log pSO2(g) Cu-O -S Phase Stability Diagram at 1200.

000 C
25

20

15
CuS

10
CuO

Cu2S
5

Cu2O

Cu(l)
0
-12 -8 -4 0 4 8
File: C:\HSC6\Lpp\CuOS1200.ips log pO2(g)
Cu-O -S Phase Stability Diagram at 1200.000 C
C:\HSC6\Lpp\CuOS1200.ips
Species 5
Elements 3
Temperature 1473.150 K
Species Cu O S DeltaG, kcal/mol
1 Cu(l) 1.000 0.000 0.000 -0.014
2 CuO 1.000 1.000 0.000 -6.260
3 Cu2O 2.000 1.000 0.000 -14.310
4 CuS 1.000 0.000 1.000 -3.297
5 Cu2S 2.000 0.000 1.000 -21.377
X = O2(g) 0.000 2.000 0.000 0.000
Y = SO2(g) 0.000 2.000 1.000 -60.883

REACTIONS at T = 1473.150 G / cal

1 1.000 Cu(l) + 0.500 O2(g) -> CuO -6246.200
2 2.000 Cu(l) + 0.500 O2(g) -> Cu2O -14282.500
3 1.000 Cu(l) + 1.000 SO2(g) -> 1.000 O2(g) + CuS 57600.400
4 2.000 Cu(l) + 1.000 SO2(g) -> 1.000 O2(g) + Cu2S 39533.700
5 2.000 CuO -> 0.500 O2(g) + Cu2O -1790.100
6 1.000 CuO + 1.000 SO2(g) -> 1.500 O2(g) + CuS 63846.600
7 2.000 CuO + 1.000 SO2(g) -> 2.000 O2(g) + Cu2S 52026.100
8 0.500 Cu2O + 1.000 SO2(g) -> 1.250 O2(g) + CuS 64741.650
9 1.000 Cu2O + 1.000 SO2(g) -> 1.500 O2(g) + Cu2S 53816.200
10 2.000 CuS + 1.000 O2(g) -> 1.000 SO2(g) + Cu2S -75667.100
COORDINATES OF TRIPLE POINTS
Phases Present Log pO2(g) Log pSO2(g)
1 Cu(l) - Cu2O - Cu2S -4.237 1.627
2 CuO - Cu2O - Cu2S 0.531 8.780
3 CuO - CuS - Cu2S 3.507 14.731
LINES BETWEEN TRIPLE POINTS AND AXIS
Log pO2(g) Log pSO2(g) Log pO2(g) Log pSO2(g)
1 Cu2O - Cu2S -4.237 1.627 0.531 8.780
2 CuO - Cu2S 0.531 8.780 3.507 14.731
3 Cu(l)-Cu2O -4.237 0.000 -4.237 1.627
4 Cu(l)-Cu2S -5.864 0.000 -4.237 1.627
5 CuO-Cu2O 0.531 0.000 0.531 8.780
6 CuO-CuS 12.000 27.471 3.507 14.731
7 CuS-Cu2S -11.225 0.000 3.507 14.731
log pSO2(g) Cu-O -S Phase Stability Diagram at 1250.000 C
25

20

CuS

15

CuO
10

Cu2S
5
Cu2O

Cu(l)
0
-12 -8 -4 0 4 8
File: C:\HSC6\Lpp\CuOS1250.ips log pO2(g)
Cu-O -S Phase Stability Diagram at 1250.000 C
C:\HSC6\Lpp\CuOS1250.ips
Species 5
Elements 3
Temperature 1523.150 K
Species Cu O S DeltaG, kcal/mol
1 Cu(l) 1.000 0.000 0.000 -0.015
2 CuO 1.000 1.000 0.000 -5.361
3 Cu2O 2.000 1.000 0.000 -13.311
4 CuS 1.000 0.000 1.000 -2.467
5 Cu2S 2.000 0.000 1.000 -20.960
X= O2(g) 0.000 2.000 0.000 0.000
Y= SO2(g) 0.000 2.000 1.000 -60.026

REACTIONS at T = 1523.150 G / cal

1 1.000 Cu(l) + 0.500 O2(g) -> CuO -5345.900
2 2.000 Cu(l) + 0.500 O2(g) -> Cu2O -13280.800
3 1.000 Cu(l) + 1.000 SO2(g) -> 1.000 O2(g) + CuS 57574.400
4 2.000 Cu(l) + 1.000 SO2(g) -> 1.000 O2(g) + Cu2S 39096.100
5 2.000 CuO -> 0.500 O2(g) + Cu2O -2589.000
6 1.000 CuO + 1.000 SO2(g) -> 1.500 O2(g) + CuS 62920.300
7 2.000 CuO + 1.000 SO2(g) -> 2.000 O2(g) + Cu2S 49787.900
8 0.500 Cu2O + 1.000 SO2(g) -> 1.250 O2(g) + CuS 64214.800
9 1.000 Cu2O + 1.000 SO2(g) -> 1.500 O2(g) + Cu2S 52376.900
10 2.000 CuS + 1.000 O2(g) -> 1.000 SO2(g) + Cu2S -76052.700

COORDINATES OF TRIPLE POINTS

Phases Present Log pO2(g) Log pSO2(g)
1 Cu(l) - Cu2O - Cu2S -3.811 1.798
2 CuO - Cu2O - Cu2S 0.743 8.629
3 CuO - CuS - Cu2S 3.768 14.680
LINES BETWEEN TRIPLE POINTS AND AXIS
Log pO2(g) Log pSO2(g) Log pO2(g) Log pSO2(g)
1 Cu2O - Cu2S -3.811 1.798 0.743 8.629
2 CuO - Cu2S 0.743 8.629 3.768 14.680
3 Cu(l)-Cu2O -3.811 0.000 -3.811 1.798
4 Cu(l)-Cu2S -5.609 0.000 -3.811 1.798
5 CuO-Cu2O 0.743 0.000 0.743 8.629
6 CuO-CuS 12.000 27.027 3.768 14.680
7 CuS-Cu2S -10.911 0.000 3.768 14.680
log pSO2(g) Cu-O -S Phase Stability Diagram at 1300.000 C
25

20

15 CuS

10

CuO
Cu2S
5

Cu2O
Cu(l)
0
-12 -8 -4 0 4 8
File: C:\HSC6\Lpp\CuOS1300.ips log pO2(g)
Cu-O -S Phase Stability Diagram at 1300.000 C
C:\HSC6\Lpp\CuOS1300.ips
Species 5
Elements 3
Temperature 1573.150 K
Species Cu O S DeltaG, kcal/mol
1 Cu(l) 1.000 0.000 0.000 -0.017
2 CuO 1.000 1.000 0.000 -4.678
3 Cu2O 2.000 1.000 0.000 -12.772
4 CuS 1.000 0.000 1.000 -1.646
5 Cu2S 2.000 0.000 1.000 -20.544
X = O2(g) 0.000 2.000 0.000 0.000
Y = SO2(g) 0.000 2.000 1.000 -59.169

REACTIONS at T = 1573.150 G / cal

1 1.000 Cu(l) + 0.500 O2(g) -> CuO -4660.700
2 2.000 Cu(l) + 0.500 O2(g) -> Cu2O -12737.200
3 1.000 Cu(l) + 1.000 SO2(g) -> 1.000 O2(g) + CuS 57540.800
4 2.000 Cu(l) + 1.000 SO2(g) -> 1.000 O2(g) + Cu2S 38660.000
5 2.000 CuO -> 0.500 O2(g) + Cu2O -3415.800
6 1.000 CuO + 1.000 SO2(g) -> 1.500 O2(g) + CuS 62201.500
7 2.000 CuO + 1.000 SO2(g) -> 2.000 O2(g) + Cu2S 47981.400
8 0.500 Cu2O + 1.000 SO2(g) -> 1.250 O2(g) + CuS 63909.400
9 1.000 Cu2O + 1.000 SO2(g) -> 1.500 O2(g) + Cu2S 51397.200
10 2.000 CuS + 1.000 O2(g) -> 1.000 SO2(g) + Cu2S -76421.600
COORDINATES OF TRIPLE POINTS
Phases Present Log pO2(g) Log pSO2(g)
1 Cu(l) - Cu2O - Cu2S -3.539 1.832
2 CuO - Cu2O - Cu2S 0.949 8.563
3 CuO - CuS - Cu2S 3.951 14.567
LINES BETWEEN TRIPLE POINTS AND AXIS
Log pO2(g) Log pSO2(g) Log pO2(g) Log pSO2(g)
1 Cu2O - Cu2S -3.539 1.832 0.949 8.563
2 CuO - Cu2S 0.949 8.563 3.951 14.567
3 Cu(l)-Cu2O -3.539 0.000 -3.539 1.832
4 Cu(l)-Cu2S -5.370 0.000 -3.539 1.832
5 CuO-Cu2O 0.949 0.000 0.949 8.563
6 CuO-CuS 12.000 26.641 3.951 14.567
7 CuS-Cu2S -10.616 0.000 3.951 14.567