Professional Documents
Culture Documents
Engineering
Modelling in Environmental Engineering :
Transport and Transformation Models
Balance
Deposit Withdrawal
Balance
Deposit Withdrawal
Accumulation
Input Output
Balance
Deposit Withdrawal
Accumulation
Input Output
-k0 = dCA/dt
Batch/Plug flow
1 C Ai
CAo = CAi e-kt t ln
k C Ao
Complete mixed flow reactors
dCA/dt = 0
CAo =CAi/(1+k1 T)
Reaction order
8/5/2016
Problem 2
Glucose was added to a batch culture of m/o and the removal was measured
over time.
Conc. Of glucose time (days)
As COD mg/l
180 0
155 5
95 12
68 22
42 31
26 40
Determine the order of reaction and reaction constant.
Treatment process kinetics (continued)
1. Batch reactors
2. complete mix flow (CMF) or continuous flow stirred (CFST)
3. Complete mix reactors in series
4. Ideal plug flow (PF)
5. Ideal plug flow with retard reaction rate
6. Plug flow with axial dispersion
Important relationships for different reactor
configurations (summery)
C Ai 1 C Ai
C Ao T ( 1)
1 k1T k1 C Ao
C Ai
C1 1 k1T C Ai Q, CAi C1 C2 Cn
C2 V,K
1 k1T 1 k1T (1 k1T ) 2
C Ai 1
Cn 1 C Ai n
(1 k1T ) n T 1
k1 Cn
Example 2.