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Introduction
Mass Transfer Components
Process design Thermodynamics
Column design - Fluiddynamics
Capacity, Pressure Drop,
Efficiency
Column Internals
Squared columns:
up to 20 m x 25 m
Structured Packings
Rings
Trays
Gas
Distributors
Structured Packings
Collectors
Rings
Supports
Trays
Gas
Gas inlets
Gas/Liquid Liquid/Liquid
Separators Separators Static Mixers
Driver in G/L Separator Breakthrough L/L Separator Technology Pace-setting Technology
Lecture ETHZ | March 2017 | slide 7
Mass Transfer Technology Sulzer Chemtech
Efficiency
per Technical Considerations
m height
Pressure
Capacity
drop
Experience of
Cost of
technology When to use what? vessel
licensor
V g
load factor : (m/s)
g Ac l g
L g
flow parameter : (-)
V l
where Ac: column cross section (m2)
L : liquid flow rate (kg/s)
V : vapour flow rate (kg/s)
g : vapour density (kg/m3)
l : liquid density (kg/m3)
Lecture ETHZ | March 2017 | slide 9
When to use what ? Sulzer Chemtech
Vapor Capacity
Conventional Equipment - Trays vs. Structured Packing
Maximum capacity of column internals (TS=600 mm)
0.14
0.12
0.1
[m/s] "vapor"
0.08
Mellapak 250.Y
0.06
Conv. trays
0.04
0.02
0
0.01 0.1 1
Vacuum
[-] liquid" High pressure
Vapor Capacity
High Performance Devices - Trays vs. Structured Packing
Maximum capacity of column internals (TS=600 mm)
0.14
0.12
0.1
[m/s] "vapor"
Conv. Packing
0.08
Conv. trays
0.06
High Perf. Packing
High Perf. Tray
0.04
0.02
0
0.01 0.1 1
Flanged Columns
Diameters from 50
Welded Columns
mm
Monobloc Type
Diameters
up to 14,000 mm
One piece or
Segmented internals
segmented
for
internals for
installation through
installation
manhole
through column
flanges
Mellacarbon for
Mellagrid and
Mellapak AYPlus DC non-oxidizing media
Nutter Grid
in plastic and alkaline solutions
in metals and alloys
Nutter Ring
Float Valves Enhanced Deck Enhanced Deck Shell Calming Section (CS) Shell ConSep
and Downcomer
BDH / BDP MVG Shell CS Plus
Round Valve VGPlus
MMVG Shell HiFi
Fixed Valves
Shell HiFi Plus
SVG / LVG
Shell Swirl Tube
Sieve
Bubble Cap MVG Valve High Performance
Downcomer
Dual Flow
Baffle
Shower Deck
Disc & Donut
Cartridge
Redirecting Devise
Introduction
Mass Transfer Components
Process design Thermodynamics
Column design - Fluiddynamics
Capacity, Pressure Drop
Efficiency
Column Internals
Assumptions: Assumptions:
Equilibrium stage model Mass transfer considerations
HETP rather constant for Dependent on loading
different physical properties
and hydraulic behavior
Used: Used:
Vapor side controlled systems Liquid side controlled systems
Mostly Distillation Mostly Absorption
L/V 1 L/V not close to unity
Relative volatility < 2 Relative volatility > 2
=
1
Lecture ETHZ | March 2017 | slide 19
Content Sulzer Chemtech
Introduction
Mass Transfer Components
Process design Thermodynamics
Column design - Fluiddynamics
Capacity, Pressure Drop
Efficiency
Column Internals
= 34000 , = 25000
= 34000 , = 60000
= 0.4 , = 930
= 100
= 35
= 6.3
= 34000 , = 60000
= 0.4 , = 930
= 100
= 35
= 6.3
= 34000 , = 60000
= 0.4 , = 930
=?
= 100 = 12
= 35
= 6.3
> 20 2 Beds
: = 12
= ( )
Lecture ETHZ | March 2017 | slide 26
Column Design Distillation Column Sulzer Chemtech
= 100
= 35
= 6.3
= 100
= 35
= 6.3
= 100
= 35
= 6.3
< 0. 9 /
Lecture ETHZ | March 2017 | slide 29
Column Design Distillation Column Sulzer Chemtech
= 100
= 35
= 6.3
= 100
= 35
= 6.3
= 100
= 35
= 6.3
= 100
= 35
= 6.3
Given Data:
= 25000 , = 60000
= 1.4 , = 1000
= 2.5 2
, = 325 2
Given Data:
= 25000 , = 60000 Effective Interfacial Area (Separation Efficiency)
275
= 1.4 , = 1000 Test System: Air/NaOH-CO 2
250 F-factor: 1.5 Pa0.5
= 2.5 , = 325
aI [m /m ]
3
2 2 225
2
200
Results from process design:
175
y
= ln( in ) =13
yout 150
0 10 20 30 40 50 60
3 2
Liquid Load [m /(m h)]
=
MellapakCC Mellapak 250.Y Mellapak 2X
= = 0. 52
Lecture ETHZ | March 2017 | slide 35
Solution Absorption Column M250.Y Sulzer Chemtech
Given Data:
= 25000 , = 60000 Effective Interfacial Area (Separation Efficiency)
275
= 1.4 , = 1000 Test System: Air/NaOH-CO 2
250 F-factor: 1.5 Pa0.5
= 2.5 , = 325
aI [m /m ]
3
2 2 225
2
200
Results from process design:
175
y
= ln( in ) =13
yout 150
0 10 20 30 40 50 60
3 2
Liquid Load [m /(m h)]
=
MellapakCC Mellapak 250.Y Mellapak 2X
Introduction
Mass Transfer Components
Process design Thermodynamics
Column design - Fluiddynamics
Capacity, Pressure Drop,
Efficiency
Column Internals
3in1, VFS
(specials)
Lecture ETHZ | March 2017 | slide 40
Liquid Distributor Types Sulzer Chemtech
Support bar
Arm channel
Liquid guide
Arm channel
Liquid guide
Distributor VKR2
Distributor VRGF
Arm tube
+ simple & cost competitive + flexible turndown 10:1 + robust against fouling
sensitive to fouling expensive @ high DPD + fast bed wetting
limited turndown 3:1 + cost competitive
limited turndown 3:1
Mainly decided by
specific liquid load (m 3/m2h)
column diameter
but also by
medium loads plugging risk
turndown requirement
available space
low loads
Vapor Distribution
Definition of distribution quality
Type of vapor distributors
Evaluation of distribution quality with CFD
H >2 d
ID
d
H >1.5 d
H
Hs
H >1.5 d
For Fv > 60 Pa^0.5 and
Momentum 8000 - 12000 (15000) Pa
Rating of CFD-results
Comparison of different inlet configurations
1 2 3