ok eee ; NadH + KHCsH4 04 > len (8-10) Seti KNeOsHaDa * He0 5 $42 Frep: Stowdardication: aso nh iy 3h) Crfee HO teolto rm temp aot m0 Fike: i fondo er fr wot pale prt, ehpldn Sotlner REIS: Nabl is hyjrosiopc« welghing bettie + Dost store ges eee leaches. stopper Ua be > Kay 80> © Lage ont of Naot was dsooied mn water beo NasCO2 (hah Obe* 20H Clss Hep) © mole m ntorly Saturated Nablt. acu» NADH + Mads are filtered oF * Grit watlor 1s used t dissolve NaOH = ut alkali salns adlily absorb Cds ; facilidaks chscoluhen since, nan is XO * Handed Allee paper torrotands alkali sits wlo hydrolyss Addétenal. Info + > Corbmak. uror + 20-4002 00, +H20 OH” becomes 1 Cos?” * aad- range wdvatar: to @ tnd oink : COs?" aH Hab Ca RH* consumed by COs* 2 fate ecg scarbmae enor id bok +H Ha oa, LH consumed a Hel + Direct tera + Tromnethanine (HOCHe)>CNH2 + HOI > + Bomnocresel green (4-6-6) oe + blue pale yelled (HoOH2)sCNHa Cl; f+ 1 Sandordization RFLS: s Advantage of tremethamine ovr KistDs = greater mass ‘ry (105, 3h) desole w HD _ ree weighing err) ifole 9] Hel & Ha804 (HocH)sONHe t HeSO«> Peie O — (WoctHe)s ONHs” HOE, $24 mole of Hemme (devs + :aartthy dry (1102) dissolve mn HeO. © atc oF cat increases as nan proceeds + Mat somes as Catalyst aKMnOst GNaC04 + BHeSO4 > 2MnSO4 + Na S04t K2804 + 10 Cost + SH20 Frans? 6 Fanon = 2 RFIS+ . + Boil Rep) to hasten decom posi ibe larkon of Mas ppt 5 4 OBE > Mine V * re te totalypcd by Ught AMnO4 4 RHO? AMaDe + 0s + aN thas + Aeidic + prov fe sarin ‘eu chen YD to M - A oudio: Un?" Mn, Mal may for HO Wok ue ee aMa04 + 10er a> aun + 50a + BH20 * Ue glass-steppered burct? Male roy fate ner + tdraon at (0°-10 +i m sted ak rm tunp; should be fost enrugh be emalte Wd pt dekmanetion + Add Kindy sinaly to pout codhauston of H* localy * prkaton Of collidal MaDe 5 HaC04 5 = Direat Pe Te en Standardszation « + KMD. a@ 1 alors > pale pn Guten: Kao © acidic; tump bet 60'=70" & Co(804)e * Direct tehrarhy : ines a E0000), + NOsC.Oe> “ies Si fl 00» * Cos (SOn)e * asS04 a Feasods * F Mascon? &SION PRY Oi TICE regenee" ee Additional, Info . fal stench ater tn urns yuh on ‘Wadaed cay se, ea verran avin to Starch oun af re ord paint + starch ° en Seas ray Wapholyze in aad theo (oglu, lich = a RA-> ear ) conker (better self Ore Addthmal Info * (Hesber ited) ar ine ly rok OA (rcs) cc hyo ere ? + 3 Bes fang asus ociee, $303 hee onelahe, heat beh 10-15 an dP” FE ty SHO Leto DE)» on pnt Sechignetic titre CeO) By nin wf > story A ss deshyl « equnolont aut. of Zo @ TS nk sag ——Prmbed = sehme« rd cca ens * Rei: rolgsts propdeen Fase ae ‘celoi)4 8 Bre ( Koppeschaar's: Solution) . nackte ledemehy C: Iodine Tratims (Reclr’) * NaS 96 + gharch + NaSe0s Katrsb* KEY HOI> | Gevaiiss —— SKBe+ KErOst GHC! kel + + Indircot-nheation ; lodemetry geen + aadic + Kel 01 GIy + &CrCls +BKCI+ THO 3Orght SH20 (Pep) + starch + ite? ears iNlagS2064 Te > NawS0, NAL Prep ONL + Bi, > 2 KBr+ Te, + acide, Foor? KBeOs Tht 2Na28203> ANal* NaSeOe ranean Prep Fans 1 en Faye & NaS Standardaaten Stondardization a ae rs bal inse, 0] Ha! ° , ther cooled Hed ait tien Fae) soe dig seer te air ihntcny NasSOs +Hel onidahun > more stabie~ Wahl yoleehgeen 1 stoner, shake + Stopper Hack. after adding Hol ial whl als Spe choke +t pment ange of Br vepors standndare blank stand (Ser) REIS: + blank: to acmunt tr That get midwid to Ip 602) “rats «| NaSOs + NaSi03 sasha rae Lo H:0> Stcalrahen (> . ; “antl hese yelled backenal dekrrorotion) * renneval. # CDs (HslDs causes hydilyss) N2sSA05* Ale > Nes * Ha Ss ay wh ods Sin prod ad ete ley > medrol 9h + addy cata 3 + te Ch ae * Radke: moreases reduce MONEE + * Dee im csorpthuly of shrch a + NasSs03 Ty+9Na2G0.> QNal + NaSsOe ab highs fa 20H" +14 H2O + Starch + Todine, ask used: be of Ze (volahle) + ondahen = Hue? colorless Fr Q Biddle (calolyeed Wy Walt hgh aadty) + acidic MIs Oat FHt > Qlat QHD ++ HOG: predate ar edhe of T= by blarkehng salu] mec gps ~ meHOOs: AHL * On > Ie + HeO Prep Standardization: = wl Hoar + HE + NAHOy > Nate CO, + HeO Cr sna etd '} e + Stand for 1 mire: mn 8 et mstartanas ‘assolve in ‘alate of Heo + + (mas) 99 Ha Ts wl be held sh os Is Ca as LE Gone tt) 15 etach s shite beg w sil tederene bly 1) pekatn§ F8e game Orme + got : fe . eabrss Sa ile be tli male see aly ae + Ban strong te poset laoal, xan f uosubfate REIS 4 Salat + Ht Hest + SY * 2 utctice en stondina taults maenlu fom backerial acter che eohud sheng bothe in sols lade Sblty: valoihy Yin attacks ganic matenals, arr eidkshen (caboly eck by ocd, aad Ay ht)0: KIO (005m) tga ate icanetsy ao, SKE GHC > * Starch . Bue > colortcss SIa+ Bia0 + OKC] oe Ja+ 205 NaS, + ONal Pep: Fea, ; ‘i Stondardeahs : de C0"), Pets — USO rata +kL titrate. uh! colorless + dulled He} Sond m dark 5) cold ‘helo NaS, aeht crau-ooler RFIS: + 1d wanker © added to oncure thak Tr stays wn satin D. Volumetric: Fecipitation - AgNOs (era Foyans method onto + White pt > prnke cay ali pet AgNOs+ Nact> Agcld * NaNiOs Faauy Standardization: Nac (Wt 2h) cdssolyein Hod * acthe aaa : SRL Pera Sl ue gd (pipes se of eosin fir involv ae recemmendid bec: co501 1 more Shargly bund to Agel than ef premature, end gone. ee ets pres eM 4 an, (An 6 awerk aad > must be pesent m Hs anernic$rm Se ttt be adsorbed ) thas proverting rt fram displacing CI» guns a premature oot: lor 8 of coon sharpest wm aeeke aad stl CqH 3) © sega parhcks dspostd * have logy Oc acephen 4,1 E. Complexahon 1 EDTA (005M) fi +» Dwect-htration ea raprttol Wee red sain > Bue colin + basic: 1& NHASCA) "hgh Aig NO, *NHASCN > AgSCA + See ene NNO Hein Fey ade BUH USCA > Fe(Son)s+ 2 (wHA)S0+ Fiousen * 1 Standardization: ‘ila wl HeO + HNO + NH tera] NHASCAD > Since NHASCA) © dokqueccurt, a Sight ant excus $f the “yeneckeal uh wed Is used Uce weighing botte oR pla arg toa pert pape +f othte anions: Head are. lable me med, + ctrng wihie aad retords 1 # [FeSca] onmplox + temp shed vob orcad &C. temps way bleach Tn color © Oxides of webrgen que’ colered salts a) eenc alarn. Navi se se i ier han + RAASON Is Ught-cererive, Na. EDTA + CaCl. > CoEDTA + ANaol ea idlicate: Caln + NasED1A > we NaIn'+ CaEDTA + Nat RFIS: *Dsedaum salt plored mer Hate cid vt AA Vs, since itis wor al ates + Ha exhbitce Cet, by covering Cals tHAPCadhr Le at + + Slum fomud tals asier and disootation ee ance deed 1 prevent: lise of summple (mn 8 Yigerrus + Ot Mhewaed) + Hae 2 sasha 1} HR fo dalute eb. High naka encontraron wakes t+ harder te SEs ond hall OT Cbd) Ee re Nu nas aC wy fm «Ha, tbh O 8 kn ek mei be pra a ontamant tall no reack+ Stobuity of metat-In complex : - must be less stable than metal - EDTA compl EDTA wall nok displace Indicatey’ firm the m ex , odumaisc, tha — must not be too unstale ; otherwist, EDTA will start displacing In ak the start of titraton >d fuse enol pout + After all Ca* have been wsmplexed by EDTA the red Ca-Ty Comper glues up Ca¥ ty EDTA ih Wodkoafer, 14. ZnSO. (0.05M) + Direct hhraton - EDTA + Dthizone TS + gren? chiar, rose pink soln Add n order: & Bedioaad-ammnanium > alooho| 3: dithivone TS titrate w/ ZnSO4 boating the Wue: uncomplexed Naz EDTA t ZNS04> Zn EDTA fi Nasso4 RELS: + + butt + maintans pH © 4.63 Th requues actdie pH * Adal in order: Alcolto| before thy inchoate, sihce Indicate used 1s ‘prparel using alcool. Alcohol ts addid ence metal comnplerca % ditt ron are soluble in alcohat - - Indicator is insoluble in HO , Soluble m dilute aq, AMMO « Dituzme (Aiphenyl tiocarbarone) should be freshly prepatcol ; way gt ridrud te diphenylthtocarbadiaune, Cena pont vail! tok be showp) * Dithtzone - Zn esmplen: pink fru dlithivone : greenrtd. by the, Oe a the tue, wnchmplex cl Nas EDTA t 21500 ZHEDTA + Na;s04 ON BE Reparaken Compute: fsx ao KBr, KBr (5K REG * inet f RLS. “ 1 baler wrarane yt © EAL Thrace acuc pt ot Ba gy ON a © fk erder ala tire the ob Bed r wot Bray A ea th a00s Be 2 ‘lr Beas 4 = SSVI g Kies TREO Berg Keb» Biss 2 ayer Ba Fi pone Dees 3 Fir vate As M9359 KBr ep 006 gen MN > Mies eas DUSM +: Qh. x BRR gle worn = 97, 22409, NisDTA +2rS06—> ZnEMA* New 30+) EDA SN E Waianae Be 006M > O09L * “tec ndgient iheea 04t0lg