Nama : Melva Hilderia Sibarani

NIM : 06101381520043
Prodi : Pendidikan Kimia 2015
Kelas : Palembang
Mata Kuliah : Kimia Anorganik 2

Bentuk Geometri

Discuss the geometry of :

1. [PtCl4]2-
2. [NiCl4]2-
3. [Co(NH3)6]3+

Answer :
1. Solution : Geometry of [PtCl4]2-
Konfigurasi elektron dari unsur 78Pt = [Xe] 4f14 5d9 6s1
Konfigurasi elektron dari Pt2+ = [Xe] 4f14 5d8 6s0 6p0
Ada 4 Cl- 4 pasang elektron
5d8 6s0 6p0
Ground state Pt2+

8
5d 6s0 6p0
2+
Excited state Pt

Hybridization state

dsp2

Electrons donated
2-
Geometry of [PtCl4] by ligand 4Cl-
dsp2 hybrid = square planar.
Gives [PtCl4]2- all paired electrons, which makes it diamagnetic and weakly
repelled by magnets.

Magnetic Behavior of [PtCl4]2-

M =
 M =
M =

2. Solution : Geometry of [NiCl4]2-

Konfigurasi elektron dari unsur 28Ni = [Ar] 3d8 4s2 4p0
Konfigurasi elektron dari Ni2+ = [Ar] 3d8 4s0 4p0
Ada 4 Cl- 4 pasang elektron
3d8 4s0 4p0
Ground state Ni2+

Hybridization state

sp3

Electrons donated
by ligand 4Cl-
Geometry of [NiCl4]2- :
sp3 hybrid = tetrahedral.
Gives [NiCl4]2- two unpaired electrons, which makes it paramagnetic and
attracted by magnets.

Magnetic Behavior of [NiCl4]2-

M =

M =

M =
M = 2,83

3. Solution : Geometry of [Co(NH3)6]3+

Konfigurasi elektron dari unsur 27Co = [Ar] 3d7 4s2 4p0
Konfigurasi elektron dari Co3+ = [Ar] 3d6 4s0 4p0
Ada 6 NH3 6 pasang elektron
3d6 4s0 4p0
Ground state Co3+

3d6 4s0 4p0

 Excited state Co3+

Hybridization state


d2sp3

Electrons donated
by ligand 6NH3
Geometry of [Co(NH3)6]3+ :
d2sp3 hybrid = octahedral.
Gives [Co(NH3)6]3+ all paired electrons, which makes it diamagnetic and
weakly repelled by magnets.

Magnetic Behavior of [Co(NH3)6]3+

M =

M =
M = 0

DAFTAR SENYAWA KOMPLEKS

No Ion Ligand Ion Kompleks Senyawa Nama Senyawa

Pusat Koordinasi

1 Zn2+ CN [Zn(CN)4]2+ K2[Zn(CN)4] Kalium

tetrasianozinkat(II)

2 Ag+ NH3 [Ag(NH3)2]+ [Ag(NH3)2]Cl Diaminperak(I) klorida

3 Cr3+ NH3 [Cr(NH3)5]3+ [Cr(NH3)5]Cl3 Pentaaminkromium(III)

klorida

4 Co
3+ NH3 [Co(NH3)4]3+ [Co(NH3)4]Cl Tetraaminkobalt(III)
klorida

5 Cr3+ NH3 [CrCl4(NH3)2]3+ [CrCl4(NH3)2]Br Diamintetrakloro

kromium(III) bromida

6 Cr3+ NO2 [Cr(NO2)6]3+ Na3[Cr(NO2)6] Natrium heksanitro

kromat(III)

7 Co3+ NH3 [Co(NH3)6]3+ [Co(NH3)6]Cl3 Heksaaminkobalt(III)

 klorida

8 Pt4+ NH3 [Pt(NH3)4]4+ [Pt(NH3)4]Br4 Tetraaminplatina(IV)

bromida

9 Pt4+ NH3 [Pt(NH3)2]4+ [Pt(NH3)2]Cl4 Diaminplatina(IV)

klorida

10 Co3+ NH3 [Co(NH3)3]3+ [Co(NH3)3]Cl Triaminkobalt(III)

klorida

11 Ni2+ H2NCH [Ni(H2NCH2CH2N [Ni(H2NCH2CH2 Diklorobis(etilendiamin)

2CH2N H2)2]2+ NH2)2]Cl2 nikel(II) klorida
H2

12 Co3+ NO2 [Co(NO2)6]3+ K3[Co(NO2)6] Kalium

heksanitrokobaltat(III)

13 Cr3+ NH3 [Cr(NH3)3]3+ [Cr(NH3)3]Cl3 Triaminkloromium(III)

klorida

14 Ni2+ CN [Ni(CN)4]2+ [Ni(CN)4]Br2 Tetrasianonikel(II)

bromida

15 Cr3+ NO2 [Cr(NO2)6]3+ Na3[Cr(NO2)6] Natrium

heksanitrokromat(III)

16 Co3+ H2O [Co(H2O)6]3+ [Co(H2O)6]Cl3 Heksaaquakobalt(III)

klorida

17 Cu2+ NH3 [Cu(NH3)4]2+ [Cu(NH3)4]SO4 Tetraamintembaga(II)

sulfat

18 Fe3+ CN [Fe(CN)6]3+ K3[Fe(CN)6] Kalium

heksasianoferat(III)

19 Fe2+ CN [Fe(CN)6]2+ K4[Fe(CN)6] Kalium

heksasianoferat(II)

20 V3+ CO [V(CO)5]3+ [V(CO)5]Cl3 Pentakarbonilvanadiu(III)

klorida

21 Fe2+ CO [Fe(CO)4]2+ [Fe(CO)4]Br Tetrakarbonilbesi(II)

bromida

22 Cu2+ NH3 [Cu(NH3)4]2+ [Cu(NH3)4]Cl2 Tetraaminatembaga(II)

klorida

23 Mg2+ MeCN [Mg(MeCN)6]2+ [Mg(MeCN)6]Cl Heksaasetonitrilmagnesiu

 2 m(II) klorida

24 Fe4+ CN [Fe(CN)6]4+ K4[Fe(CN)6] Kalium heksasianidoferat

(IV)

25 Cu2+ H2O [Cu(H2O)2]2+ [Cu(H2O)2]SO4 Diaquatembaga(II) sulfat

26 Co3+ NH3 [Co(NH3)4]3+ [Co(NH3)4]Cl Tetraaminakobalt(III)

klorida

27 Co2+ H2O [Co(H2O)6]2+ [Co(H2O)6]Br2 Heksaaquakobalt(II)

bromida

28 Cr3+ NH3 [Cr(NH3)6]3+ [Cr(NH3)6] Heksaaminkromium(III)

(NO3)3 nitrat

29 Co3+ NH3 [Co(NH3)4]3+ [Co(NH3)4]Br Tetraaminakobalt(III)

bromida

30 Ni2+ en [Ni(en)3]2+ [Ni(en)3](SO4)2 Trisetilendiaminanikel(II)

sulfat

31 Fe2+ CN [Fe(CN)6]2+ Na2[Fe(CN)6] Natrium

heksasianoferat(II)

32 Fe3+ CN [Fe(CN)6]3+ Na3[Fe(CN)6] Natrium

heksasianoferat(III)

33 Cu2+ NH3 [Cu(NH3)4]2+ [Cu(NH3)4]F2 Tetraaminatembaga(II)

florida

34 Cu2+ CN [Cu(CN)4]2+ K2[Cu(CN)4] Kalium

tetrasianokuprat(II)

35 Cr3+ NH3 [Cr(NH3)5]3+ [Cr(NH3)5]Cl3 Pentaminkromium(III)

klorida