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IMPORTANT INSTRUCTIONS
1. Immediately fill the particulars on this page of the Test Booklet with Blue / Black Ball Point Pen.
Use of pencil is strictly prohibited.
2. The Answer Sheet is kept inside this Test Booklet. When you are directed to open the Test
Booklet, take out the Answer Sheet and fill in the particulars carefully.
3. The test is of 3 hours duration.
4. The Test Booklet consists of 90 questions. The maximum marks are 360.
5. There are three parts in the question paper A, B, C consisting of Mathematics, Physics and Chemistry
having 30 questions. Each part consists of Three sections.
6. For each question in Section 1, you will be awarded 3 marks if you darken all the bubble(s)
corresponding to only the correct answer(s) and zero mark if no bubbles are darkened. In all other
cases, (1) marks will be awarded.
I have read all the instructions and I have verified all the information
shall abide by them. filled in by the Candidate.
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Signature of the Candidate Signature of the Invigilator
PART- A 3. The median of set of nine distinct observations
is 20.5. If each of the observations of the set is
question has 4 choices (1), (2), (3) and (4) for (2) is decreased by 2
its answer, out of which ONLY ONE is correct. (3) is two times the original median
(4) remains the same as that of the original
1. For three square matrix A, B & C if ABC = O & set
| A | 0, B is non-zero singular matrix then
(1) C must be zero matrix 4. The coefficient of x48 in the product (x 2)
(2) C must be non-singular matrix (x 4) (x 6)........(x 98) is
(3) C must be singular matrix
(1) 992
(4) Data insufficient
(2) 2450
(3) 2500
2. If a 2x 2 i 4 xj k and b 7 i 2 j xk are (4) 2352
inclined at an obtuse angle and a is parallel
5. A closet has 5 pairs of different types of shoes.
to c i 20 j 50k then
The number of ways in which 4 shoes can be
1 drawn from it such that there will be no
(1) x =
10 complete pair is
RESONANCE JPJMT1251113C0 - 1
6. If A is a square matrix of order 3 such that 9. Number of divisors of the number N = 23 . 35.
|A| = 2, then |(adjA1)1| is 57 . 79 which are perfect square is
(1) 24
1
(1)
4 (2) 60
(4) 8
x2 y3 4z
10. The lines and
1 1 k
7. Let a = 2 i j k , b i 2 j k , c i j 2k .
x 1 y 4 z 5
A vector coplanar with b and c , whose
are coplanar if
k 2 1
2
projection on a is of magnitude is
3 (1) k = 0 or 1
(1) 2i 2j 3k (2) k = 0 or 1
(3) k = 0 or 3
(2) 2 i j 5k
(4) k = 3 or 3
(3) 2 i 3 j 3k
11. If the system of linear equations x + 2ay + az = 0,
(4) 2 i j 5k
x + 3by + bz = 0, and x + 4 cy + cz = 0 has a
non-zero solution, then a, b, c
8. In the expansion of (3x/4 + 35x/4)n the sum of (1) are in AP
binomial coefficient is 64 and term with the (2) are in GP
greatest binomial coefficient exceed the third
(3) are in HP
term by (n 1), the value of x must be
(4) satisfy a + 2b + 3c = 0
(1) 0
(2) 1
(3) 2
(4) 3
RESONANCE JPJMT1251113C0 - 2
15. Let ABC be a triangle where A = (2, 3, 5),
12. Let a j k and c i j k . The vector b
B = (1, 3, 2) and C = (, 5, ). If the median
satisfying a b c 0 and a .b 3 is through A is equally inclined to the axes, then
(1) = = 5
(1) 2 i j 2k (2) i j 2k
(2) = 5, = 7
(3) i j 2k (4) i j 2k (3) = 7, = 10
(4) = 0, = 0
RESONANCE JPJMT1251113C0 - 3
21. If a,b, c are three vectors mutually perpendicular
SECTION - II
to each other and | a | =1, | b | = 3 and | c | = 5,
Straight Objective Type
This section contains 10 questions. Each
then [a 2b b 3c c 4a] =
question has 5 choices (1), (2), (3), (4) and
(1) 0 (2) 24
(5) for its answer, out of which ONLY ONE is
(3) 3600 (4) 345
correct.
(5) 15
x 1 y z
18. Image of line L = = in the x z
1 1 0 22. If A is a square matrix and A 3 3 A 2 3 A O
plane is
then A 2 2A I is equal to
z
(1) x 1 = y = (2) x y = 1, z = 2
0 1
(1) ( A I) (2) O
x 1 y z x 1 y z
(3) = = (4) = = (3) I (4) 3A + I
0 1 1 1 1 1
x 1 y z
(5) (A + I)
(5) = =
1 0 1
RESONANCE JPJMT1251113C0 - 4
27. A variable plane passes through a fixed point
24. A unit vector coplanar with i j 2k and
(a, b, c) and meets the coordinate axes in A,
i 2 j k and perpendicular to i j k is B, C. Locus of the point common to the planes
through A, B, C and parallel to coordinate
j k i j k
(1) (2) planes, is
2 3
a b c x y z
i j k j k (1) 1 (2) 1
(3) (4) x y z a b c
6 2
(3) ax + by + cz = 1 (4) ax + by + cz = 2
j 2k a b c
(5) (5) 2
5 x y z
RESONANCE JPJMT1251113C0 - 5
29. Consider the system of the equations 30. STATEMENT-1 : A card is drawn from a well
kx + y + z = 1, x + ky + z = k and x + y + kz = k2 shuffled ordinary deck of 52-playing cards.
Statement- 1 : System of equations has Let A be the event that 'card drawn is an Ace'
infinite solutions for k = 1. and B be the event that 'card drawn is a
RESONANCE JPJMT1251113C0 - 6
PART-B 33. A block of weight W rests on a rough horizontal
plank hinged at point 'O'. The plank starting from
horizontal position rotates such that the angle
SECTION - I it makes with horizontal increases slowly upto
Straight Objective Type 90. If f is the friction between the block and
This section contains 17 multiple choice f
the plank, identify the graph of versus .
questions. Each question has choices (1), (2), W
s and k are coefficients of static and kinetic
(3) and (4) out of which ONLY ONE is correct.
friction between the plank and block ) ?
(4) 4 R/3
(1) (2)
90 90
32. In the circuit shown in figure, the resistance of
voltmeter is 6 K.The voltmeter reading will be:
f
W
(3) (4)
90
(1) 6V (2) 5V
(3) 4V (4) 3V
RESONANCE JPJMT1251113C0 - 7
34. In the diagram shown, no relative motion 36. A river is flowing with a speed of 1 km/hr. A
takes place between the wedge and the swimmer wants to go to point 'C' starting from
block placed on it. The rod slides downwards 'A' . He swims with a speed of 5 km/hr, at an
over the wedge and pushes the wedge to angle w.r.t. the river. If AB = BC = 400 m .
move in horizontal direction. The mass M of Then the value of is:
wedge is equal to 1kg and is same as that of
1
the block. If tan = , find the mass of rod.
3
(1) 1kg
(2) 2kg
(3) 3kg
(4) 4kg
RESONANCE JPJMT1251113C0 - 8
39. A stone is projected with speed u aiming the 41. At an instant particle-A is at origin and moving
mango at some height from ground as shown
with constant velocity (3 i 4 j ) m / s and
in figure. At the instant of projection of stone
particle-B is at (4,4)m and moving with constant
the mango released (dropped) from the tree.
Then which of the following is correct. (Distance velocity ( 4 i 3 j ) m / s . Then at this instant which
between foot of tree and point of projection is of the following options is incorrect :
less then R(Range)
(1) relative velocity of B w.r.t. A is ( i 7 j) m / s
RESONANCE JPJMT1251113C0 - 9
43. A man standing on a truck which moves with 45. A prism produces same deviation 40 for two
a constant hor izont al accelerat ion different angles of incidence 37 and 42 in
2
a (= 10 m/s ) when speed of the truck is same surrounding medium on both sides. Then
10 m/s. The man throws a ball with velocity prism angle is :
5 2 m/s with respect to truck. In the direction (1) 30
x1 x 2
(3) (4) x1 + x2
2
RESONANCE JPJMT1251113C0 - 10
49. Two point charges (q1 and q2) are placed on
SECTION - II
x-axis. Figure shows graph of potential (V) on
Straight Objective Type x-axis with x-co-ordinate distance x1 and x2
This section contains 10 multiple choice shown in figure then which of the following
questions. Each question has choices (1), (2), option is true :
(3), (4) and (5) out of which ONLY ONE is
correct. V
x1
(1) q1 x q2
2
R (2) q2 > 0
(1) electric potential at (0,3R,0) is 4
0
x12
(3) q1 q2
R x 22
(2) electric potential at (0,0,0) is 2
0
RESONANCE JPJMT1251113C0 - 11
50. Two concentric rings, one of radius R and total 52. A block of mass 1 kg is at rest relative to a
charge +Q and the second of radius 2R and smooth wedge being moved leftwards with
total charge 8 Q, lie in x-y plane (i.e., z = 0 constant acceleration 5m/s2. Let N be the
plane). The common centre of rings lies at origin normal reaction between the block and the
and the common axis coincides with z-axis. The wedge. Then N and tan are :
charge is uniformly distributed on both rings.
The net electric field on z-axis is zero at a
8R
distance from origin. Then find x.
( 2 )x
1
(1) N = 5 5 N and tan =
2
z 1
(2) N = 15 N and tan =
2
(3) N = 5 5 N and tan = 2
51. A nonconducting circular ring is having charge 53. Two coaxial rings are separated by a distance
distribution as shown in figure. Find electric field x. R is radius of larger ring having charge Q
intensity at the centre of ring : uniformly distributed on it.The other ring is
having very small radius r (<<R) then magnitude
of electric flux through smaller ring due to larger
ring is maxium if x is equal to :
R
(1) 0 (2)
3
R R
(3) (4)
3 2
(1) 9 103 N/C (2) 5.4 103 N/C
(5) R
(3) 5.4 104 N/C (4) 2.7 x 104 N/C
(5) Zero
(SPACE FOR ROUGH WORK)
RESONANCE JPJMT1251113C0 - 12
54. The capacitance of a parallel plate air capacitor 56. I n t he capacit or discharg e f or m ula
is 1F. This region is now filled with a dielectric q = q 0 et/ the symbol represents :
slab of dielectric constant 4 and capacitor is (1) the time, it takes for capacitor to loose
connected with battery of EMF 5 volt and zero q 0/e charge.
internal resistance. Now slab is taken out, then (2) the time it takes for capacitor to loose
during the removal of slab then which of the
1
following options is incorrect : charge q0 1
e
(1) 15C charge flows through the cell
(3) the time it takes for capacitor to loose
(2) 75J energy is absorbed by the cell
essentially all of its initial charge.
(3) energy stored in the capacitor is reduced
(4) time in which charge of capacitor
by 75J
becomes half of initial value
(4) the external agent has to do 37.5 J amount
(5) none of the above.
of work to take out the slab
(5) charge on capacitor reduced by 15 C
57. Figure shows a hemisphere of charge Q and
radius R and a sphere of charge 2Q and radius
55. The spherical planets have the same mass but R. The total potential energy of hemisphere is
densities in the ratio 1: 8. For these planets, UH and that the sphere is US. Then.
the :
(1) acceleration due to gravity will be in the ratio
4:1
(2) acceleration due to gravity will be in the ratio
1:4
(3) escape velocities from their surfaces will be
in the ratio 2 : 1
(1) 2UH = US
(4) escape velocities from their surfaces will be
(2) 2UH < US
in the ratio 1 : 2
(3) 2UH > US
(5) ratio of radius of two planet is 1 : 2
(4) UH = US
(5) Data insefficient
RESONANCE JPJMT1251113C0 - 13
60. Statement-1: The gravitational force between
SECTION - III
Reasoning Type a thin rod of finite length and a disc of infinite
This section contains 3 reasoning type radius is inversely proportional to the square of
questions. Each question has 4 choices (1), distance between their centre of mass. Mass is
(2), (3) and (4), out of which ONLY ONE is uniformly distributed on both.
correct.
RESONANCE JPJMT1251113C0 - 14
PART- C
Atomic masses : [H = 1, D = 2, Li = 7, C = 12, N = 14, O = 16, F = 19, Na = 23, Mg = 24,
Al = 27, Si = 28, P = 31, S = 32, Cl = 35.5, K = 39, Ca = 40, Cr = 52, Mn = 55, Fe = 56, Cu = 63.5,
Zn = 65, As = 75, Br = 80, Ag = 108, I = 127, Ba = 137, Hg = 200, Pb = 207]
SECTION - I
Straight Objective Type
This section contains 17 questions. Each question has five choices (1), (2), (3), and (4) for its
answer, out of which ONLY ONE is correct.
61. CsBr has b.c.c. structure with edge length 63. Two Ist order reactions have half-lives in the
4.3 . The shortest inter ionic distance in ratio 3 : 2. Then the ratio of time intervals t1 :
between Cs+ and Br is : t2 , will be? Where t1 is the time period for
(1) 3.72 (2) 1.86 25% completion of the first reaction and t2 is
(3) 7.44 (4) 4.3 time required for 75% completion of the
second reaction. [log 2 = 0.3, log 3 = 0.48]
62. In hcp (ABAB...) and ccp (ABCABC...) (1) 0.2 : 1 (2) 0.42 : 1
structures made up of spheres of equal (3) 0.28 : 1 (4) 0.3 : 1
size, the volume occupied per sphere
(including the empty spaces) is (a = radius 64. For a certain reaction the variation of the rate
of sphere) : constant with temperature is given by the
(1) 5.66 a3 (2) 1.33 a3 equation
3 3
(3) 2.66 a (4) 7.40 a
ln 3
ln kt = ln k0 + 10 t (t 0C)
RESONANCE JPJMT1251113C0 - 15
65. Which of the following is wrong : 68. If HA + NaOH NaA + H2O
(1) Enthalpy (numerical value) of
H = 12 kcal
physisorption is greater than that of
and HB + NaOH NaB + H2O
chemisorption
(2) Physisorption is not very specific but H = 11 kcal
chemisorption is highly specific then equimolar solution of which acid has
(3) Chemisorption takes place at relatively higher pH -
high temperatures (1) HA
(4) In physisorption generally multi (2) HB
molecular layers are formed on the (3) both have same pH
adsorbent (4) information insufficient
66. Which of the following ions will be most 69. Barium ions, CN and Co2+ form an ionic
(1) Fe3+ (2) Ba2+ ionised in water with vant Hoff factor (i) equal
to four, then the coordination numbers of
(3) Cl (4) PO 34
Co2+ in the complex can be:
(1) 6
67. Electrolysis of a solution of HSO4
ions (2) 4
produces S2O 8
. Assuming 75% current (3) 6 & 4 both possible
efficiency, what current should be (4) 5
employed to achieve a production rate of
1 mole of S2O8 per hour ? 70. A solution of 0.2 mole KI ( = 100%) in 1000
(1) 71.5 amp (2) 35.7 amp g water freezes at T1 0C. Now to this solution
(3) 142.96 amp (4) 285.93 amp 0.1 mole Hg2 is added and the resulting
solution freezes at T 2 0C. Which of the
following is correct :
(1) T1 = T2 (2) T1 > T2
(3) T1 < T2 (4) Can't be prediced
RESONANCE JPJMT1251113C0 - 16
71. In the reaction CrO5 + H2SO4 Cr2(SO4)3 75. 16 gm of an ideal gas SOx occupies 5.6 lt.
+ H2O + O2 one mole of CrO5 will liberate at STP. The value of x is
how many moles of O2 (1) x = 3 (2) x = 2
(1) 5/2 (2) 5/4 (3) x = 4 (4) none
(3) 9/2 (4) none of these
76. The volume occupied by 2.0 mole of N2 at
72. In the following reaction 2MnO4 + 5H2O218 PC VC 3
+ 6H+ 2Mn2+ + 8H2O + 5O2 200 K and 8.21 atm pressure, if RT =
C 8
The radioactive oxygen will appear in :
(1) H2O Pr Vr
and Tr = 2.4, is
(2) O2
(3) both
(4) above reaction does not take place 5
(1) 1.8 L (2) 8 L
73. 20 ml of H2O2 after acidification with dil (3) 12.8 L (4) 3.6 L
N
H2SO4 required 30 ml of KMnO4 for 77. The increase in volume of air, when
12
temperature of 600 ml of it, is increased from
complete oxidation. The strength of H2O2
27C to 47C under constant pressure, is :
solution is [Molar mass of H2O2 = 34]
(1) 20 mL (2) 80 mL
(1) 2 g/L (2) 4 g/L
(3) 40 mL (4) 500 mL
(3) 8 g/L (4) 6 g/L
RESONANCE JPJMT1251113C0 - 17
80. When a graph is plotted between log x/m
SECTION - II and log p, it is straight line with an angle 45
Straight Objective Type and intercept 0.3010 on y-axis. If initial
This section contains 10 questions. Each pressure is 0.3 atm, what will be the amount
question has five choices (1), (2), (3), (4) of gas adsorbed per gm of adsorbent :
and (5) for its answer, out of which ONLY (1) 0.4 (2) 0.6
ONE is correct. (3) 0.8 (4) 0.1
(5) 0.5
78. A crystal of formula AB3 has A ions at the
cube corners and B ions at the edge centres.
81. The reduction potential of hydrogen half cell
The coordination numbers of A and B are
will be negative if (T = 298 K)
respectively
(1) 6 and 6 (2) 2 and 6 (1) PH2 = 1 atm and [H+] = 1.0 M
(3) 6 and 2 (4) 8 and 8
(5) 8 and 6 (2) PH2 = 2 atm and [H+] = 2.0 M
79. For the following parallel chain reaction (3) PH2 = 2 atm and [H+] = 1.0 M
RESONANCE JPJMT1251113C0 - 18
83. 3 mole of a mixture of FeSO4 and Fe2(SO4)3 86. At 27C the ratio of rms velocities of ozone
required 100 ml of 2M KMnO4 solution in to oxygen is
acidic medium. Hence mole fraction of
(1) 5/5 (2) 4/3
FeSO4 in the mixture is
(3) 2/3 (4) 0.25
3 2
(1) (2)
5 3
(5) 3/4
2 1
(3) (4)
5 3 87. Equal amount (mass) of methane and
ethane have their total translational kinetic
5
(5) energy energy in the ratio 3 : 1 then their
2
temperatures are in the ratio.
(1) 5 : 8 (2) 45 : 8
84. Common salt obtained from sea - water
(3) 15 : 8 (4) 8 : 5
contains 96% NaCl by mass. The
(5) 8 : 15
approximate number of molecules present
in 10.0 g of the salt is (At. wt. Na = 23)
SECTION - III
(1) 1021 (2) 1022
Comprehension Type
(3) 1023 (4) 1024
(5) 1025 This section contains 1 paragraphs. Based
open each paragraph, there are 3
85. A mixture of HCl(g), PCl3(g) and PCl5(s), questions. Each question has 4 choices (1),
each have equal number of Cl-atom then (2), (3) and (4), out of which ONLY ONE is
their molar ratio in the mixture is : correct.
(1) 1 : 3 : 5 (2) 1 : 1 : 1
(3) 15 : 2 : 3 (4) 15 : 5 : 3
(5) 15 : 3 : 2
RESONANCE JPJMT1251113C0 - 19
Paragraph for Question Nos. 88 to 90 89. While Fe3+ is stable, Mn3+ is not stable in acid
solution because :
Redox reactions play a pivotal role in
chemistry and biology. The values of (1) O2 oxidises Mn2+ to Mn3+
standard redox potential (E) of two half-cell (2) O2 oxidises both Mn2+ to Mn3+ and Fe2+ to
reactions decide which way the reaction is Fe3+
expected to proceed. A simple example is a (3) Fe3+ oxidises H2O to O2
Daniel cell in which zinc goes into solution (4) Mn3+ oxidises H2O to O2
and copper gets deposited. Given below are
a set of half-cell reactions (acidic medium) 90. Sodium fusion extract, obtained from aniline,
along with their E (V with respect to normal on treatment with iron (II) sulphate and
hydrogen electrode) values. H2SO4 in presence of air gives a Prussian
RESONANCE JPJMT1251113C0 - 20