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General Description
Important data for the VRU sizing
(see the questionnaire)
Whilst a tank truck is filled with a product or more products simultaneously, the
mixture of air and hydrocarbon vapours is forced out of the compartments and is led
through a common pipe to a 4 API vapour coupler, located in the same area as the
product loading points. From there the vapours run through a vapour arm or hose
with detonation arrestor to a common vapour collecting line. The vapour collector is
connected to the VRU. Depending on the risk assessment and philosophy of the
terminal owner, a detonation arrestor is installed on the vapour inlet to the VRU. The
design of all components in the vapour circuit inclusive the VRU itself is such that
the total pressure drop at maximum throughput never results in an excess of the
maximum allowable pressure in the compartments of the truck. A mechanical devise,
for instance a vapour blower, is not required.
The hydrocarbon/air mixture usually flows upwards through the carbon beds. The
hydrocarbons are rapidly adsorbed in the pores of the activated carbon in the bottom
The regeneration of the activated carbon is done by pulling vacuum by means of dry
screw vacuum pumps. The engineers of CarboVac have developed this technology
specially to overcome the problems of corrosion and abrasion related to the use of
glycol based seal liquid in liquid ring vacuum pumps.
On top of that the dry pumps consume approximately 40% less energy. Because the
dry screw pumps can be equipped with frequency controllers, the capacity of the
pump can be perfectly adapted to the fluctuating needs in a vapour recovery system.
This way a secondary means is available to reduce the overall energy consumption
considerably. The load of hydrocarbons on the activated carbon is also more
balanced, which reduces the risk of hot spots.
Gasoline and diesel vapours consist mainly of butane and pentane. Their re-
absorption in one of the products of the terminal will slightly increase the REID
Vapour Pressure (RVP) of the product. It is therefore recommended to use a product
with a reasonable daily throughput as absorbent for the VRU. Except the light ends,
also the heat generated by the system is transferred to the circulation storage tank. To
prevent a short circuit of heat and light ends in the circulation system, the inlet and
outlet connections for circulation should be at least 3 meters apart. To prevent an
unacceptable increase of temperature in the storage tank, the volume of the
circulation tank should at least be 300 m3. In extreme cases a closed cooling circuit
for the vacuum pumps can be installed. The temperature difference between
absorbent inlet and outlet at the VRU battery limit is not more than 5 C.
2 PROCESS CONTROL
The system is fully automated, controlled and monitored by means of a PLC. The
cycle time of the system is fixed between 10 and 17 minutes. The start and stop
functions are based on the activity on the loading rack (truck, rail or ship loading). If
the system is also connected to the vapour space of storage tanks, usually a ventilator
is required in the outlet of the VRU and the start/stop function is than based on the
pressure in the vapour collector. This ventilator is usually frequency controlled.
To prevent that the sump of the re-absorber column can be fully emptied and the
return pump runs dry, a level control system is installed, controlling the speed of the
return pump.
All process control parameters are freely adjustable via the PC screen and by
modem. More than 500 process parameters can be accessed and make it possible to
optimize the system fully for the specific loading profile of the terminal at any time.
3 DESIGN REQUIREMENTS
The VRU is usually designed for a maximum daily loading profile, in order to assure
compliance with the emission laws under all circumstances. The loading profile
forms the basis for the selection of the most efficient combination of activated carbon
volume and capacity of the vacuum system. This maximum profile usually occurs
only sporadically. The capacity of a VRU based on activated carbon cannot easily be
enhanced in a later stage, unless precautions have been taken in the design. The
terminal owner should include his enlargement assumptions for the near future in the
design basis of the VRU (for instance an additional loading bay). The daily loading
profile is characterized by following periodical loading volumes. Each of these
values determines a specific part of the VRU.
The flow rate per loading spot is determined by the number of loading arms that can
be in operation simultaneously and the capacity of the loading arms. For truck
loading most commonly used are 4API loading arms. For reasons of static electrical
charge, the flow rate is limited to 144 m3/h for gasoline and 108 m3/h for diesel
loading. A modern truck loading spot is usually equipped with 4 to 6 loading arms.
The truck driver connects one or two arms and starts loading, than he connects one or
two more. Not more than 4 arms are usually in operation at the same time. The larger
the terminal the lower the average number of loading arms simultaneously in
operation. A useful estimate is given by the following formulas:
Na = (Ns x 2) + 2
And
Q(i) = Na x Ca
For two spots we usually take 8 loading arms connected and for very large terminals
(Ns>10) the average number may be even less than 2 per spot.
For the determination of Q(i) we take an average arm capacity of 135 m3/h.
The flow rate may also be limited by the maximum simultaneous pumping rates of
the loading pumps.
Rail car filling stations can be either on-spot or in-line. The flow rates depend on
the capacity of the loading lance, respectively the pumping flow rate.
Q(c) = Ns x Vt
Maximum 16 trucks could be loaded theoretically per spot in a 4 hour period, but
practically only 10 to 12 trucks. For larger terminals the number drops to average 8
to 10 trucks per spot.
On the average rail loading spot a complete train (1000 m3) can be loaded in 2,5 to 3
hours. The time lost between two trains is usually around 1 hour.
The mid section of the carbon bed is used as buffer zone for hydrocarbons. The
regeneration method used by CarboVac, based on a stable vacuum end pressure,
ensures the availability of this buffer at all times.
VRU start/stop control systems based on emission monitoring value push the
saturated zone of the activated carbon high up in the bed and sometimes even past
the buffer zone into the purification zone. The result is that the buffer zone may not
be available at the time it is needed and on top of that elevated adsorption
temperatures may occur in the top of the bed, with risk of a carbon bed heat-up.
The starting method has an almost negligible influence on the energy consumption of
the system and is therefore not recommended.
4 RECOVERED PRODUCT
The number of components present in gasoline and diesel vapours is numerous. The
major part, however, consists of butane and pentane. The average molar mass of the
pure vapour is around 65 g/mole. The average concentration of pure gasoline vapours
is 40% by volume. The mass of recovered product can be calculated as follows.
1 Nm3 of inlet vapour contains 400 litres of hydrocarbons. This is 400/22,5 x 65
grams of HC, or 1161 g HC/m3. In the outlet of the VRU we find less than 5 g/m3.
The recovered mass of hydrocarbons is therefore more than 1158 g/m3. The liquefied
butane/pentane mixture has a density of approximately 600 kg/m3.
The volume of product recovered per m3 gasoline vapour treated is at least 1,9 litres.
This volume goes back to the storage tank.
Increasingly the taxes on gasoline sales are based on volume entering into the
terminal.
The calculation below is hypothetical but illustrative for the potential benefits of the
installation of a gasoline vapour recovery system.
Basic assumptions:
Sales price of 1 litre gasoline at the service station = 1 per litre
Tax at the inlet of the terminal = 0,60 per litre
Cost price of the product = 0,20 per litre
Product sold = 1000 litres
Product recovered = 1,5 litres per m3 vapour treated.
In some European countries a tax exemption of 1,15 litres per 1000 litres leaving the
terminal is granted The calculation is than as follows:
The increase in gross margin is in the order of 1 par m3 product sold at the service
station.
5 MATERIALS USED
Quality and reliability are the prevailing factors for the choice of materials and
equipment used in a CarboVac VRU and insures the satisfaction of end user with
his equipment on the long term. On top of that, equipment, spare parts and services
must be quickly and universally available. CarboVac wants to be an anticipating
and reactive VRU supplier and not a reactionary one. To support these goals we form
partnerships with our principal sub-suppliers.
The pore structure of wood based carbon is most suitable for application in vapour
recovery systems. The mini, meso and macro pores are evenly distributed. The
activation was done by phosphoric acid, which makes it necessary to rinse the carbon
thoroughly with water afterwards to obtain a pH-neutral product. Because of it high
reactivity, the carbon is also more sensitive for the formation of hot spots during the
first period of operation.
Coal based carbons have a much larger percentage of mini pores at the expense of
the meso pores. This makes this type of carbon more sensitive for aging. Aging is
caused by the formation of an oily heel, built up from high boiling hydrocarbons (e.g.
isobutanol) from the gasoline vapour. Due to the narrow pore structure the heel is
slowly restrained from participation in the cyclic adsorption/regeneration process.
The carbon looses a considerable part of it adsorption capacity in 5 to 10 year of
operation. The sensitivity for hot spots is less than that of wood based carbon.
The first generation of vapour recovery systems used liquid ring vacuum pumps,
using a glycol-water mixture as seal liquid. The continuous and turbulent contact of
the glycol with air causes oxidation of the glycol and formation of acids. Although
this process can be slowed down by introducing anti- oxidation dopes, it is usually
necessary to change the fluid once per year. The formation of acids causes excessive
corrosion and abrasion inside the system and the pumps with loss of capacity and
increase of power consumption.
An other type of pump applied in vapour recovery systems is the oil lubricated rotary
vane pump. This pump is however not explosion proof and cannot handle liquid
slugs without damaging the oil film that lubricates the metal to metal contact
between vanes and the inside of the pump housing. The loss of oil to the re-absorber
CarboVac uses dry screw vacuum pumps type Cobra, manufactured by BUSCH
Company in Switzerland. This pump complies with all requirement mentioned
above, whilst CarboVac and Busch engineers in close co-operation have enhanced
the pump to adapt perfectly to the VRU application. A secondary advantage is that
the pumps can be fully speed controlled to adapt the capacity to the variable
requirements.
The pumps are completely manufactured from nodular cast iron type GGG40. The
inner parts are PTFE coated. The bearing on both end are oil lubricated. Intermediate
chambers between pump section and the bearings prevent any contact of the
lubricant with the process fluids.
6 SAFETY SYSTEMS
CarboVac supplies an ATEX Explosion Protection Document with the VRU, as
per the European Directive 94/9EU. The VRU is considered to be a unit as per 3.7.1
of the directive. The basic safety feature of the unit is its entire explosion proof
design. The unit resists the pressure of an eventual internal explosion. The direct
Vapour Recovery System installed on the Shell Truck Terminal of Arnhem, Holland.
Capacity 1000 m3/h with an emission limit of < 10 g/m3.
VRU
Naphta circulation
(Absorbents liquid)
Vapour
from other
sources
Naphta tank
Vapour
from tanker
(Naphtha or gasoline)
Tanker loading operation
Tanker
Please provide us with a Plot plan (with scale) and when possible with the following information: location of electrical
room / operator room / pump station / PLC room / Circulation tank / location available for VRU / pipe tracks
Whenfullfilofthequestionnairepleaseprecisewhennecessarytheterminalfutureexpansionorrewampingsothatwecan
alreadycalculatethedesign/costimpactofthosechangesontheVRU
TOPLOADINGBAYS
PLEASEDESCRIBETHETERMINALASITWILLBEINTHEFUTURE(forinstancesomeToploadingbaysmaybetransformintoBottom)
TRUCK Truckaveragecapacity m3
Truckaverageloading
time minute
Dotheyrecovervapour
Yes/No
fromServicestation
Dotheycanloadeddiesel
aftergasolineortheyare Explain
dedicatedtooneproduct
Pressureavailableat
vapourarm(ifknown) mbar
Vapourpressureor
Quantityloadedperday Quantityloadedperyear
PRODUCT Productloaded: Truevapor Temperature(C) Ratio loaded (%)
(m3) (m3)
pressure(mbar)
SOMME=100%
LOADING Max number of trucks to Max trucks in loading
N of top loading Max. nber of arms Max instantaneous flow Maxinstantaneousflowgenerated
Top Loading bays Mono or bi side ? Products to be loaded Flow m3/h be loaded in 4 hours per operation at the same time
BAYS arms connercted simultaneously generated by the bay bythewholeloadinginstallation
loading bays in the loading bays
1 Arm
2 Arms
n1 3 Arms
4 Arms
5 Arms
6 Arms
1 Arm
2 Arms
n2 3 Arms
4 Arms
5 Arms
6 Arms
1 Arm
2 Arms
n3 3 Arms
4 Arms
5 Arms
6 Arms
1 Arm
2 Arms
n4 3 Arms
4 Arms
5 Arms
6 Arms
1 Arm
2 Arms
n5 3 Arms
4 Arms
5 Arms
6 Arms
1 Arm
2 Arms
n6 3 Arms
4 Arms
5 Arms
6 Arms
1 Arm
2 Arms
n7 3 Arms
4 Arms
5 Arms
6 Arms
BOTTOMLOADINGBAYS
TRUCK Truckaveragecapacity m3
Truckaverageloading
time minute
Dotheyrecovervapour Yes/No
fromServicestation
Dotheycanloadeddiesel
aftergasolineortheyare Explain
dedicatedtooneproduct
Pressureavailableat
vapourarm(ifknown) mbar
Vapourpressureor
Quantityloadedperday Quantityloadedperyear
PRODUCT Productloaded: Truevapor Temperature(C) Ratio loaded (%)
(m3) (m3)
pressure(mbar)
SOMME=100%
LOADING Max number of trucks to Max trucks in loading
N of bottom Max. nber of arms Max instantaneous flow Maxinstantaneousflowgenerated
bottom Loading bays Mono or bi side ? Products to be loaded Flow m3/h be loaded in 4 hours per operation at the same time
BAYS loading arms connercted simultaneously generated by the bay bythewholeloadinginstallation
loading bays in the loading bays
1 Arm
2 Arms
n1 3 Arms
4 Arms
5 Arms
6 Arms
1 Arm
2 Arms
n2 3 Arms
4 Arms
5 Arms
6 Arms
1 Arm
2 Arms
n3 3 Arms
4 Arms
5 Arms
6 Arms
1 Arm
2 Arms
n4 3 Arms
4 Arms
5 Arms
6 Arms
1 Arm
2 Arms
n5 3 Arms
4 Arms
5 Arms
6 Arms
1 Arm
2 Arms
n6 3 Arms
4 Arms
5 Arms
6 Arms
1 Arm
2 Arms
n7 3 Arms
4 Arms
5 Arms
6 Arms
MARINELOADINGJETTIES
InthecaseofmarineloadingitisimportanttoproceedastudytoknowdistancefromjettiestotankfarmandtoVRU.Aplotplanwillbehelpful
VESSEL Vesselaveragecapacity
vesselaverageloading
time hour
Aretheyinerted?Which
gas?
Dotheycanloadeddiesel
aftergasolineortheyare Explain
dedicatedtooneproduct
Pressureavailableat
vapourconnection(if mbar
known)
Vapourpressureor
Quantityloadedperday Quantityloadedperyear
PRODUCT Productloaded: Truevapor Temperature(C) Ratio loaded (%)
(m3) (m3)
pressure(mbar)
SOMME=100%
Max vessel in loading Maxinstantaneousflow
LOADING Max. nber of arms Max instantaneous flow
Loading jetties N of loading arms size of the arm in " Products to be loaded Flow m3/h operation at the same time generatedbythemarine
Jetties connercted simultaneously generated by the jetty
in the loading jetties loadinginstallation
1 Arm
2 Arms
n1 3 Arms
4 Arms
5 Arms
6 Arms
1 Arm
2 Arms
n2 3 Arms
4 Arms
5 Arms
6 Arms
1 Arm
2 Arms
n3 3 Arms
4 Arms
5 Arms
6 Arms
1 Arm
2 Arms
n4 3 Arms
4 Arms
5 Arms
6 Arms
1 Arm
2 Arms
n5 3 Arms
4 Arms
5 Arms
6 Arms
1 Arm
2 Arms
n6 3 Arms
4 Arms
5 Arms
6 Arms
1 Arm
2 Arms
n7 3 Arms
4 Arms
5 Arms
6 Arms
RAILCARLOADINGFACILITY
RailCar/
m3
Train RailCaraveragecapacity
RailCaraverageloadingtime minute
Dotheycanloadeddiesel
aftergasolineortheyare Explain
dedicatedtooneproduct
Pressureavailableatvapour
arm(ifknown) mbar
Nberofrailcarspertrain
Averageloadingtimeofa
completetrain hour
Howmanytrainareloadedin
oneday
VapourpressureorTruevaporpressure
PRODUCT Productloaded:
(mbar)
Temperature(C) Ratio loaded (%) Quantityloadedperday(m3) Quantityloadedperyear(m3)
SOMME=100%
Max
Max. nber of arms Max number of rail car to be Max rail car in loading instantaneous
LOADING Loading is: On Flow m3/h per product if Max instantaneous flow
Loading Track N of loading point Arms per point Products to be loaded connercted simultaneously loaded in 4 hours in this operation at the same time flowgeneratedby
TRACKS Spot or In line different generated by rail car
per rail car track in all the tracks thewholeloading
installation
n1
n2
n3
n4
n5
n6
n7
TANKFARM
Vapourpressureor
Quantityloadedperday Quantityloadedperyear
PRODUCT Productstored: Truevapor Temperature(C) Ratio loaded (%)
(m3) (m3)
pressure(mbar)
SOMME=100%
TOBEFILLEDIFCLIENTWANTSTOCONNECTTHEVRUTOITSSTORAGETANKS,IFTHECLIENTDOESN'TWANTPLEASEFILLONLYTHEINFORMATIONCONCERNINGTHE
ABSORBENTTANK
Filling Flow m3/h Unfilling Flow m3/h Transfer tank to tank are
Max instantaneous filling
Fixed roof or Floating Which tanks can be filled Pumping max capacity How long can be the filling possible ? (please precise Flow Rate of those
TANKS Size (meter) Volume (m3) Products stored flow generated by tank
roof tanks? simultaneously (m3/h) at max flow rate ? (hour) if necessary 1 to transfer
farms (m3/h)
TANKS by pipe/rail/truck/vessel by pipe/rail/truck/vessel tank2,3,4)
n1
n2
n3
n4
n5
n6
n7