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H = NI/L
1.6105 =100 I /0.01m
I=16 A
V=IR
100V=16A. R
R= 6.25
R=L/A
6.25 =1m/10-6m2
= 1.6 105 S/m
= ne
= 1.6 105 /(10241.610-19)=1m2/V-s (6marks)
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CHEM ENG 3029: Materials III
result in higher current and higher magnetic field strength. At very low
temperatures the charge carriers will be frozen and conductivity will decrease
and this results in lower magnetic field strength. (1marks)
2. The following phase diagram is available for Lead/Tin alloys. Develop a graph
that demonstrates electrical conductivity of the alloys as a function of alloy
composition at 0C (Include at least five data points) When lead and tin are
mixed at low concentrations they can dissolve in each other. At this solid
solutions the electrical resistivity can be calculated using the following equation,
=0(1+A.C)
where 0 is the resistivity of the pure metal, A is a constant and C is the weight
percent of the impurity. The value of A for lead/tin system is 0.1. The following
additional information is also available. (15 marks)
Conductivity of pure Tin: 107 Scm-1
Conductivity of pure Lead: 0.5107 Scm-1
Density of -phase at 0C: 5 g.cm-3
Density of -phase at 0C: 10 g.cm-3
Atomic Weight of Tin:119
Atomic Weight of Lead:207
-phase composition at 0C:99.5%Sn, 0.5%Pb
-phase composition at 0C:1.5%Sn, 98.5%Pb
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CHEM ENG 3029: Materials III
= 1/ = 0.68107 (5 marks)
The rest of data points can be calculated in the same way using excel. (5marks)
Sn% alfa wt% beta wt% alfa V% beta V% rho-alfa rho-beta resistivity conductivity
0 5.00E+06
10 91.32653 8.673469 84.03756 15.96244 2.30E-07 1.05E-07 2.10E-07 4760840
25 76.02041 23.97959 61.31687 38.68313 2.30E-07 1.05E-07 1.82E-07 5505211
50 50.5102 49.4898 33.7884 66.2116 2.30E-07 1.05E-07 1.47E-07 6791841
75 25 75 14.28571 85.71429 2.30E-07 1.05E-07 1.23E-07 8139535
90 9.693878 90.30612 5.093834 94.90617 2.30E-07 1.05E-07 1.11E-07 8979297
100 1.00E+07
1.20E+07
1.00E+07
Conductivity S/m
8.00E+06
6.00E+06
4.00E+06
2.00E+06
0.00E+00
0 20 40 60 80 100 120
Sn wt%
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