 373
= 3 17 37 54 = 34 2 17 37
Total factors = 5 23 = 40
No. of composite factors = 40 (4 + 1) = 35.
9. Answer (2)
N = 112 + 122 + 132 +...+ 302
30 31 61 10 11 21
9070
6 6
10. Answer (3)
Let f(x) = (x 1)2 (x 2)
f(2) = 0 and f(3) = 4 f(0) f(3) = 4.
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KVPY(SA) Hints & Solutions 25
11. Answer (3)
Consider a, b, b, c, c, c
Using AM GM
1
abbc c c
6
ab2c 3 6
1
ab 2c 3 6
1
6
1
ab2c 3
66
12. Answer (4)
a ab abc abcd
K (let)
3 4 5 6
2b 3c 4d
a = 3k, b = c = d = k 3
a
13. Answer (4)
Angle between minute and hour hand at 7 : 20 OClock is 100 or 260
( sum of angles = 360)
difference between angles = 160.
14. Answer (3)
ab = 180 45 = 22 34 52
Number of ordered co-prime pair = 23 (way to distribute 22, 34 and 52 having two options a and b for each).
15. Answer (3)
n
an 2 k n(n 1)
n 1
n n
bn (2k ) 1 n(n 1) n n2
k 1 k 1
Now,
lim
n
n2 n n2 = lim
n 2
n n n
n
1 1
lim
= n
1 1 2
16. Answer (2)
R pr a A b V c
a b c
MLT 2 ML3 L2 LT 1
MLT 2 MaL3a 2b c T c
c 2
17. Answer (2)
GM
When satellite losses mechanical energy it comes closer to the earth so orbital speed v increases so
r
kinetic energy increases.
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26 Hints & Solutions KVPY(SA)
GMm 11 R 2
=
2R 3 4
3GMm 1 11GMm
mv 2
2R 2 8R
1 3GMm 11GMm
mv 2
2 2R 8R
1 12GMm 11GMm
mv 2
2 8R
1 GMm
mv 2
2 8R
GM
v
4R
20. Answer (2)
21. Answer (3)
Final temperature of mixture will be 100 C. A part of steam condenses
mice Lice + mice Sw (100 0) + mw sw (100 10) = msteam Lvap
1000 80 + 1000 1 100 + 1000 1 90 = msteam 540
1000 270 = msteam 540
msteam = 500 g of steam condenses
total mass of water in final composition = 2.5 kg
22. Answer (2)
For isochoric process,
P T
nRT
U nCv T = 1
So, U P
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KVPY(SA) Hints & Solutions 27
23. Answer (2)
In open pipe,
V
nf
2 l 2e where e is end correction
320
320
2 0.48 2e
0.96 + 4e = 1
0.04
e 0.01 m
4
In closed pipe,
v 320 320
nf
4 l e 4 0.48 0.01 1.96 = 163 Hz
24. Answer (1)
Molten sodium is used as coolant.
25. Answer (2)
A 0 B
60
0 90
1200
300
= 60
On vertical face angle of incidence is 30 inside the prism.
From Snells law,
4
2 sin30 = sin
3
3
sin
4
26. Answer (2)
27. Answer (4)
The tension in the string depending on the direction of magnetic field. It may increase or decrease.
28. Answer (2)
29. Answer (1)
= 0sin (t)
g
g
2
g
1m
2
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28 Hints & Solutions KVPY(SA)
+
CH3 CH2 CH2 OH H CH3 CH2 CH2 OH2
H2O
CH3 CH3CH2CH2
CH-CH3 CH3CHCH3
Aromatic 1,2H-shift
electrophilic
substitution
36. Answer (1)
IE3 and IE4 are having maximum difference. So, metal has 3e in outermost shell and donate 3e to convert into
M3+ ion. So, formula of metal halide will be MX3.
37. Answer (2)
M(NO3)n = gm equivalent of M2 (SO4)n
1.0 0.86 1 0.86
E M E NO
3
E M E SO 2
4 E
62
E
96
1 2
38. Answer (4)
Fact.
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KVPY(SA) Hints & Solutions 29
39. Answer (4)
H2 I2
2HI
2 1 1
1 (Moles at equilibrium)
9 9 9
KC
H I or K
2 2
1 1 9 9
KC
1
HI 2 C
9 9 7 7 49
40. Answer (1)
2 M H2O2 solution means 1 mole (or 34 g of H2O2)
1 mole present in 103 mL solution
68 g H2O2 gives 22400 mLO2
22400 34
11200mL of O
34 g H2O2 gives 68 2
11200
Volume strength = 11.2
103
41. Answer (3)
42. Answer (1)
P4 3NaOH 3H2O
PH3 3NaH2PO2
(Phosphine) (Sodium hypophosphite)
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30 Hints & Solutions KVPY(SA)
Required number of ways = 3 (groups of (0, 5), (1, 4), (2, 3)).
62. Answer (1)
It is equivalent to having non-negative integral solution of x1 + x2 + x3 + x4 = 3 and y1 + y2 + y3 + y4 = 10
Simultaneously.
2 b2 3b 2 c 2 2c 2 3d 2 5d 2 2
a ab bc cd d 0
4 4 3 3 8 8 5
2 2 2 2
b 3b c 2c 3d 5d 2
a 0
2 2 3 3 2 2 2 2 5
4 3 2 1
d , c , b , a a b c d 2 .
5 5 5 5
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KVPY(SA) Hints & Solutions 31
65. Answer (4)
Let f(x) = 3x3 6x2 + 4
f ' x 9 x 2 12x
4
9x x x
3
+
4
0
3
4
f(x) has it minimum value at x
3
3 2
4 4 4
f 3 6 4
3 3 3
64 16
3 6 4
27 9
64 96
4
9 9
32 36 4
9 9
66. Answer (4)
Initially kinetic friction is towards right
fk= k N
= 0.2 20
v = 6 m/s
=4N
retardation F=8N
fk
12
a1 6 m/s2
2
So block will stop momentarily at t = 1 s. After that block moves towards right.
After t = 1 s
84
a2 2 m/s
2
So velocity at t = 2 s.
v = 2 m/s towards right.
67. Answer (3)
m = (10.0 0.1) kg
v = (5.0 0.2) m/s
p = mv = 50.0 kg/s
p = mv + vm
p = (0.1)(5) + 10(0.2)
p = 2.5
p p (50.0 2.5) kg m/s
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32 Hints & Solutions KVPY(SA)
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KVPY(SA) Hints & Solutions 33
VI VM 2 m/s
VI 2 2
VI 0
71. Answer (1)
1014
K a HOCN 10
104
10
Kb 10 10
10 4
C 0.01
0.1 K b C
2
OH C; OH 0.01 10 4 10 6 M
W RT
V M
RT
Slope
M
RT
M
Slope
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34 Hints & Solutions KVPY(SA)
1 a b
a = 2 and b = 2.5
2 4 5
ab 45
9
a b 0.5
2. Answer (4)
Sn = 1 + 3 + 32 + ..... + 3n 1
3n 1
2500
2
3n 5001
n=8
3. Answer (4)
A = 2xy = 2xex y
dA
dx
2 e x xe x (0, 1)
y=e
x
y
= 2ex (1 x) x
Ox
+
A is maximum at x = 1
2
Maximum area = 2.1.e1 =
e
4. Answer (3)
Number of rectangle = 10 10 = 100
Number of squares = 8 + 3 = 11
5. Answer (2)
56 = 23 71
Exponent of 2 in 25! = 12 + 6 + 3 + 1 = 22
Exponent of 7 in 25! = 3
Hence maximum accepted k in 56k is 3
6. Answer (2)
In given triangle cos B + cos C = 1
1
and B cos C C
3 2 3
Hence A = B = C
7. Answer (4)
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KVPY(SA) Hints & Solutions 35
8. Answer (3)
n(AB) can be 12, 10, 8, 6, 4, 2
Hence sum = 2 (1 + 2 + 3 + 4 + 5 + 6)
(6 7)
2 42
2
9. Answer (1)
x + y + 1 = 0 and y = x are perpendicular
10. Answer (2)
2
Period of sinx =
2
Period of cosx = 2
On observation we see may be
11. Answer (1)
9 9!
C5 4! 9876
5!
12. Answer (2)
We have direction ratios of AG (a, a, a) and of BH are (a, a, a)
Hence angle between AH and BH
a 2 a 2 a 2 1
cos
3a 3a 3
13. Answer (1)
Domain = x 2, 2 and x (1, )
Domain of f(x) is (1,2]
Required answer is 1
14. Answer (1)
T.A of hyperbola is 2a 8
15. Answer (1)
(n !)n
As (n!)n is a constant lim vanishes
x ex
16. Answer (2)
F mg kv
As ball goes up v decreases but weight remains constant.
17. Answer (2)
a
F F0
m m
cos t i sin t j
t F0
v adt sin t i (1 cos t ) j
0 m
2
1 1 F
K.E. v v m 0 (2 2cos t )
2 2 m 2
F2
0 (1 cos t )
m
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36 Hints & Solutions KVPY(SA)
mv MVcm
2
L ML
mv
2 12
Also,
L ML
2
MVCM
or 2 12
6VCM
L
2L L
d Vcm t Vcm
6Vcm 3
21. Answer (2)
mgsin f = macm
a
fr mr 2 cm f macm
r
sin
acm g
2
g sin
2r
g sin
L I (mr 2 ) t Lt
2r
25. Answer (1)
m m x
T 2
4K
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KVPY(SA) Hints & Solutions 37
27. Answer (3)
Acceleration of topmost point.
(2v )2 v 2
r R
r = 4R.
28. Answer (2)
A A
Speed is larger close to equilibrium position. So, minimum time to go from displacement to
2 2
T T T
i.e. ,
12 12 6
29. Answer (1)
Tension in the string
L
T S mg
S
n3
T
z2
23 2
T2 ,He 2 2
3 1
2
T3,H 3 27 27
12 1
32. Answer (3)
a
Pc
27b2
8a 64a2
Tc , Tc 2
27Rb 272 R2b2
64a2
Tc 2 27 R b
2
2 2
Pc a
27b2
Tc 2 64a 27R2 Tc 2
2
a=
Pc 27R 64Pc
8a
Tc 8b RTc
27Rb b
Pc a R 8Pc
27b2
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38 Hints & Solutions KVPY(SA)
PCl5 g
PCl3 g +Cl2 (g)
ng = (1 + 1 ) 1 = 1
2NH3 g
N2 g +3H2 (g)
ng = (1 + 3) 2 = 2
N2 g O2 g
2NO(g)
ng = 2 (1 + 1 ) = 0
0.0250
N2 = N2 = 0.01
100
So, [OH] = 102
pOH = 2
pH = 12
38. Answer (2)
V = 5.6 N
= 5.6 0.8
= 4.48
39. Answer (4)
CH3I + Mg CH3MgI
O OMgI OH
HC HC CH3 HC CH3
H3O
+ CH3MgI
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KVPY(SA) Hints & Solutions 39
40. Answer (1)
Due to intramolecular H-bond
Intra molecular
OH hydrogen bond
H OH
H H
H
41. Answer (2)
CH3 CH3
H2
CH3 C C CH3 C=C
Pd, CaCO3
H H
CH3
H Br Br2
Anti addition
Br H
CH3
Racemic
42. Answer (2)
NO2 HSO4 H2O
H2SO4 HNO3
43. Answer (2)
In presence of sunlight photo chemical reactions occur.
44. Answer (3)
Bridge bonds are (3C2e) are weaker than normal terminal BH (2C2e) bonds. B is in sp3 hybrid state.
45. Answer (2)
In chain silicate, 2corner O atoms are shared.
46. Answer (4)
47. Answer (1)
48. Answer (4)
49. Answer (4)
Bulliform/motor cells are large, empty transparent cells on adaxial surface of monocot leaf that help in rolling and
unrolling of leaf.
50. Answer (1)
51. Answer (1)
Nitrogenase enzyme complex helps in nitrogen fixation but it is functional only in anaerobic condition.
52. Answer (2)
According to chemiosmotic hypothesis, the transport of H+ from intermembrane space to matrix is based on
concentration gradient i.e., H+ move from their higher concenteration with formation of ATP.
53. Answer (3)
54. Answer (1)
Tubular secretion of H+ takes place in the proximal convoluted tubule, DCT and also in collecting duct. It is
an important step in urine formation as it helps in maintenance of the ionic and acid-base balance of body
fluids.
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40 Hints & Solutions KVPY(SA)
63 53 216 125 91
Preq 3
6 216 216
63. Answer (1)
sin 2 sin 1 0
sin 1
3
sin 1
2
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KVPY(SA) Hints & Solutions 41
64. Answer (2)
x iy 2 x iy 0
x 2 y 2 x 0 and 2 xy y 0
1 3 1 3
z 0, i, i
2 2 2 2
65. Answer (1)
x + y + z = 10
x 0, y 0, z 1
x 0, y 0, z 1 0
x 0, y 0, c 0
x y c 1 10
x+y+c=9
No. of solution = 9 3 1
C9
11 10
11C9 55
2
66. Answer (4)
67. Answer (2)
v v
L1 L2
2n1 2n2
v n1n2
nnew
2(L1 L2 ) (n1 n2 ) .
C
O O1
60 60
A B
ml 2 ml 2
IAC = IBC = sin2 60
3 4
2
l 3 3 2
I AB m ml
2 4
5 2
IOO' = ml
4
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42 Hints & Solutions KVPY(SA)
d dmv 2
2T sin v T
2 R
1 v2 d
2T d Rd T sin
2 R d
d 2 2
2
T v 2 T sin
d
2
T v 2
Now, Velocity v
71. Answer (2)
Be (4) = 1s22s2
B (5) = 1s22s22p1
C (6) = 1s22s22p2
N (7) = 1s22s22p3
After loss of 2e,
Be+2 = 1s2 Stable inert gas
B+2 = 1s22s1
C+2 = 1s22s2 Stable full filled
N+2 = 1s22s22p1
Be > C> N > B
IE3 14.85 4.62 4.57 3.66 MJ mol1
72. Answer (3)
73. Answer (4)
N atom is in sp2 state, so lone pair will be present in remaining unhybridized pure p-orbital.
+ SiH3 + SiH3
H3Si = N H3Si N
SiH3 SiH3
+ SiH3
H3Si N
SiH3
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KVPY(SA) Hints & Solutions 43
74. Answer (2)
3
For monoatomic gas, Cv R,
2
3 5
Cp Cv R = RR R
2 2
8
No. of moles of gas = = 2 mole
4
T2
S nCp ln T1 = 27C = 300 K
T1
T2 = 327C = 600 K
T2
= 2.303nCp log
T1
5 600
= 2.303 2 R log
2 300
= 2.303 5 8.314 log 2
= 2.303 5 8.314 0.3010
= 28.8 JK1
75. Answer (2)
Alkene with highest number of H will be most stable. So will have lowest Hhydrogenation, i.e., least negative.
H H H
CH2 H
H CH3
H H H CH3
4H 10H
3H
H
H CH3
CH2 H H
H
1H 7H
76 Answer (3)
Certain species of cyanobacteria possess some special cells called heterocyst. These cells are devoid of
photosystem II. Nitrogenase enzyme convert atmospheric N2 into Ammonia. Nitrogenase enzyme can only work
in the absence of O2. Therefore, these cells are modified in such a way that they lack photosystem II, which is
responsible for O2 production by breaking down H2O.
77. Answer (2)
In cilia and flagella the microtubules arrangement is 9+2 where 9 peripheral microtubule are doublet and the two
microtubule at the centre are connected by central bridge forming central singlet fibre.
78. Answer (2)
79. Answer (4)
In emergency situations like the fight and flight body needs more oxygen, specially our skeleton muscles needs
more oxygen for flights and fight . Sympathetic system become activated which dialate the blood vessels that
supply blood to the skeleton muscle and cut the blood supply to digestive system. So all the functions of
digestive system is suppressed like motility, decrease in saliva secretion, decrease in bile juice and HCl secretion.
80. Answer (1)
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44 Hints & Solutions KVPY(SA)
AD AB 2 BD 2 A
C Bridge
2 2
DC AD AC
After time t sec
AC = 6t, BD = 8t
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KVPY(SA) Hints & Solutions 45
7. Answer (1)
Substitute x = y = 0 in
f(x + y) + f(x y) = 2f(x) f(y)
f(0) + f(0) = 2(f (0))2
(f (0))2 f(0) = 0
f(0) = 0 or f(0) = 1
Now substitute x = 0 in
f(x + y) + f(x y) = 2f(x) f(y)
f(y) + f( y) = 2f(0) f(y)
f(y) + f( y) = 2f(y)
f( y) = f(y)
f(x) is an even function
f(2) = f( 2)
8. Answer (4)
2 3 1
,
2 4
2 1 1 2
9. Answer (4)
x 2n 1
x 1 lim 1
n x 2n 1
x 2n 1
x 1 lim 0
n x 2n 1
x 2n 1
x 1 lim 1
n x 2n 1
B(6, 2)
P
O Q
B'(6, 2)
PA + PQ + BQ = PA + PQ + BQ which will be minimum when A, P, Q, B are collinear.
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46 Hints & Solutions KVPY(SA)
y 2
they lie on the line y 4 x 1
1 6
6x + 7y = 22
22 22
So P is 0, , Q is ,0
7 6
1 1 13
OP OQ 22
11. Answer (4)
C
A A B B
2 2
A B
ASB =
2 2
C 3
2 4
12. Answer (1)
Given curve can be written as (y 2)2 = 4(x + 1)
Focus be (0, 2) and vertex (1, 2)
y
(0, 4)
(1, 2) y=4
(1, 2) (0, 2)
x
(0, 0)
If any ray is coming parallel to axis of parabola then after it get reflected it passes through the focus, therefore
equation of reflected ray be x = 0
13. Answer (1)
sin4x + (a + 2)sin2x (a + 3) = 0
[sin2x + (a + 3)](sin2x 1) = 0
sin2x = 1 or sin2x = (a + 3)
So the equation possesses a solution of all values of a.
14. Answer (1)
24 = 2 3 4 = 2 2 6
=138=164
= 1 2 12 = 1 1 24
Number of positive integral solutions
3! 3!
3! 3! 3! 3!
2! 2!
=6+3+6+6+6+3
= 30
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KVPY(SA) Hints & Solutions 47
15. Answer (2)
21a2 + 21b2 + 21c2 = a2 + 4b2 + 16c2 + 4 ab + 16bc + 8ca
2 2 2
2a b 4b 2c c 4a 0
b c c
a , b a
2 2 4
a b c
a, b, c are in GP
1 2 4
16. Answer (2)
W. = F.S; S = A T2
[W] = [FAT2]
17. Answer (4)
a = kt
dv
kt
dt
dv k t dt
kt 2
v
2
ds k 2
t
dt 2
k 3
s t
6
18. Answer (3)
19. Answer (1)
20. Answer (4)
Its a property.
21. Answer (3)
22. Answer (1)
N A
4
23. Answer (1)
L
2m 2m
y cm 2
3m cm
L y
y
3
24. Answer (4)
First decreases then increases.
25. Answer (1)
26. Answer (4)
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48 Hints & Solutions KVPY(SA)
2GM
ve
r
29. Answer (3)
m
T 2
keff 2k
1 1 1
keff 2k 2k 2k
keff k m
m
T 2
k
30. Answer (3)
31. Answer (3)
3RT
URMS
M
C2H6, M1 = 30
O2, M2 = 32
3RT1
U1 M1
U2 3RT2
M2
T1 T2
M1 M2
T1 300
30 32
T1 = 281.25 K
32. Answer (2)
(1) Na2O < P2O5 < SO3 < Cl2O3 : Acidic nature
(2) KCl < RbCl < CsCl : Solubility of alkali metal chloride
(3) BaO < SrO < BeO < MgO : Melting point of alkaline metal oxide
(4) NaF < MgO < SCN < TiC : Hardness
33. Answer (4)
In[Ni(H2O)2(NH3)4]2+, Ni is in +2 oxidation state.
Ni+2 : [Ar]3d84s0
Number of unpaired electrons, n = 2
n(n 2) B.M.
2(2 2) B.M.
= 2.83 B.M.
34. Answer (4)
B2H6
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KVPY(SA) Hints & Solutions 49
35. Answer (4)
(1) Heg for F = 328 kJ/mol
(2) Heg for Cl = 349 kJ/mol
(3) Heg for Ar = +96 kJ/mol
(4) Heg for Ne = +116 kJ/mol
36. Answer (2)
O O O
, ,
CH 3 1 CH3 SiH 3 2 SiH3 F 3 F
1= 110 2= 144 3= 102
37. Answer (1)
Carboxylic acid is most acidic than alcohol & C=O is more acidic than ethers due to -Hydrogen
38. Answer (2)
39. Answer (3)
Ka = 5 1010
pKa = 9.3
[acid]
pH pK a log
[salt]
[acid]
9 9.3 log
[salt]
[HCN]
log 0.3
[KCN]
[HCN]
2
[KCN]
Number of millimoles of HCN = 2 number of millimoles of KCN
10 2 = 2 5 V
V = 2 mL
40. Answer (4)
Mg2C3 + 4D2O 2Mg(OD)2 + CD3CCD
41. Answer (4)
Borax Bead test
Ni Brown
Cu Blue
42. Answer (4)
H2O C2H5OH HCCH NH3
pKa 15.7 16 25 38
Higher the pKa ,lesser is the acidic strength & Vice-Versa
43. Answer (4)
Radical trap
44. Answer (4)
M = 2V.D
32 + 16x = 240
x=3
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50 Hints & Solutions KVPY(SA)
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KVPY(SA) Hints & Solutions 51
63. Answer (4)
Let the tangent is drawn at the point (a sec, a tan)
x sec y tan = a
t sec a
any point on it will be of the form t ,
tan
the equation of chord of contact to parabola is
t sec a
y 2a x t
tan
ya y sec
2ax t 2a 0
tan tan
the point Q will be point of intersection of
ya y sec
2ax 0 and 2a 0
tan tan
y = 2a sin, x = a cos
so the point Q is (a cos, 2a sin) which lies on an ellipse.
64. Answer (1)
A A A
AI ' I ' P cosec rA cosec and AI r cosec
2 2 2
A
So, II ' r rA cosec
2
A A
r + rA = (r rA)cosec
2
P Q
A I'
1 sin
So, rA r 2 r tan2 A
A 4
1 sin I
2
B B C
1 sin
r r
2 r tan2 B
Similarly, B B 4
1 sin
2
C
1 sin
rC r 2 r tan2 C
and C 4
1 sin
2
A B
rArB rBrC rCrA r tan tan
4 4
So,
If A + B + C = /2, then
A B B C C A
tan tan tan tan tan tan 1
2 2 2 2 2 2
A B C
as
4 4 4 2
A B
So, tan 4
tan
4
1
rA rB rB rC rC rA r
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52 Hints & Solutions KVPY(SA)
g 2g
aB and aA
7 7
67. Answer (4)
x4 x2
U( x )
4 2
dv
F x3 x
dx
0 x( x 2 1)
x=0&x=1
1 1 1
U ( x 1) joule = Minimum
4 2 4
E K U const Kmax Umin
1 2 1
2 1 v max
2 4
2
1 v max
2
4 2
2
9 v max
4 2
3
v max m/s
2
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KVPY(SA) Hints & Solutions 53
68. Answer (1)
N mg cos
O
f mg cos f
m
mg cos mg sin N
1
cot mg cos
mg mg sin
cot 3
69. Answer (2)
m v m2v 2 m3v 3
v cm 1 1
m1 m2 m3
11 7
v cm v 0 i v 0 j
6 6
70. Answer (2)
71. Answer (4)
for cyclic P=0
P P
V T v T T V T V
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54 Hints & Solutions KVPY(SA)
___H___E___I___C___S___
z!
5! 5C2 5! 6C2
2!
65
120
2
= 120 15
1800
2. Answer (4)
33 33 33 33 33
= 2 3 4 5
2 2 2 2 2
= 16 + 8 + 4 + 2 + 1
= 31
3. Answer (4)
b=
c=
a + b + c = 3
4. Answer (2)
= 9! 9 8 8 7!
= 9! 8 9! 9 9!
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KVPY(SA) Hints & Solutions 55
5. Answer (2)
1 1 1
t100 .....
5 5
(100C0 ) (100C1 ) (100C100 )5
0 1 2 100
S100 ... ...(i)
5 5 5
(100C0 ) (100C1 ) (100C2 ) (100C100 )5
Adding
1 1
we get the minimum value of 5
a 20
a = 100
So, answer = 100
7. Answer (3)
y=1+x
x=y1
(5 x )(2 x ) (4 y )( y 1)
p
1 x y
2
4 2
= y 5 y 9
y y
So, minimum value of p is 9.
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56 Hints & Solutions KVPY(SA)
8. Answer (2)
A
x y
G
B C
O
1 2
AO x y 2 (For maximum area of triangle)
2
2 1 2
AG OA x y2
3 3
9. Answer (3)
Given, x and y are the sides of squares. Then the area of the squares are x2 and y2
We have to obtain
dy
2y
d(y 2 ) dx y dy
d(x2 ) 2x x dx
dy
Given that y = x + x2 1 2x
dx
d(y 2 ) y ( x x 2 )(1 2x )
(1 2 x )
d(x2 ) x x
= 1 x 1 2x
d y2
(1 4)(1 8) 5 9 = 45
d x2
x 2
10. Answer (2)
Length of angle bisector
2bc A
cos
bc 2
2bc A A
cos 2 60
bc 2
bc
bc
11. Answer (1)
EC = DC = 15 cm B
x
BD = BF = x
x
AB = (6 + x) D
AC = 6 + 15 = 21 cm
15
BC2 = AB2 + BC2 F O
(x + 15)2 = (6 + x)2 + 212 6
A 6 E C
x = 14 15
BD = 14 cm
CD BD = 15 14 = 1 cm
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KVPY(SA) Hints & Solutions 57
12. Answer (1)
(123)321 = (120 + 3)321
321
C0 120321 321
C1120320.3 321
C2 120319.32.... ... 321
C320 120.3320 321
C321.3321
Divisible by 5.
Now, 3321 = 3.3320 = 3.(81)80
= 3 [1 + 80]80
y=2
y = 2 x=2
y = 2
a0 t 2 a
v a0 t v 0 t 2 a0 t
t0 2 2t0
upto time t0 acceleration is +ve so velocity must be increasing.
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58 Hints & Solutions KVPY(SA)
AB R 2 R 2 2.R.R.cos60
AB 3 R
As point in contact with ground act as instantaneous axis of rotation
VB 3 R 3 V
24. Answer (2)
As torque acting on planet is zero its angular momentum remains conserved.
r v
mv1r1 mv 2 r2 1 2
r2 v1
So smaller is the distance larger is the speed.
25. Answer (1)
26. Answer (1)
27. Answer (2)
a b adiabatic
b c isobaric
c a isochoric
28. Answer (3)
amax. = A2
Vmax. = A
3rd option satisfies the condition.
29. Answer (4)
30. Answer (4)
W Area
Efficiency
Q Q AB QBC
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KVPY(SA) Hints & Solutions 59
31. Answer(3)
PA .A
Rate of diffusion rA
2RTM A
PA= Partial pressure of gas A
A = Area of cross-section
T = Temperature
MA = Molar mass of A
So at constant temperature
PA
rA
MA
32. Answer (2)
Enthalpy of neutralizations neq.
for HCl = N1V1 1 x v = x ....1
for H2SO4 = N2V2 2 v = y ....2
from eq. 1 and eq. 2
1 x
2 y
y
x
2
33. Answer (3)
H2 + Cl2 2HCl Cl2 has less volume
12L 11.2 L 22.4 L So it is a limiting reagent
volume of H2 unreacted 12 11.2 = 0.8L
34. Answer (3)
1 1 rc Cationic radius
Hydration energy
rc ra ra Anionic radius
So smaller cation have more degree of hydration.
35 Answer (1)
In acid anhydride as electronegativity of central atom increases or percentage of oxygen increases, acidic nature
also increases.
36. Answer (1)
Hb
Ht Ht
B B
Ht Ht
Hb
37. Answer (1)
o 0.059 [Fe2 ]
EFe3 /Fe2 EFe 3
/Fe2
log
n [Fe3 ]
0.059 (1.5)
0.770 log
1 (0.015)
= 0.770 0.059 2
= 0.65 V
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60 Hints & Solutions KVPY(SA)
4 1
Position of Br 4
3
Cl
2
I
2
Position of Br 2
1
Cl
41. Answer (4)
CH3 CH3
C C
CH3 C2H5
larger EDG
CH3 CH3
C C
CH3 C2H5
42. Answer (4)
Butane 2-methylbutane 2,3-dimethylbutane
C4H10 C5H12 C6H14
Having difference of CH2, so forms a homologous series.
43. Answer (3)
1
CH CH + Na HC C Na + H2
2
44. Answer (3)
Due to presence of more +I effect in benzyl alcohol, (C6H5 CH2 OH) it is less acidic
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KVPY(SA) Hints & Solutions 61
45. Answer (4)
Heat
C6H5 COOH NaOH CaO C6H6 Na2CO3
soda lim e
C6H5 OH
Zn dust
C6H6 ZnO
f ( x 2 1) x 4 7 x 2 k1
Putting x = 1
f (0) 1 7 k1 6 k1
in f ( x 3 2) putting x 3 2
f (0) 14 k2
So 14 k2 6 k1
k2 k1 8
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62 Hints & Solutions KVPY(SA)
R
C1 C2
D1 O D
1R
Now, OC22 = OD2 + DC22
(1 R)2 = R2 + R2
R 1 2 (Rejected)
R 1 2
Now, R 2 3 2 2 R1R2
65. Answer (3)
n 200 5300
1
n 200 5380 n (5300 ) 200
3
n 52 n2 < 125
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KVPY(SA) Hints & Solutions 63
66. Answer (1)
V2 = 2aS3
Differentiating
d (V 2 ) d (2aS 3 )
2
3aS
dS dS V
dV
2V 2a 3S 2 a
dS V2/R
at 3aS 2
a V2 1
tan c
at R 3aS 2
2aS 3 1 2S
tan
R 2 3R
3aS
67. Answer (1)
68. Answer (2)
mg
2T sin mg T ... (i)
2 sin A l l B
Change in length is
T T
l AC BC 2l C
1
mg
2 l2 x
2 2
2l
1
x2 2
2l 1
l 2
1 x2
2l 1 2l
2 l2
x2
l
l
l x2
Strain =
2l 2l 2
T mg
Stress =
A 2 A sin
is very small sin tan
x
tan
l
mgl
Stress =
2 Ax
Stress mgl 2l 2
Y
Strain 2 Ax x 2
1
mg 3
x l
AY
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64 Hints & Solutions KVPY(SA)
GMm 1
mv 2 0
2R 2
1 GMm
mv 2
2 2R
GM
V gR
R
V gR
s m
2m 40 T s T 20 m2s T 10
2 2
T 20
40 T 2 T 10
2
T = 24C
71. Answer (3)
Electronic confriguration of C2 molecule
2
1s 1s 2s 2s 2Px
2 2 2 2 2
2Py
In this both electron pairs are present in (2Px) and (2Py) bonding molecular orbital
so in C = C both bonds are -bonds
72. Answer (2)
1 d[C] d[B]
2 dt dt
d[C] d[B]
2
dt dt
Rate of appearance of C is twice of the rate of disappearance of B.
73. Answer (1)
Z2
(1) KE = +13.6 (ev)
n2
Z
(2) v = 2.18 108 (cm / sec)
n
So v n = 2.18 108 Z
velocity
(3) Frequency fn =
2r
z n2
v r
n Z
Z Z Z2
So fn 2 3
n n n
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KVPY(SA) Hints & Solutions 65
(4) Coulombic force of attraction
kZe2
(F) =
r2
Z n2
F & r
r2 Z
Z3
So F
n4
74. Answer (4)
Solubility is the concentration of salt in mol/L which is present in dissolve state in solution.
Compound having higher value of solubility will be more soluble
In Ag3PO4 Ksp = (3S)3 S = 27S4
S4 = 1016
S = 104 mol/L
Ag3PO4 has higher value of solubility
75. Answer (3)
H+ after rearrangement
H2O
CH3 shifting
OH 2-carbocation
more stable
according to 3-carbocation
saytzeff's rule
76. Answer (3)
77. Answer (4)
C4 plants are tropical and subtropical plants which are more efficient in CO2 fixation. They have both RuBisCO
and PEPcase for CO2 fixation.
They can also tolerate high salt concentration due to formation of malic acid in their cells.
78. Answer (3)
Miller et al. discovered cytokinin.
Auxin was the first hormone to be discovered
Yabuta extracted first gibberellin.
79. Answer (2)
Terrestrial animals have less availability of water as compared to aquatic animals.
80. Answer (3)
Insulin is a hormone, which increases the uptake of glucose inside the cell. So before meal glucose
concentration is less and after meal glucose concentration increases in the blood. So, insulin secretion is
increases after meal which increases the uptake of glucose inside cell.
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