PAPER Adva PI Sol PDF

1
AITS-CRT-I(Paper-1)-PCM (Sol)-JEE (Adv)/14
From Classroom/Integrated School Programs 7 in Top 20, 23 in Top 100, 54 in Top 300, 106 in Top 500 All India Ranks & 2314 Students
from Classroom /Integrated School Programs & 3723 Students from All Programs have been Awarded a Rank in JEE (Advanced), 2013
FIITJEE JEE(Advanced)-2014
ANSWERS, HINTS & SOLUTIONS
CRTI
(Paper-1)
Q. No. PHYSICS CHEMISTRY MATHEMATICS

ALL INDIA TEST SERIES
1. C C D
2. A D A
3. B D B
4. B C A
5. A B B
6. D D A
7. B C C
8. A. C A
9. B B C
10. C B A
11. A, B, C A, C A, B, C
12. A, B, C, D B, C A, B, C, D
13. B, C, D A, C A, D
14. A, B, C A, B, C B, C
15. A, B, C A, C B, C
1. 2 2 4
2. 1 1 2
3. 5 4 6
4. 1 3 2
5. 2 6 3
FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com
2
Physics PART I
SECTION A
1. Urel g t 10 1
= 10 m/s
1
S1 g(1) 5m
2
1
Srel S1 ure are t 2 = 5 + 10 3 + 0 = 35 m
2
h /2
2. sin =
/2

mgh = mg cos (/2)

h cos

2

tan =
2
3. Centre of mass does not move in the absence of external force so

m1x1 = m2x2
x1 m 2

x 2 m1
dA1 r 2 d r 2
4. A
dt 2 dt 2
2
L = Mr
L = 2MA
Gm(M m)
5. F 0
r2
dF G
(M 2m) 0
dm r 2
M = 2m
m = (M/2)
Ag
6. s
A
s

g
h
7. ghr 2 (2rdh)gh
0
h2
ghr 2 2rg
2
h
r2
2
r=h
3
(v r t)2 (v mr t)2
8. Avg. speed 3
t
v 2r 5 9
vr 2m / s
1 t 1
v v
2 2 2 3v
9. v avg
t 4
m m
10. gT a (i)
2 2
ma
T cos 60 = (ii)
cos 60
2g
Solving (i) and (ii) acceleration of ring =
9
2kq2 mv 2
11. mg 2
T (i)
R R
1 1
mgR + mu2 mgR mv 2 (ii)
2 2
2Kq2
if T = 0 umin 5gR
mR
dU
12. F 5(2x 4)
dx
At mean position F = 0 x = 2m
Umin 20 J
a = 50 2(x 2)
= 10 rad/sec
T = /5 sec
V
13. If the volume immersed initially is (V/3). Then
g mg (i)
3
If the volume immersed when the system accelerates is V then
g mg V
V ' g mg V'
2 2 3
14. The potential of the two surface will be equal when the whole charge Q flows from inner to other
shell.
SECTION C
1. Consideration refraction at glass-water interface
r
2 2 1 (27r/20)

v u R
4 3 ( 4 / 3) ( 3 / 2)
(4/5)r
3v 2r r
4
4 3 1

3v 2r 6r
r
v=
5
Now refraction at water air surface
4 9r
u = - r r
5 5
2 1 2 1

v u
1 4 5 1 ( 4 / 3)

v 3 9r
1 20

v 27r
27r
v=-
20
27r
so height above centre = 2r -
20
40r 27r 13
= = r = 13 cm.
20 20
2. Mg T = Ma (i)
T mg = ma (ii)
2Mmg
T=
(M m)
T 2Mmg 2mg
2 109 m
A A(M m) m
A 1
M M
M = 1.86 Kg
3. Relative motion between block and table 4 cm

2
will start when m r
m2 r sin (mg m 2r cos ) (i)
t (ii) 3 cm

solving (i) and (ii)
t 500 22.4 sec .
g
4. = = 1 rad/sec
R
5. N1 + N2 = mg . . . (1) N1
N2
N1 = N2 . . . (2)
mg
N2 = N1
1 2
mg N2
N1 =
1 2 mg
Torque about centre of mass
5
1
(N1 + N2)R = mR2
2
2 N1 N2 2 1 g
= =
mR 1 2 R
2 = 20 2
20
=
2
20 1 2 R
=
2 2 1 g
Hence number of turns
02R 1 2
N= =
2 4 1 g.2
20R 1 2
N=
8g 1
Chemistry PART II
SECTION A
1. In A bond is at bridge head which is not stabilized in the given structure;

CN
In B the product is ;
ACOH
In D the product is
2. HO
O N OH
O NH2 OH HO NH
H 2N OH
H2 O

IMPT

N OH2 OH
N N
H O
H

2

HO

2
H
5. CH3Cl is formed by SN2 while CH3CHClC2H5 is formed by SNi.
6.

PCl5 g
PCl3 g Cl2 g
Let initially no. of moles x
at equilibrium volume V x 1 x x
6
x 2 2 n
Kc , also Kp = Kc(RT) g
x 1 V
V
on reducing volume to , initial concentration of PCl5 doubles and its degree of dissociation is
2
increased but Kp does not change, as it is characteristic constant for a reaction at constant
temperature.
7. 2H3 Al OH 6 6HCl ;
Al2Cl6 12H2 O
10. In blast furnace,

In combustion zone, CO is produced ultimately which reduce Fe2O3 to Fe3O4 in reduction zone,
which is uppermost zone.
11. O
P=
Q=
O
Oxidation by XO
R= CH3 COOH C 2H5 OH ; C2H5 OH CH3CHO
O
O
S=
12. Due to hydrogen bonding Gauche conformation of H2C CH2 NH2and H C CH2F
2
NH2 OH
are more stable than their anti-conformations.
In case of ClCH2CH2Cl, on increasing temperature, % of Gauche conformation increases. Hence
dipole moment increases. In case of option (D) boat conformation is most stable.
13. Mn appears colourless in reducing flame in Borax Bead Test.

Fe3 K 4 Fe CN6 Fe 4 Fe CN 6 K
3
Prussian blue

Na2 S2O3 .5H2 O Na2 S5 Na2 SO4 H2 O
14. At pH = pI, amino acid exists as Zwitter Ion, they are highly soluble in polar solvents.
7
15. pH of 108 M HCl (aq) is 6.96 and pH of 108 M NaOH (aq) is 7.04
SECTION C
1. = CRT i
hence i = 1.1; so = 0.1
hence [H+] = c = 0.1 0.1 = 102 M
pH = 2
2. It has only one CH2OH group.
3. Three equivalents to remove three hydrogens from CH3 group and one for attack on C of CHO
group.
4. BaCrO4 Yellow, soluble in dil HNO3

Hg2CrO4 Red, soluble in conc. HNO3
ZnS White, soluble in Conc. HNO3
BaSO4 White, insoluble in all mineral acids
BaS2O3, CH3COOAg and AgNO2 all are white solid and are soluble in dilute HNO3 solution.
Cl
5. Except and Cl
Mathematics PART III
SECTION A
1. [y + [y]] = 2 cosx [y] = cosx

1
y = [sinx + [sinx + [sinx]]] = [sinx]
3
[sinx] = cosx
Number of solution in [0, 2] is 0
Hence total solution is 0.
both are periodic with period 2
2. (x 0)2 + (y k)2 = k2
x2 + (y k)2 = k2
dy
2x + 2 (y k) 0
dx
dy x

dx y k
xdx
yk=
dy
xdx
k=y+
dy
8
2 2
xdx xdx
x2 + y y y
dy dy
2 2
2 dx dx 2xydx
x + x y2 x 2
2
dy dy dy
2xydx
x 2 = y2 +
dy
dy
(x2 + y2) 2xy 0
dx
3. Given < < < also sin = sin = sin = sin = k

and , , , are smallest positive angles
= , = 2 + , = 3
as sin = sin and >
sin = sin and >
sin = sin and >
Putting these values in the given expansion, we have given expression

= 2 sin cos 2 1 sin 2 1 k
2 2
2
4. x3 x < a2 + a
3 3
f(x) = x3 x
f(x) = 3x2 1 = 0
1
x=
3
1 1 2
In positive region minimum value of f(x) =
3 3 3 3 3
2 2
So, a2 + a >
3 3 3 3
a2 a < 0
a (0, 1)
5. 3x 2 4x 4 5x 1 4x 5 (1)
v u p q
u2 v2 = x + 6 = p2 q2
uv=pq (2)
solving (1) and (2)
we get, 2 4x 4 2 5x 1
x=3
6. Limit be equal to y

1
logy = lim log n 1 log n 2 ...
n n n n
n n 1
1 n r 1 r
= lim log
n n r 1 n = lim
n n
r 1 n
log 1 log 1 x dx
0
9
1 4
= . 2 log2 = [log4 loge] = log
2 e

4
logy = log
e

7. 0 argz , represent the region of complex plane lying in the first quadrant and bounded by x-
4
axis and the line y = x
|2z 4i| = 2|z 2i|
least value of |z 2i| is length of perpendicular from (0, 2) to y = x, which is 2
So the least value of 2 |2z 4i| is 4
8. Let f(x) = 2x3+ 3x2 12x + 3

f(x) = 0 has three real roots (, , )
3
++=
2
Centroid =

,

,
1 1 1
= , , which lies on x = y = z.
3 3 3 2 2 2

9. If a > b > c and a2 = b = c then b < 1 cot1x < 1 x > cot1
a
10. a 4sinA 4 R2
sin A
so for any point (x, y) inside the circumcircle, x 2 +y2 < 4
|xy| < 2
11. a, b and A are given in ABC,

b2 c 2 a2
cos A =
2bc
c2 2bc cos A + (b2 a2) = 0
c2 (2b cos A)c + (b2 a2) = 0
which is quadratic in c and gives two values of c and let these are c1 and c2
c1 + c2 = 2b cos A
and c1 c2 = (b2 a2)
c12 c 22 2c1c 2 cos2A
= (c1 + c2)2 2c1c2 (1 + cos 2A)
= 4b2 cos2 A 2 (b2 a2) (2 cos2 A)
= 4b2 cos2 A 4b2 cos2 A + 4a2 cos2 A
= 4a2 cos2 A
1 1 1
12. n terms
2 5 5 8 8 11
5 2 8 5 11 8 5 (n 1)3 2 (n 1)3
=
3 3 3 3
3n 2 2 3n 2 2 n
=
3
3 3n 2 2 3n 2 2
10
n n
= n
2 3n 2 3n
2
13. sin
24 R 2

R 2 1 cosec
24
2

sin cos
2 2
(A) is true 1 cosec
sin A
(D) is true
14. x2 + x + 1 = |[x]|
Hence only 2 solutions exist
i.e. x = 1 and another lie 2 < x < 1
15. sin x + cos x = 1 a sin x cos x

a2 sin2x cos2x 2(a + 1) sin x cos x = 0
2
sin2x a sin 2x 2 a 1 = 0
2
Hence sin2x = 0 a R
n
x= ,nI
2
4 a 1
And sin2x = a (, 2 2 2 ] [2 + 2 2 , )
a2
SECTION C

1 1
1. a= r
r 1
2
, b (2r 1)
r 1
2
1 1 1 1 1 1 1 1
a= 2
2
2
2
... and b = 2
2
2
...
1 2 3 4 1 3 5 72
1 1 1 1 1 1 1
b = 2 2 2 2 ... 2 2 2 ...
1 2 3 4 2 4 6
1 1 1 1 1 1 1
b = 2 2 2 2 ... 2 1 2 2 ...
1 2 3 4 2 2 3
1
b=a a
4
3
b = a
4
a 4

b 3

2. f 1(x)dx t f (t)dt

0 0
11

= t f t 0 t sin t dt

0
2

= 2 1 1
2
2
= 2
2
k=2
3. Case I: When we use 6, 7 or 8 at ten thousand place then number of numbers

4
= 3 P4 = 72
Case II: When we use 5 at ten thousand place and 6, 7 or 8 at thousand place then number of
numbers is
= 1 3 3P3 = 18
hence the required numbers of numbers is 72 + 18 = 90
4. f(x) is an odd function

g(x) is f 1(x)
2 2
Area = f 1 y dy x f x dx
0 0
2
2
= x f x 0 x sin x dx = 22

0

2 2 2
5. a b b c c a = 2 a2 b2 c 2 2 a b b c c a

= 2(4 + 9 + 16) 2 a b b c c a

= 58 2 a b b c c a .
2
Now a b c 0

a2 + b2 + c2 2 a b b c c a

2 a b b c c a 29
2 2 2
a b b c c a 87

PAPER Adva PI Sol PDF

Uploaded by

Document Information

Original Title

Copyright

Available Formats

Share this document

Share or Embed Document

Sharing Options

Did you find this document useful?

Is this content inappropriate?

Copyright:

Available Formats

PAPER Adva PI Sol PDF

Uploaded by

Copyright:

Available Formats

1

AITS-CRT-I(Paper-1)-PCM (Sol)-JEE (Adv)/14

Q. No. PHYSICS CHEMISTRY MATHEMATICS

3. Centre of mass does not move in the absence of external force so

3. Relative motion between block and table 4 cm

Torque about centre of mass

1. In A bond is at bridge head which is not stabilized in the given structure;

5. CH3Cl is formed by SN2 while CH3CHClC2H5 is formed by SNi.

10. In blast furnace,

are more stable than their anti-conformations.

In case of ClCH2CH2Cl, on increasing temperature, % of Gauche conformation increases. Hence

13. Mn appears colourless in reducing flame in Borax Bead Test.

2. It has only one CH2OH group.

4. BaCrO4 Yellow, soluble in dil HNO3

Mathematics PART III

1. [y + [y]] = 2 cosx [y] = cosx

3. Given < < < also sin = sin = sin = sin = k

8. Let f(x) = 2x3+ 3x2 12x + 3

9. If a > b > c and a2 = b = c then b < 1 cot1x < 1 x > cot1

11. a, b and A are given in ABC,

15. sin x + cos x = 1 a sin x cos x

3. Case I: When we use 6, 7 or 8 at ten thousand place then number of numbers

4. f(x) is an odd function

You might also like