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Paper, Paper 2
Pyridine was discovered in 1849 by the Scottish chemist Thomas Anderson as one of the
constituents of bone oil. Two years later, Anderson isolated pure pyridine through fractional
distillation of the oil. It is a colorless, highly flammable, weakly alkaline, water-soluble liquid with a
distinctive, unpleasant fish-like odor.
b) Using relevant bond energy data from the data booklet, calculate another value for the enthalpy
change of atomization of pyridine
c) Write an equation to represent the enthalpy change of combustion of pyridine
d) When 1.13g of pyridine was combusted in a calorimeter, the procedure heated 100g of water
from 25 0C to 87 0C. This is process was known to be 65% efficient. Calculate the enthalpy
change of combustion of pyridine
(Specific heat capacity of water: 4.20 J g-1K-1)
b) The decomposition of H202 can be catalyzed by bromide ions. The rate equation is :
Rate= k[H202][Br-]. Give a 2 step mechanism involving BrO- as an intermediate that is consistent
with this rate equation [2 marks]
CCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCC