Professional Documents
Culture Documents
1
DOKUZ EYLL NVERSTES
MHENDSLK FAKLTES
METALURJ VE MALZEME MHENDSL BLM
Answer 2
a. Percentage amount of component for X and
Y are indicated in figure on the right in
proportion to the side of the triangle. AX, BX
and CX for X and AY, BY and CY for Y,
b. Binary joint: It is also called Alkemades line connecting two composition points whose
primary fields are adjacent and have intersection with the border line separating their primary
fields.
Non-binary joint: It is the line connecting two composition points and having the intersection
with the border line separating the adjacent fields at its extension.
c. Comp. X solidifies in comp. Triangle AXBY-B-C
Comp. Y solidifies in comp. Triangle A-AXBY-C
d. For X: XXP. The final solidification point is P(peritectic).
For Y: YYPE. The final solidification point is E(ternary eutectic). The ternary eutectic
reaction: Liq. AXBY+A+B
+
e. For Y at T :
E
For Y at T E : Amount of liquid (Liq%) taking part in ternary eutectic reaction is: 13.6
The ternary eutectic reaction: Liq.%(13.6) A(5%)+AXBY(2.15%)+C(6.45%). To calculate the
products of the reaction the perpendiculars drawn from E to each of the side of triangle are used.
E E3
A% =36.8 , 13.6*0.368 = 5%
E E 1+ E E 2 + E E 3
E E1
AXBY% = =15.8 13.6*0.158 = 2.15%
E E 1+ E E 2+ E E 3
E E1
C% = =47.4 13.6*0.474 = 6.45%
E E 1 + E E 2+ E E 3
C% (Total) = 41.5+6,45=47,95
f. A% = 31.25
B% = 68.75 x=1 ; y=2.2 AXBY = A1B2.2
3. A schematic free energy curves at different temperatures (T1, T2, T3, T4 and T5) leading to a
binary phase diagram are given in Figure below. By making use of the free energy curves
given, draw the phase diagram having eutectic and eutectoid reactions in Fig. at bottom right.
It is known that element A goes an allotropic transformation at temperature between T 3 and
T4.
Answer 3
Answer 4
a. G= A X A + B X B ( B A) X B
G= A ( 1X B ) + X B= A +
dG VZRZ
tg = =B A = Since AB=1 and RZ=PX (See the diagram)
dX B AB
dG VZPX
tg = =B A = =VZRX Therefore; B =VZ and A =PX
dX B 1
G= X A G A+ X B G B + RT ( X A ln X A + X B ln X B )
(b) Eqn. (1)
Eqn. (2) G= A X A + B X B
G= X A ( G A + RT ln X A ) + X B ( G B + RT ln X B )
By rearranging Eqn. (1) and comparing this
with Eqn. (2)
A =G A + RT ln X A and B =GB + RT ln X B are obtained.
5. Answer the questions below as regards to the following phase diagram
which forms under equilibrium cooling condition.
a. How can you explain the decrease in melting temperature of the terminus metals as they are
mixed in each other?
b. Calculate the partial amount of and for an alloy
X at temperature T 2
0
which corresponds to a situation where a tendency for separation of A-rich and B-rich phases
exists as a results of mixing.
d. A spinodal transformation takes place when the cooling proceeds under non-equilibrium
condition, due to the slow rate of diffusion with high rate of decrease in temperature.
Formation of a new phase starts with an embryonic transformation which needs an
overcooling to be able to create an embryo big enough in size which helps overcome the size
barrier providing a decreasing a surface-to-volume ratio which results in a decrease in bulk
free energy overriding the increasing free energy due to the interface formation. Formation of
B-rich embryo formation is enhanced by undercooling below the spinodal only when the free
energy change on forming an embryo becomes negative.