Nombre del alumno QUMICA ANALTICA II - SEMESTRE 2017-II - TAREA SEMANA 3

Fecha de entrega: 20/febrero/2017

Determinacin de plomo mediante titulacin con EGTA

Reaccin principal + ^( logK = 13.0 Para generar

Pb/OH +) L/H absoluta a u
para tomar un
_1 _2
_3 _1 _2 _3 _4
_^(/) que se mu
_^(/) _^(/)
6.2 10.3 13.3 9.5 8.9 2.7 2.1 seleccionada)
1.58E+06 2.00E+10 2.00E+13 _1 _2 _3 _4 quieres refe
PbL/H _^(/) _^(/) _^(/) _^(/) M/OH uti
En los cuadros verdes coloca 9.5 18.4 21.1 23.2
el valor de log de la constante,
_1 de acuerdo con las tablas del 3.16E+09 2.51E+18 1.26E+21 1.58E+23
_^(/) Ringbom (slo un decimal).
5.3 En las celdas blancas calcula el
2.00E+05 valor de .

Sin aproximacin
pH [ ^ [ _( _( _(
0 +] 1 ^]1E-14 ())
6.88E-09 ()) 5.30E+00 _-4.90E+00
2.32E+01 ())
0.1 0.794328235 1.25893E-14 8.67E-09 2.28E+01 5.20E+00 -4.60E+00
0.2 0.630957344 1.58489E-14 1.09E-08 2.24E+01 5.10E+00 -4.31E+00
0.3 0.501187234 1.99526E-14 1.37E-08 2.20E+01 5.00E+00 -4.01E+00
0.4 0.398107171 2.51189E-14 1.73E-08 2.16E+01 4.90E+00 -3.71E+00
0.5 0.316227766 3.16228E-14 2.18E-08 2.12E+01 4.80E+00 -3.41E+00
0.6 0.251188643 3.98107E-14 2.74E-08 2.08E+01 4.70E+00 -3.11E+00
0.7 0.199526231 5.01187E-14 3.45E-08 2.04E+01 4.60E+00 -2.82E+00
0.8 0.158489319 6.30957E-14 4.34E-08 2.00E+01 4.50E+00 -2.52E+00
0.9 0.125892541 7.94328E-14 5.47E-08 1.96E+01 4.40E+00 -2.23E+00
1 0.1 1E-13 6.88E-08 1.92E+01 4.30E+00 -1.93E+00
1.1 0.079432823 1.25893E-13 8.67E-08 1.88E+01 4.20E+00 -1.64E+00
1.2 0.063095734 1.58489E-13 1.09E-07 1.85E+01 4.10E+00 -1.35E+00
1.3 0.050118723 1.99526E-13 1.37E-07 1.81E+01 4.00E+00 -1.07E+00
1.4 0.039810717 2.51189E-13 1.73E-07 1.77E+01 3.90E+00 -7.83E-01
1.5 0.031622777 3.16228E-13 2.18E-07 1.73E+01 3.80E+00 -5.03E-01
1.6 0.025118864 3.98107E-13 2.74E-07 1.69E+01 3.70E+00 -2.27E-01
1.7 0.019952623 5.01187E-13 3.45E-07 1.66E+01 3.60E+00 4.24E-02
1.8 0.015848932 6.30957E-13 4.34E-07 1.62E+01 3.50E+00 3.06E-01
1.9 0.012589254 7.94328E-13 5.47E-07 1.58E+01 3.40E+00 5.62E-01
2 0.01 1E-12 6.88E-07 1.55E+01 3.30E+00 8.10E-01
2.1 0.007943282 1.25893E-12 8.67E-07 1.52E+01 3.20E+00 1.05E+00
2.2 0.006309573 1.58489E-12 1.09E-06 1.48E+01 3.10E+00 1.28E+00
2.3 0.005011872 1.99526E-12 1.37E-06 1.45E+01 3.00E+00 1.49E+00
2.4 0.003981072 2.51189E-12 1.73E-06 1.42E+01 2.90E+00 1.70E+00
2.5 0.003162278 3.16228E-12 2.18E-06 1.39E+01 2.80E+00 1.89E+00
2.6 0.002511886 3.98107E-12 2.74E-06 1.36E+01 2.70E+00 2.08E+00
2.7 0.001995262 5.01187E-12 3.45E-06 1.34E+01 2.60E+00 2.25E+00
2.8 0.001584893 6.30957E-12 4.34E-06 1.31E+01 2.50E+00 2.41E+00
2.9 0.001258925 7.94328E-12 5.47E-06 1.28E+01 2.40E+00 2.56E+00
3 0.001 1E-11 6.88E-06 1.26E+01 2.30E+00 2.71E+00
3.1 0.000794328 1.25893E-11 8.67E-06 1.24E+01 2.20E+00 2.84E+00
3.2 0.000630957 1.58489E-11 1.09E-05 1.21E+01 2.10E+00 2.98E+00
3.3 0.000501187 1.99526E-11 1.37E-05 1.19E+01 2.00E+00 3.10E+00
3.4 0.000398107 2.51189E-11 1.73E-05 1.17E+01 1.91E+00 3.22E+00
3.5 0.000316228 3.16228E-11 2.18E-05 1.15E+01 1.81E+00 3.34E+00
3.6 0.000251189 3.98107E-11 2.74E-05 1.13E+01 1.71E+00 3.46E+00
3.7 0.000199526 5.01187E-11 3.45E-05 1.10E+01 1.61E+00 3.57E+00
3.8 0.000158489 6.30957E-11 4.34E-05 1.08E+01 1.51E+00 3.68E+00
3.9 0.000125893 7.94328E-11 5.47E-05 1.06E+01 1.42E+00 3.79E+00
4 0.0001 1E-10 6.88E-05 1.04E+01 1.32E+00 3.90E+00
4.1 7.94328E-05 1.25893E-10 8.66E-05 1.02E+01 1.23E+00 4.01E+00
4.2 6.30957E-05 1.58489E-10 1.09E-04 1.00E+01 1.13E+00 4.12E+00
4.3 5.01187E-05 1.99526E-10 1.37E-04 9.81E+00 1.04E+00 4.23E+00
4.4 3.98107E-05 2.51189E-10 1.73E-04 9.61E+00 9.51E-01 4.34E+00
4.5 3.16228E-05 3.16228E-10 2.18E-04 9.41E+00 8.64E-01 4.46E+00
4.6 2.51189E-05 3.98107E-10 2.74E-04 9.21E+00 7.79E-01 4.57E+00
4.7 1.99526E-05 5.01187E-10 3.45E-04 9.00E+00 6.97E-01 4.69E+00
4.8 1.58489E-05 6.30957E-10 4.34E-04 8.80E+00 6.19E-01 4.82E+00
4.9 1.25893E-05 7.94328E-10 5.46E-04 8.60E+00 5.46E-01 4.94E+00
5 0.00001 0.000000001 6.88E-04 8.40E+00 4.76E-01 5.07E+00
5.1 7.94328E-06 1.25893E-09 8.66E-04 8.20E+00 4.12E-01 5.21E+00
5.2 6.30957E-06 1.58489E-09 1.09E-03 8.00E+00 3.54E-01 5.35E+00
5.3 5.01187E-06 0.000000002 1.37E-03 7.80E+00 3.01E-01 5.50E+00
5.4 3.98107E-06 2.51189E-09 1.73E-03 7.60E+00 2.54E-01 5.65E+00
5.5 3.16228E-06 3.16228E-09 2.17E-03 7.40E+00 2.12E-01 5.81E+00
5.6 2.51189E-06 0.000000004 2.73E-03 7.20E+00 1.76E-01 5.97E+00
5.7 1.99526E-06 0.000000005 3.44E-03 7.00E+00 1.46E-01 6.14E+00
5.8 1.58489E-06 6.30957E-09 4.32E-03 6.80E+00 1.19E-01 6.31E+00
5.9 1.25893E-06 7.94328E-09 5.43E-03 6.60E+00 9.73E-02 6.49E+00
6 0.000001 0.00000001 6.83E-03 6.40E+00 7.90E-02 6.67E+00
6.1 7.94328E-07 1.25893E-08 8.58E-03 6.20E+00 6.39E-02 6.85E+00
6.2 0.000000631 1.58489E-08 1.08E-02 6.00E+00 5.15E-02 7.04E+00
6.3 5.01187E-07 0.00000002 1.35E-02 5.80E+00 4.14E-02 7.23E+00
6.4 3.98107E-07 2.51189E-08 1.70E-02 5.60E+00 3.32E-02 7.41E+00
6.5 3.16228E-07 3.16228E-08 2.12E-02 5.40E+00 2.66E-02 7.60E+00
6.6 2.51189E-07 3.98107E-08 2.66E-02 5.20E+00 2.12E-02 7.79E+00
 6.7 1.99526E-07 5.01187E-08 3.32E-02 5.00E+00 1.70E-02 7.98E+00
6.8 1.58489E-07 6.30957E-08 4.14E-02 4.80E+00 1.35E-02 8.17E+00
6.9 1.25893E-07 7.94328E-08 5.15E-02 4.60E+00 1.08E-02 8.35E+00
7 0.0000001 0.0000001 6.40E-02 4.41E+00 8.58E-03 8.54E+00
7.1 7.94328E-08 1.25893E-07 7.91E-02 4.21E+00 6.83E-03 8.72E+00
7.2 6.30957E-08 1.58489E-07 9.75E-02 4.01E+00 5.43E-03 8.90E+00
7.3 5.01187E-08 1.99526E-07 1.20E-01 3.81E+00 4.32E-03 9.07E+00
7.4 3.98107E-08 2.51189E-07 1.46E-01 3.61E+00 3.44E-03 9.24E+00
7.5 3.16228E-08 3.16228E-07 1.77E-01 3.42E+00 2.73E-03 9.41E+00
7.6 2.51189E-08 3.98107E-07 2.13E-01 3.22E+00 2.17E-03 9.57E+00
7.7 0.00000002 5.01187E-07 2.55E-01 3.03E+00 1.73E-03 9.72E+00
7.8 1.58489E-08 0.000000631 3.03E-01 2.83E+00 1.37E-03 9.86E+00
7.9 1.25893E-08 7.94328E-07 3.56E-01 2.64E+00 1.09E-03 1.00E+01
8 0.00000001 0.000001 4.16E-01 2.45E+00 8.66E-04 1.01E+01
8.1 7.94328E-09 1.25893E-06 4.81E-01 2.27E+00 6.88E-04 1.03E+01
8.2 6.30957E-09 1.58489E-06 5.52E-01 2.08E+00 5.46E-04 1.04E+01
8.3 0.000000005 1.99526E-06 6.28E-01 1.90E+00 4.34E-04 1.05E+01
8.4 0.000000004 2.51189E-06 7.08E-01 1.73E+00 3.45E-04 1.06E+01
8.5 3.16228E-09 3.16228E-06 7.93E-01 1.56E+00 2.74E-04 1.06E+01
8.6 2.51189E-09 3.98107E-06 8.82E-01 1.39E+00 2.18E-04 1.07E+01
8.7 0.000000002 5.01187E-06 9.75E-01 1.24E+00 1.73E-04 1.08E+01
8.8 1.58489E-09 6.30957E-06 1.07E+00 1.09E+00 1.37E-04 1.08E+01
8.9 1.25893E-09 7.94328E-06 1.17E+00 9.52E-01 1.09E-04 1.09E+01
9 0.000000001 0.00001 1.28E+00 8.24E-01 8.66E-05 1.09E+01
9.1 7.94328E-10 1.25893E-05 1.38E+00 7.07E-01 6.88E-05 1.09E+01
9.2 6.30957E-10 1.58489E-05 1.49E+00 6.02E-01 5.47E-05 1.09E+01
9.3 5.01187E-10 1.99526E-05 1.61E+00 5.07E-01 4.34E-05 1.09E+01
9.4 3.98107E-10 2.51189E-05 1.73E+00 4.24E-01 3.45E-05 1.08E+01
9.5 3.16228E-10 3.16228E-05 1.86E+00 3.52E-01 2.74E-05 1.08E+01
9.6 2.51189E-10 3.98107E-05 1.99E+00 2.91E-01 2.18E-05 1.07E+01
9.7 1.99526E-10 5.01187E-05 2.12E+00 2.38E-01 1.73E-05 1.06E+01
9.8 1.58489E-10 6.30957E-05 2.27E+00 1.94E-01 1.37E-05 1.05E+01
9.9 1.25893E-10 7.94328E-05 2.42E+00 1.58E-01 1.09E-05 1.04E+01
10 1E-10 0.0001 2.58E+00 1.28E-01 8.67E-06 1.03E+01
10.1 7.94328E-11 0.000125893 2.75E+00 1.03E-01 6.88E-06 1.02E+01
10.2 6.30957E-11 0.000158489 2.92E+00 8.26E-02 5.47E-06 1.00E+01
10.3 5.01187E-11 0.000199526 3.10E+00 6.63E-02 4.34E-06 9.83E+00
10.4 3.98107E-11 0.000251189 3.30E+00 5.30E-02 3.45E-06 9.65E+00
10.5 3.16228E-11 0.000316228 3.50E+00 4.24E-02 2.74E-06 9.46E+00
10.6 2.51189E-11 0.000398107 3.70E+00 3.38E-02 2.18E-06 9.26E+00
10.7 1.99526E-11 0.000501187 3.92E+00 2.70E-02 1.73E-06 9.05E+00
10.8 1.58489E-11 0.000630957 4.14E+00 2.15E-02 1.37E-06 8.83E+00
10.9 1.25893E-11 0.000794328 4.38E+00 1.71E-02 1.09E-06 8.61E+00
 11 1E-11 0.001 4.62E+00 1.36E-02 8.67E-07 8.37E+00
11.1 7.94328E-12 0.001258925 4.87E+00 1.08E-02 6.88E-07 8.12E+00
11.2 6.30957E-12 0.001584893 5.12E+00 8.62E-03 5.47E-07 7.87E+00
11.3 5.01187E-12 0.001995262 5.38E+00 6.86E-03 4.34E-07 7.61E+00
11.4 3.98107E-12 0.002511886 5.65E+00 5.45E-03 3.45E-07 7.35E+00
11.5 3.16228E-12 0.003162278 5.92E+00 4.33E-03 2.74E-07 7.07E+00
11.6 2.51189E-12 0.003981072 6.20E+00 3.44E-03 2.18E-07 6.80E+00
11.7 1.99526E-12 0.005011872 6.48E+00 2.74E-03 1.73E-07 6.52E+00
11.8 1.58489E-12 0.006309573 6.76E+00 2.17E-03 1.37E-07 6.23E+00
11.9 1.25893E-12 0.007943282 7.05E+00 1.73E-03 1.09E-07 5.95E+00
12 1E-12 0.01 7.34E+00 1.37E-03 8.67E-08 5.66E+00
12.1 7.94328E-13 0.012589254 7.63E+00 1.09E-03 6.88E-08 5.37E+00
12.2 6.30957E-13 0.015848932 7.93E+00 8.66E-04 5.47E-08 5.07E+00
12.3 5.01187E-13 0.019952623 8.22E+00 6.88E-04 4.34E-08 4.78E+00
12.4 3.98107E-13 0.025118864 8.52E+00 5.47E-04 3.45E-08 4.48E+00
12.5 3.16228E-13 0.031622777 8.81E+00 4.34E-04 2.74E-08 4.19E+00
12.6 2.51189E-13 0.039810717 9.11E+00 3.45E-04 2.18E-08 3.89E+00
12.7 1.99526E-13 0.050118723 9.41E+00 2.74E-04 1.73E-08 3.59E+00
12.8 1.58489E-13 0.063095734 9.71E+00 2.18E-04 1.37E-08 3.29E+00
12.9 1.25893E-13 0.079432823 1.00E+01 1.73E-04 1.09E-08 2.99E+00
13 1E-13 0.1 1.03E+01 1.37E-04 8.67E-09 2.70E+00
13.1 7.94328E-14 0.125892541 1.06E+01 1.09E-04 6.88E-09 2.40E+00
13.2 6.30957E-14 0.158489319 1.09E+01 8.66E-05 5.47E-09 2.10E+00
13.3 5.01187E-14 0.199526231 1.12E+01 6.88E-05 4.34E-09 1.80E+00
13.4 3.98107E-14 0.251188643 1.15E+01 5.47E-05 3.45E-09 1.50E+00
13.5 3.16228E-14 0.316227766 1.18E+01 4.34E-05 2.74E-09 1.20E+00
13.6 2.51189E-14 0.398107171 1.21E+01 3.45E-05 2.18E-09 8.99E-01
13.7 1.99526E-14 0.501187234 1.24E+01 2.74E-05 1.73E-09 5.99E-01
13.8 1.58489E-14 0.630957344 1.27E+01 2.18E-05 1.37E-09 2.99E-01
13.9 1.25893E-14 0.794328235 1.30E+01 1.73E-05 1.09E-09 -5.64E-04
14 1E-14 1 1.33E+01 1.37E-05 8.67E-10 -3.00E-01
EA SEMANA 3

in con EGTA

Para generar una referencia

absoluta a una celda (til
_4 para tomar un valor de sin
que se mueva la celda
seleccionada) por ejemplo, si
_4 quieres referirte a 1 de
(/) M/OH utiliza $A$11
=-LOG(MAX(1,$A$11*C19,$B$11*C19^2,$C$11*C19^3))
-LOG(MAX(1,$D$13*B19,$E$13*B19^2,$F$13*B19^3,$G$13*B19^4))

Con
aproximaciones Zonas
GRFICA 1 "log de Alfa en funci
-4.90E+00 13
-4.60E+00 13 log AlfaPb(OH) AlfaL(H) AlfaP
-4.30E+00 13 2.50E+01
-4.00E+00 13
-3.70E+00 13
-3.40E+00 2.00E+01
13
-3.10E+00 13
-2.80E+00 13
1.50E+01
-2.50E+00 13
-2.20E+00 13
-1.90E+00 13 1.00E+01
I
-1.60E+00 13
-1.30E+00 13
-1.00E+00 13 5.00E+00
-7.00E-01 13
-4.00E-01 13
-1.00E-01 13 0.00E+00
0 2 4 6 8 10
2.00E-01 13 pH
5.00E-01 13
8.00E-01 13
1.10E+00 13
Grfica 2 "logKf = f(pH)"
1.40E+00 13 Sin aproximacin Con aproxi
1.60E+00 logKf logKf
13 1.30E+01
1.80E+00 13
1.10E+01
II
9.00E+00

7.00E+00
 Sin aproximacin Con aproxi
logKf logKf
1.30E+01

2.00E+00 13 1.10E+01
II
2.20E+00 13
9.00E+00
2.40E+00 13
2.60E+00 13 7.00E+00
2.70E+00 13
2.80E+00 1 5.00E+00
2.90E+00 13 3.00E+00
3.00E+00 13
3.10E+00 13 1.00E+00
3.20E+00 13
-1.00E+00 0 2 4 6 8 1
3.30E+00 13
3.40E+00 13 -3.00E+00
3.50E+00 13
3.60E+00 13 -5.00E+00
3.70E+00 13 pH
3.80E+00 13
3.90E+00 13
III
4.00E+00 13
4.10E+00 13
4.20E+00 13
4.30E+00 13
4.40E+00 13
4.50E+00 13
4.60E+00 13
4.70E+00 13
4.80E+00 13
4.90E+00 13
5.00E+00 13
5.10E+00 13
5.20E+00 13
5.40E+00 13
5.60E+00 13
5.80E+00 13
6.00E+00 13
6.20E+00 13
6.40E+00 13
6.60E+00 13
6.80E+00 13
7.00E+00 13
7.20E+00 13
7.40E+00 13
7.60E+00 13
7.80E+00 13
IV
8.00E+00 IV 13
8.20E+00 13
8.40E+00 13
8.60E+00 13
8.80E+00 13
9.00E+00 13
9.20E+00 13
9.40E+00 13
9.60E+00 13
9.80E+00 13
1.00E+01 13
1.02E+01 13
1.03E+01 13
1.04E+01 13
1.05E+01 13
1.06E+01 13
1.07E+01 13
1.08E+01 13
1.09E+01 V 13
1.10E+01 13
1.11E+01 13
1.12E+01 13
1.13E+01 13
1.13E+01 13 -151.15827197
1.13E+01 13
1.13E+01 13
VI
1.13E+01 13
1.13E+01 13
1.13E+01 13
1.12E+01 13 -1
VII
1.11E+01 13
1.10E+01 13
1.09E+01 13
1.07E+01 13
1.05E+01 13
1.03E+01 13
1.01E+01 13
9.90E+00 VIII 13
9.70E+00 13
9.50E+00 13
9.30E+00 13
9.10E+00 13
8.90E+00 13
8.70E+00 13
8.40E+00 13
8.10E+00 13
7.80E+00 13
7.50E+00 13
7.20E+00 13
6.90E+00 13
6.60E+00 13
6.30E+00 13
6.00E+00 13
5.70E+00 13
5.40E+00 13
5.10E+00 13
4.80E+00 13
4.50E+00 13
4.20E+00 13
IX
3.90E+00 13
3.60E+00 13
3.30E+00 13
3.00E+00 13
2.70E+00 13
2.40E+00 13
2.10E+00 13
1.80E+00 13
1.50E+00 13
1.20E+00 13
9.00E-01 13
6.00E-01 13
3.00E-01 13
0.00E+00 13
-3.00E-01 13
*B19^3,$G$13*B19^4))

og de Alfa en funcin del pH"

(OH) AlfaL(H) AlfaPbL(H)

4 6 8 10 12 14
pH

ca 2 "logKf = f(pH)"
roximacin Con aproximaciones
roximacin Con aproximaciones

4 6 8 10 12 14

pH