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Resources, Conservation and Recycling 104 (2015) 311316

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Resources, Conservation and Recycling


journal homepage: www.elsevier.com/locate/resconrec

Full length article

An industrial ecology approach to municipal solid waste


management: I. Methodology
R.L. Smith a, , D. Sengupta a,b,1 , S. Takkellapati a , C.C. Lee a
a
Sustainable Technology Division, National Risk Management Research Laboratory, U.S. Environmental Protection Agency, Cincinnati, OH 45268, USA
b
Oak Ridge Institute for Science and Education (ORISE), Oak-Ridge, TN 37830, USA

a r t i c l e i n f o a b s t r a c t

Article history: Municipal solid waste (MSW) can be viewed as a feedstock for industrial ecology inspired conver-
Received 17 October 2014 sions of wastes to valuable products and energy. The industrial ecology principle of symbiotic processes
Received in revised form 20 February 2015 using waste streams for creating value-added products is applied to MSW, with examples suggested for
Accepted 11 April 2015
various residual streams. A methodology is presented to consider individual waste-to-energy or waste-
Available online 28 August 2015
to-product system synergies, evaluating the economic and environmental issues associated with each
system. Steps included in the methodology include identifying waste streams, specic waste components
Keywords:
of interest, and conversion technologies, plus steps for determining the economic and environmen-
Industrial ecology
Municipal solid waste
tal effects of using wastes and changes due to transport, administrative handling, and processing. In
MSW addition to presenting the methodology, technologies for various MSW input streams are categorized
Energy as commercialized or demonstrated to provide organizations that are considering processes for MSW
Sustainability with summarized information. The organization can also follow the methodology to analyze interesting
processes.
Published by Elsevier B.V.

1. Introduction and background the potential uses of materials in different contexts. The adage
that one mans waste is another mans treasure clearly indicates
Frosch and Gallopoulos (1989) introduced the term industrial that this is not a new idea. In this contribution a method is sug-
ecology. They called it an industrial ecosystem. In such a system gested for identifying and realizing the use of otherwise discarded
the consumption of energy and materials is optimized, waste gen- materials.
eration is minimized and the efuents of one process. . . serve as To begin a study on using discards as valuable materials it makes
the raw material for another process. At about the same time sense to rst identify the materials under consideration (Table 1)
Aryes (1989) wrote of an industrial metabolism that needed to and the operations used to manage them. In this work the materials
have increased efciency in the use of by-products. In this work of interest fall under the category of municipal solid waste (MSW),
the waste or by-products of interest are the streams of munici- a term which rose out of local communities caring for sanita-
pal solid waste generated by communities. A method is presented tion, avoiding epidemics, advancing public health, and maintaining
to analyze processes that perform industrial ecology, i.e., to view refuse infrastructure, as well as a result of the circumstances of
wastes as potential feedstocks and turn them into valuable prod- the times (Louis, 2004). MSW denitions are found in the Resource
ucts and/or energy with the intent of preserving valuable resources Conservation and Recovery Act (RCRA) as a subset of nonhazardous
and producing less pollution. solid waste regulated under Subtitle D (U.S. EPA, 2011, 2014b).
The term waste is out of favor because it implies something to be Implementation of MSW management is often administered by
discarded. A different way of thinking occurs by using the term sus- municipalities and operated by regional-based privately-owned
tainable materials management to capture the ideas of productivity facilities (Louis, 2004). MSW is only a portion of total solid waste.
and sustainability (U.S. EPA, 2014a). Waste does not recognize MSW refers to everyday items discarded from residences, busi-
nesses, and institutions, but is separate from construction debris,
wastewater treatment waste, or other nonhazardous industrial
process waste (U.S. EPA, 2013). Items that are part of MSW include
Corresponding author. Tel.: +1 513 569 7161; fax: +1 513 569 7677.
corrugated boxes, food waste, plastic lm, bottles, cans, newspa-
E-mail address: smith.raymond@epa.gov (R.L. Smith).
1
Present address: Artie McFerrin Department of Chemical Engineering, Texas per and ofce paper, wood pallets, and yard waste, with a more
A&M University, College Station, TX 77843, USA. complete list available from U.S. EPA (2013). These denitions also

http://dx.doi.org/10.1016/j.resconrec.2015.04.005
0921-3449/Published by Elsevier B.V.
312 R.L. Smith et al. / Resources, Conservation and Recycling 104 (2015) 311316

Table 1
MSW average percentage waste types for U.S., and average amounts of each type 1 Reduce / Reuse Conserved
for 100,000 people (U.S. EPA, 2014c). MSW Generation
Resources

Waste type Average U.S. Tonnes per Millions of


percentage (%) year for pounds per
100,000 people year for Compost
2
100,000 people
Composting
Paper and 27.4 19,834 43.73
paperboard 2
Glass 4.6 3344 7.37 Recycled
Recycling
Metals 8.9 6469 14.26 Feedstocks
Plastics 12.7 9177 20.23 Recycling Center /
Rubber and leather 3.0 2176 4.80 Transfer Station /
Textiles 5.7 4142 9.13 Material Recovery
Facility 3 Energy and
Wood 6.3 4573 10.08
Products
Food, other 14.5 10,530 23.21 Waste-to-Energy
Yard trimmings 13.5 9816 21.64
Other materials 1.8 1329 2.93 4
Misc. inorganic 1.6 1127 2.49 Landfill
Landfill
wastes Gas

Total 100.0 72,517 159.87


Fig. 1. An outline of waste management options, showing products along the right
side. The dashed line represents Reduce/Reuse as the products will not be seen
unless accounted for in appropriate measures. Circles with numbers in them refer
indicate that not everything sent to a non-hazardous landll is to the waste management hierarchy.
dened as MSW.
Management of MSW in the past has focused on one specic
solution, t to community needs. There are benets to simple and is performed on 8% of the total MSW. Recycling processes, which
historically successful operations, but the systems are likely not employ a waste as a feedstock for making products, are responsible
optimal or exible. More recently, integrated waste management for using 26% of the MSW generated. Waste-to-Energy inciner-
is the standard (U.S. EPA, 1989). Communities consider how vari- ation, the burning of wastes with energy recovery, accounts for
ous strategies can t into an overall plan to reduce waste generation 12%. That leaves 54% of MSW going to Landlls. Also represented
and control costs and pollution. In addition, the decision process has in Fig. 1 are Recycling Centers/Transfer Stations/Material Recov-
changed. Gone are the days of deciding, announcing, and defend- ery Facilities (MRF), which are needed depending on process and
ing a (MSW) community facility. Today the process is open, with location specics. Recycling Centers are normally drop off loca-
discussions on planning, site selection, facility design, construction, tions where recyclable materials are collected, grouped, and baled,
and operation. Besides obtaining necessary permits, one must com- although some processing like glass crushing can be done at Recy-
municate about risks and the sharing of benets and impacts (U.S. cling Centers. Transfer Stations provide a exible staging location
EPA, 1995). where waste is consolidated into larger vehicles to reduce ship-
A plan for integrated solid waste management should include ping costs. MRFs separate recyclables into uniform pools (Pinellas
objectives; demographics regarding population and geography; County, 2009). A further distinction can be made between Clean
recent waste data, including characteristics and amounts; pro- MRFs and Dirty MRFs, with a Clean MRF accepting single or dual
jected waste assumptions; MSW options and monitoring of stream recyclables, while a Dirty MRF separates the recyclables
collection, transport, treatment, and disposal for various types of from the rest of the MSW.
waste ows; and the evaluation of options which considers per- For sustainable solutions to waste management, those inter-
formance and the environmental, economic, and social aspects of ested in considering the socially acceptable processes and products
sustainability (World Bank, 2012). Average data on MSW in the U.S. represented in Fig. 1 can perform analyses of the environmental and
is collected and summarized regularly by the EPA (U.S. EPA, 2014c), economic aspects. These analyses should be done with information
and an example waste analysis for a community of 100,000 people relevant to the specic location and circumstances. Here, a method
is presented in Table 1. Individual communities will have specic is presented which allows an industrial ecology perspective to be
actual ows that can vary from the averages presented in Table 1. followed.
The actual ows are more important when specic processing of
each is considered, where both amount and quality can be relevant
criteria. 2. Industrial ecology
Processes for recycling, transforming, and treating (constituents
of) MSW are available for those developing an integrated solid The term industrial ecology considers a whole system of inter-
waste management plan. Fig. 1 shows how MSW can move ested parties who create desired products and exchange their
through various processes and achieve valuable outputs. The out- wastes to generate a positive system result. Industrial ecology
puts include Conserved Resources that are a positive result of appeals because it suggests that an industrial system can follow the
reducing and reusing, and other products listed down the right side principles of ecology in using wastes and doing so in an economic
of Fig. 1. The circled numbers in the gure correspond to the waste way. Both industrial and ecological systems have ows of mass and
management hierarchy (U.S. EPA, 2013). In part two of this work energy, and both can benet from mutualism, where associations
(Smith et al., 2015) the Waste-to-Energy process box in Fig. 1 will form to benet both parties involved. Chertow (2007) suggests
be expanded and various transformations (not only incineration) that industrial ecology systems most often emerge through self-
will be evaluated. organized symbiosis to reduce costs, enhance revenues, or expand a
The processes of Fig. 1 (reporting statistics from U.S. EPA, 2014c) business, while Burstrom and Korhonen (2001) put forth a concept
include MSW Generation, with the U.S. generating 251 million tons of municipalities acting as both physical anchors that drive regional
(228 million tonnes) of MSW per year. Composting, the aerobic material and energy ows and institutional anchors that provide
biodegradation of part of the organic fraction of MSW (OFMSW), infrastructure, education, and support for industrial ecology.
R.L. Smith et al. / Resources, Conservation and Recycling 104 (2015) 311316 313

Table 2 One consideration to be aware of in considering new industrial


MSW processes, their products and residual streams, and potential uses for the resid-
ecology uses for MSW streams is the legitimacy of recycling. That
uals. Waste-to-Energy (WTE) processes listed are expanded in Smith et al. (2015).
Listing as a use does not indicate regulatory acceptance. is, to be certain that processes are done to be benecial, not to treat
waste. While it is acceptable to deal with MSW under RCRA Subtitle
MSW process Product(s) Residuals Use for residual
D, the residual ows may no longer be MSW. There are many EPA
stream
documents on the topic of legitimate recycling. The ideas behind
MSW generation Compostable Non-compostable, Heat value, determining whether processing is legitimate or sham recycling
and recyclable non-recyclable recycling
include the value of the new material and the relative amount of
materials materials research
opportunity processing it takes to make it, whether there is a market for the
Composting Compost Contaminants Glass and material, and whether it is handled as other raw materials and
(glass, plastics) plastic products are (U.S. EPA, 2014d). The material has to be effective in
recycling, heat
its proposed use, and it should not be used in excess. If it is not clear
value
Recycling center/ Separated Non-compostable, Heat value, whether a residual is still treated as MSW or if a specic process is
transfer station/ recyclable non-recyclable recycling not documented as legitimate recycling, it is likely a good idea to
MRF materials materials research check with the appropriate regulator.
opportunity
WTElignocellulosic Ethanol Lignin; CO2 Heat value,
fermentation products;
beverages, 3. Similarities to chemical processes
algal process
WTEgasication Syngas, then Ash/slag Construction When considering any of the potential uses of waste-generated
(with conversion ethanol materials
feedstocks (i.e., residuals), a number of important issues must be
to ethanol)
WTEanaerobic Biogas, then Digestate slurry Composting,
addressed. Technology, feedstock supply, and product-offtake reli-
digestion power fertilizer ability are all crucial to developing a new process (Smith et al.,
WTEincineration Power Ash Construction 2013). This is so for chemical processes and waste-generated feed-
materials stock ones. Because of this similarity this discussion will parallel
some aspects of chemical process design, with the understanding
A review of aspects of industrial ecology has been presented that the reader can apply them to waste-generated processes.
by Smith (2004), the most important of which in an MSW context A common idea in chemical processes is to convert a low-cost
is exchanging waste. Other researchers have explored waste man- feedstock into a higher-value product. This difference in price for
agement from an input-output perspective (Nakamura and Kondo, the product minus the feedstock is known as a margin or spread. In
2009), life cycle assessment (LCA) for a management district (Buttol the case of petroleum rening the spread is known as the crack
et al., 2007), LCA for management scenarios (De Feo and Malvano, spread (the price of dened products minus that of crude oil).
2009), and LCA for MSW management in a large growing city (Hadi For corn to ethanol conversions it is known as the grind mar-
et al., 2012). Geng et al. (2010) studied the potential for MSW use gin (value of products minus feedstock and energy costs). Smith
(urban symbiosis) in the city of Kawasaki to avoid greenhouse gases et al. (2013) proposed that the MSW eld develop similar terms for
and use of landll space. the corresponding product-feedstock combinations. For instance, a
Exchanging waste suggests that all of the processors of Fig. 1 pro- pelletized material made of the organic fraction of MSW (OFMSW)
duce desirable products and one or more streams of lesser value. could be made into Refuse-Derived Fuel (RDF). The term would
In Fig. 1, one can think of MSW Generation as producing desired then be a RDF-OFMSW spread. Another example would consider a
compostable material and recyclable material, with a lesser value more-fully processed product, e.g., biogas or ethanol, so one could
stream being the material sent to landll. Composting produces have biogas-OFMSW and ethanol-OFMSW spreads. The benet of a
compost and a lesser value stream of contaminants. The key idea product-feedstock spread is that people familiar with the processes
here is to nd the value in the material sent to landll and in involved develop an understanding for when specic conversion
the compost contaminants. In these examples the landll mate- processes will be protable, because they also know the other costs
rial might have heat value, and the compost contaminants might for the process. A margin or spread can be combined with the other
include glass or plastics of value. Table 2 shows processes of Fig. 1, costs to quickly determine protability. For example, the grind
their product and residual streams, and potential uses for the resid- margin lets people in the biorenery industry know when their
uals. Note that this raises an important aspect of terminology and processes will make money, and sometimes news articles report
ones point of view. One can speak about treating waste: that is that a biorenery has temporarily shut down, almost always during
changing its characteristics to minimize its threat to the environ- a time of low protability.
ment. Or residuals can be perceived as potential process feedstocks. The reliability of feedstock supply and product offtake is another
Changing ones point of view regarding this dichotomy of treating critical aspect to consider. A chemical process or product-MSW pro-
wastes or processing feedstocks is an important aspect of imple- cess may have a protable product-feedstock margin or spread,
menting industrial ecology. Without a perspective that sees value but that is of little value if the feedstock supply or ability to sell
in residual streams they will be treated as waste. Seeing a stream the product are unreliable. Companies developing new processes
as a potential feedstock provides an opportunity to exchange or spend time and effort establishing reliable agreements to buy and
process it for value. sell what they need. An example where this was not established
The idea in listing processes, products, residuals, and uses for for MSW is the city of Harrisburg, PA, where reports indicate that
residuals in Table 2 is that each process leads to products and expected MSW was not available for the constructed incinerator,
residuals, and the residuals may be useful in another context. leading to very large costs for the city (Luciew, 2011).
While Table 2 presents examples, future possibilities are open. For The technology for converting the feedstock to product also
instance, if CO2 is used in algal fuel processes, where oil is removed needs to be reliable. This need for reliable processes is addressed
from the algae for biodiesel production, then what opportunities in the methodology below.
exist for using the remaining parts of the algae? Is it only valuable In many ways MSW processes are similar to chemical processes,
as biomass, or could there be specic components or properties however, they differ because there is a social benet of dealing
that make it more valuable? with MSW. Communities want MSW solutions, which can lead to
314 R.L. Smith et al. / Resources, Conservation and Recycling 104 (2015) 311316

Fig. 2. Technologies that can process/handle various portions of MSW (see footnotes). Plastics nos. 1 and 2 refer to polyethylene terephthalate (used often in bottles) and high-
density polyethylene (used in milk jugs, bottles, tubs, and some bags), respectively. Plastics nos. 37 represent polyvinyl chloride, low-density polyethylene, polypropylene,
polystyrene, and other.

processes being built. It can also mean community involvement in Within a stream it may be that only certain components are
what is being done. Stakeholders might be interested in the number valuable. The evaluator of a new process for waste conversion to
of truck trips, dust, odors, emissions, water-based releases, litter, valuable products needs to identify these components, the amount,
nuisances, etc. As an example of how important these issues could and the concentration. For instance, a valuable component in a
potentially be, Mannies and LaCapra (2014) report that a landll waste stream may be at such a low concentration that its separation
will pay $4.6 million for odors due to an underground re. and processing prove to be uneconomical and/or negative for the
environment. At this point it is important to know the amount and
4. Methodology for attaining industrial ecology concentration. Evaluations will be done in future steps (Table 3).
The third step is knowing the new technology (i.e., the alter-
A systematic procedure is proposed here for considering indus- native) used to obtain the waste-generated product. There may be
trial ecology uses of various MSW-related streams. The procedure a number of potential technologies that can convert an identied
starts with identifying waste streams for consideration. These may waste stream into valuable products. Fig. 2 shows current facili-
be obvious in a community that has specic existing processes and ties/technologies that have been commercialized or demonstrated
streams. Others may be less obvious as shown in Table 2, where for converting waste streams into more valuable products, as well
potential uses for residuals were listed. Identifying a waste stream as technologies that can handle a waste component without using it
is a rst step (Table 3). The economic value and environmental productively. Knowing that a MSW component can be handled can
impacts need to be considered in future steps. be important so that overly cumbersome sorting and pretreatment
steps are avoided. However, the reality may be that a process works
better for uniform feedstocks, so it is important to understand the
Table 3 details.
Steps in evaluating alternative waste processes. The facilities/technologies shown in Fig. 2 are described here,
(1) Identify waste streams and footnotes have been provided for some of them in the g-
(2) Identify waste components ure. Specic Recycling Processes are tuned directly to recover
(3) Identify current baseline technologies, and identify alternative a specic MSW component, e.g., aluminum. As described ear-
technologies for converting waste streams and components
lier, MRFs separate mixed streams into desirable lots for further
(4) Determine avoided economic costs and environmental impacts of
using wastes (include avoided transport and administrative processing. Anaerobic Digestion uses microorganisms to break
handling here) down biodegradable material in the absence of oxygen into
(5) Determine the value of the alternative products methane and other reaction products. Gasication reacts carbon-
(6) Determine economic costs and environmental impacts of new based waste at high temperatures by partial oxidation to produce
transport steps
(7) Determine economic costs and environmental impacts of new
a syngas of mostly carbon monoxide and hydrogen. The syngas can
administrative handling be further processed into ethanol by reaction chemistry or by bio-
(8) Determine economic costs and environmental impacts of sorting chemical routes. Fermentation as used here refers to the growth and
and pretreating wastes reaction of microorganisms to convert sugars to ethanol and car-
(9) Determine economic costs and environmental impacts of
bon dioxide. Agricultural plant-wall cellulosic material is currently
converting wastes
(10) Determine economic costs and environmental impacts of purifying being demonstrated/commercialized as the sugar-based feedstock
product streams for making ethanol, and this work assumes that yard waste is a
(11) Adjust the economic costs and environmental impacts for residual reasonable approximation for this agricultural feedstock. Inciner-
wastes ation is the nal technology represented, and it burns materials
R.L. Smith et al. / Resources, Conservation and Recycling 104 (2015) 311316 315

at very high temperature in oxygen (air), producing steam and/or because landlling with gas recovery presents a different baseline
electricity as nal products. for analysis as compared to landlling without recovery.
Before nishing step three, it is important that the baseline Step six of the procedure adds costs and potential environmental
technologies for comparison have been identied. This may be impacts due to new transport done because of the processing of
relatively simple, as it would be common to use the current facil- the waste-generated product. These transport distances could be
ities/technologies as a baseline. In the next step the costs and shorter or longer than the original, and they may involve multiple
environmental releases of baseline activities will be used to create collections in the community.
incentive values (i.e., the potential economic and environmental If there are new administrative handling procedures involved,
gains) for adopting new technologies. then step seven is used to add additional costs and/or environmen-
The fourth step is to determine the avoided economic costs tal impacts.
and potential environmental impacts by using the identied waste The processing of waste is accounted for in steps 810, where
stream with its baseline costs and environmental releases. Also, sorting and pretreating waste, converting, and purifying product
the waste stream may have had baseline costs associated with it, steps occur. These are technical processes which require an under-
for example, due to disposal, which is now avoided. Any baseline standing of the costs, reliability, form of nal product, etc. The
transport or administrative costs associated with the waste may importance of these steps should not be underestimated. Smith
now be saved as well. The total potential value of processing the et al. (2015) provide examples for WTE technologies.
identied waste is the sum of the product value and the baseline Finally, if a residual waste is generated at the end of processing,
savings. Note that these avoided costs may be short-lived, as the the costs and environmental impacts of this residual need to be
steps that follow from Table 3 may add them back in, although per- included. This could require knowledge of the components in
haps in different amounts (i.e., transport costs and environmental the residual stream and their concentrations. One would likely
releases may have been saved based on the baseline case, but new approximate how these will be dealt with and approximate costs
transport costs and releases will be added in for the new process and environmental impacts for them. The total costs and impacts
being considered). accounted for in steps 611 should be summed and compared to
The identied waste should be made into a new valuable prod- the potential avoided costs and impacts developed through step 5.
uct, so the fth step involves calculating the amount of product Higher economic values and reductions in environmental releases
and its value to estimate a total product value. The sum of avoided indicate an alternative for further detailed study.
costs from step four and the product value from step ve provide
an overall economic incentive for considering an alternative pro-
cess. If the total value is not large enough then the analysis can be 5. Discussion
stopped at this point, and different alternatives or variations can be
considered. As alternative costs are added in the following steps the In addition to providing a method for analyzing processes, it
analysis can be stopped at any point where the value is insufcient. could be valuable to discuss the technologies and MSW compo-
Potential environmental impacts may also be avoided due to nents presented in Fig. 2. For details people will have to study each
not processing waste in the baseline method. There are a num- of these more closely, but some generalizations can be pointed out.
ber of ways to account for these impacts. The simplest is to keep For instance, a Dirty MRF and Incineration can handle all types of
track of the inventory of emissions of various types: e.g., VOC, NOx , MSW. This does not mean that they are issue free, but they do
SOx , CO, CO2 , etc. One can also keep track of potential environ- not require (many) pre-treatment steps and MSW can be delivered
mental impacts using impact assessment methods, such as the directly to these facilities. The Specic Recycling Processes are spe-
Tool for the Reduction and Assessment of Chemical and other cic to a material, and so separations need to be very selective.
Impacts (TRACI) (Bare et al., 2003) or the Waste Reduction Algo- Fermentation to ethanol is also selective, in that the current sys-
rithm (Young and Cabezas, 1999). There may be many ways in tems are using corn stover as a feedstock, so using yard waste is an
which impacts could be reduced. For instance, various parts of extrapolation. However, biofuels like ethanol might have a higher
the common production chain of the generated product may be value depending on subsidies/incentives. Anaerobic Digestion and
avoided, because the waste-generated product is displacing the Gasication use a small variety of feedstocks, so some separation is
need to make the product by the common method. Also, various required. Also, these technologies and Fermentation benet from
transportation processes may be avoided, leading to less pollution. shredding their feedstocks into a form of Refuse Derived Fuel (RDF)
Also, the original waste will no longer be causing potential envi- which eases processing.
ronmental impacts. All of these should be considered in developing Another way of considering Fig. 2 is through a consideration
the total avoided potential impacts for an alternative. At this point of the MSW components in the columns. For instance, Metals and
the values determined for potential environmental impact reduc- Glass can only be fed to certain facilities. Food scraps and Fats,
tion are as large as possible, as future steps will add impacts. If the Oils, and Grease are likewise limited in terms of technologies.
potential impact reduction of the alternative is not large enough Plastics and Yard Waste nd more acceptable facilities, and Paper
to incentivize processing the waste at this point, then the process and Paperboard the most. However, without understanding the
is not worthwhile, and other alternatives or variations should be technologies, it may not be clear that the products of these dif-
considered. ferent acceptable technologies are so varied. While a Dirty MRF
Among the benets of processing waste into useable forms could might separate some (inadvertently discarded) Yard Waste into an
be the reduction in landll space used. If this is important, then the organic stream, Anaerobic Digestion will process Yard Waste into
cost of new space in a landll could be added to the savings for not useful methane. Similarly, a Clean MRF might separate Plastics 1
sending materials to a landll. Another benet of not landlling and and 2, a Gasication process might turn them into syngas and
thus not creating landll gas is the reduction in emissions of these other products, while a Specic Recycling Process could convert
greenhouse gases (although they can be captured). This highlights them into other useful solid products. Thus, Fig. 2 should be used
the idea that people need to recognize all of the costs of MSW. For as a starting point for considering technologies and various MSW
example, if people do not experience the costs of landll opera- streams.
tion, closure, cleanup, and pollution, they may not understand the As for Plastics 37, they can be recycled, but the markets
need to reduce, reuse, recycle, or nd other uses for materials. The are not largely developed (Association of Postconsumer Plastic
complexity of the analysis is also highlighted with this example Recyclers, 2014). For instance, polyvinyl chloride (PVC) (3) is
316 R.L. Smith et al. / Resources, Conservation and Recycling 104 (2015) 311316

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