Professional Documents
Culture Documents
1
Cathode Material Capacities
Material Atomic or Standard Valence Density Specific
molecular Potential at Change (g/cm3) Charge
weight 25C (V) (Ah/g)
(g/mol)
O2 32.0 1.23 4 3.35
Cl2 71.0 1.36 2 0.756
SO2 64.0 1 0.419
MnO2 86.9 1.28 1 5.0 0.308
NiOOH 91.7 0.49 1 7.4 0.292
CuCl 99.0 0.14 1 3.5 0.270
FeS2 119.9 4 0.89
AgO 123.8 0.57 2 7.4 0.432
Br2 159.8 1.07 2 0.335
HgO 216.6 .010 2 11.1 0.247
Ag2O 231.7 0.35 2 7.1 .0231
PbO2 239.2 1.69 2 9.4 0.224
LixCoO2 98.0 2.7 0.5 0.137
Standard Potential
Load
Theoretical specific charge: e-
Zn anode OH- MnO2 cathode
H 2O Aqueous
KOH
electrolyte
2
Alkaline Battery Construction
Load
M = hydride forming metal e-
e.g. LaNi5 which forms LaNi5H6
M anode OH- NiOOH cathode
More generally AB5 where:
A = La, Ce, Nd, Pm, and H 2O Aqueous
B = Ni, Co, Mn KOH
electrolyte
Theoretical specific charge:
3
Li Ion Batteries
Discharge
Graphitic CoO2 Layers
sheets Li+
Charge
LixC6 anode Li Ion Electrolyte LiCoO2 Cathode
Both anode and cathode reactions are intercalation reactions, meaning
that Li is shuttled in and out of existing, layered structure.
Discharging (use) Cell Reactions
x,y not fixed, but
Anode depend on charging
Cathode and operating
conditions
Cell
Specific Charge Capacity:
Anode has specific charge of 0.37 Ah/g Cell specific charge is 0.10 Ah/g
Cathode has specific charge of 0.137 Ah/g
Actual capacity = 0.94 Ah/19 g = 0.05 Ah/g
This is about half that of an alkaline battery. But the voltage is over twice as high (4.1 V
vs 1.5 V), so the specific energy is greater
Li Ion Batteries
Electrolyte:
Non aqueous electrolyte needed
Cell voltage is high enough to decompose water
Li reacts strongly with water
Electrolytes are:
Li salts such as LiPF6, LiBF4, or LiClO4
In organic solvent such as ethylene carbonate, dimethyl carbonate
Electrolyte reacts with anode
Controlled reaction produces reaction product called solid electrolyte
interphase (SEI) that prevents further reaction
Organic/Li-Salt
Electrolyte
Cu Contact Al Contact
4
Battery Construction
Battery design is a trade-off between high rate and high capacity
High rate batteries will have large surface areas between electrodes
High capacity batteries will have maximum amount of material
5
Polarization Losses in Batteries
0.8 0.4
0.6 0.3
0.4 0.2
0.2 0.1
0.0 0.0
0.0 0.2 0.4 0.6 0.8 1.0
Normalized Cell Current (I/Imax)
I Cell current
Load resistance
Ri
Rload
Internal resistance
Concentration polarization potential
Internal Resistance Activation potential
Electrolyte resistance
Internal contacts
Electrode bulk resistance
Electrode surface resistance
Can increase with time and cycling as surfaces are contaminated and reactions occur
e.g. Increase of SEI thickness
Other Degradation Mechanisms
Battery Capacity
6
Real Battery Discharge Behavior
Theoretical voltage is the cell potential we discussed earlier
Open circuit voltage is usually close to the theoretical voltage
Nominal voltage is one that is generally accepted as typical of the operating
voltage of the battery as, for example, 1.5 V for a zinc-manganese dioxide
battery.
Working voltage is more representative of the actual operating voltage of the
battery under load and will be lower than the open-circuit voltage.
End or cut-off voltage is designated as the end of the discharge. Usually it is the
voltage above which most of the capacity of the cell or battery has been
delivered. The end voltage may also be dependent on the application
requirements.
Voltage
Vworking = 1.8 - 2.0 V 0.6
Vend = 1.75 V (moderate discharge)
= 1.5 V (engine cranking loads) 0.4 Higher discharge
Vcharge = 2.3 - 2.8 V rate or internal
0.2 resistance
0.0
0.0 0.2 0.4 0.6 0.8 1.0
Time
Coming up: