1.

2.2
2.

1015

3.


pH 3-3.5 10 mg/L

4.

1-2 N HCl
4-5% NaOH

5.

6.

Ca(OH)2CaSO4 CaCl2

7.
pH Al2(SO4)3 BF4

1

pH=6-7 70-95 2

8.

3.1
9. HCN pH pH CN
HCN H++CN (Ka=4.8101025) pH = 7.0
HCN pH 11.5 CN
100 0

90 10

80 20

70 30

60 40
%HCN

%CN
50 50

40 60

30 70

20 80

10 90

0 100
6 7 8 9 10 11 12 13
pH

3.2
10.

11. 2

C12+2OH+CN CNO+2C1+H2O
3C12 +6OH+2CNO 2HCO3+N2+6Cl+2H2O

2
12.

CO2N2 NH4+

13.

14.

15.

16. ()


HCN

HCONH2

NH3 FORMAMIORSE

HCOOH

CO2

4.1
17.
Cr2O3 ()
CrO42 ()Cr2O72 ()
CrO42
Cr2O72 CrO42

3
 Cr2O72

18. 25 pH = 6.5 HCrO4 CrO42

pH = 6.5 HCrO4 CrO42

4.2
19.

20.

21.

22. pH

pH
H2SO3
pH3.0

23.
NaOH Ca(OH)2

24. pH

4
 pH = 7.5-10.0

3.50

3.00

[mg/L Cr()]
2.50

2.00

1.50

1.00

0.50

0
5.5 6.5 7.5 8.5 9.5 10.5 11.5
pH

25.

26.

pH = 4.5-5.0
pH NaOH

5.2
27.
KOHCS2 (xanthogenic acid)

28.
(polystyrene, PS)

5
29.

1 2

6.2
30.
2,000 mg/L 200
L/min

31.


60 mg /L
20 mg/L

32.
18%

33.
1.
2.

3.

4.

5. (natural attenuation)

34.
1.

2.

6
 3.

35.

(wet air oxidation, WAO)
Fenton

36.
(200-350) (1.5-7.0 MPa)

37. Fenton
Fe2+ H2O2 OH
H2O2 Fe2+ OH

38. Fenton
Fe2+ H2O2

7.2
39.

>>