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Rigid PET Bottles

Quality aspects of rigid


PET for beverage packaging
Dr. R. Rangaprasad*, Sapan Pandya, Hardik Soni & Swati Patil
PET Testing Laboratory, Hemshell Services, 903/1,
GIDC Makarpura, Vadodara-390 010.

Introduction In glass, the biggest problem is breakage and metal closure


and it is also more expensive now. Beverage manufacturing is
Beverage packaging: worldwide & India market scenario growing at the rate of 20 per cent and all the global beverage
The PET bottle stands out as one of the most dynamic makers are very bullish on India. They are investing in new
pack formats in the retail packaging marketplace, facilities and will continue to drive our growth.
particularly in its stronghold of soft drinks where it accounts New techniques like flip open caps and better closures are
for 77% of all packaging unit volume gains over 2004-2009. emerging and there is greater emphasis on packaging with the
Health-driven purchasing decisions further provide growth of modern retail and rising competition
potential for PET outside its core remit of bottled water.
RTD tea, juices and milk offer other sources of growth. In India, dairy to emerge as a major consumer of PET
Global Polyethylene Terephthalate (PET) market is bottles by 2020
estimated at 20.98 million tonnes in 2014. The market is Demand for PET bottle packaging of milk and milk
expected to grow at a CAGR of 6.1% during the forecast products is clocking 25-30 per cent CAGR.
period, to reach 29.93 million tonnes by 2020. Asia-Pacific, As dairy majors increase packing milk products in PET
with its thriving economies and rapidly expanding bottles, packaging firms are upbeat on the growing demand.
population, will experience highest growth rate during this Besides, dairy majors like Amul are mulling to add two more
period. aseptic lines that will create an additional one million bottle
Replacement of traditional packaging applications and per day capacity at two sites, Gandhinagar and near Godhra.
reduced atmospheric emissions are the reasons for increase in In dairy, the advent of PET is very recent, about two-three
the demand of Polyethylene Terephthalate (PET). The Asia- years old since the time Gujarat Cooperative Milk Marketing
Pacific region contributes to 38% share of the global Federation (GCMMF) set up the aseptic PET bottle
consumption. China is the largest consumer in the Asia- line.Amul is planning to add another one million bottles per
Pacific region. day (bpd) capacity in two aseptic lines, one each at
About 77 % of the PET resin demand is from packaging Gandhinagar and Godhra in the coming months for an
bottle industry which includes beverage bottles for mineral investment of about Rs 200 crore, informed GCMMF,
water, carbonated soft drinks, ready to drink tea, dairy, and Managing Director, R S Sodhi. He added that with the
functional & energy drinks. It is expected that light-weight expansion, Amul's total bottling capacity would touch 2.5
PET bottle trend will continue in future as it is an efficient million bpd.
cost saving measure. "We are the pioneers in bringing in aseptic technology in
India, and it involves a rigorous process of heating the liquid
Indian market for PET bottles to about 170 degrees, then cooling it down, sanitising the
The market of PET bottles is around Rs 4,000 crore and is bottles as well as the filling chamber," he said adding that as of
growing at the rate of 20 per cent. Liquor and pharma
companies are increasingly switching over to plastics as it is a
more convenient form of packaging compared to glass. It is
unbreakable, occupies less space, and is liked by consumers.

For enquiries : email: author.ppp@gmail.com Dr.R.Rangaprasad Mr. Sapan Pandya Mr. Hardik Soni Ms. Swati Patil
Email: rangaprasad@hemshellservices.com

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Rigid PET Bottles

now GCMMF had no plans to pack liquid milk inPET they have become more expensive to produce compared to
bottles as the shelf life would be low. GCMMF is packing its plastic bottles and cumbersome for most consumers to carry.
flavoured milk and certain other value-added products in The company is sampling Rs 10-12 small plastic bottles in
PET bottles as one of the greatest advantages of such Maharashtra, said people familiar with the development, and
packaging is it is not only handy and is multi-serve(one can it may withdraw reusable glass bottles from most regional
just close the lid and consume the remaining liquid later), it is markets in the next three to four years. In its biggest market,
also more convenient to transport. the US, Coke stopped selling its iconic 6.5 oz (192 ml) glass
Other dairy majors, like Maharashtra-based private dairy bottles in 2012 due to similar reasons.
player Parag Milk Foods too is upbeat on PET bottle "Each of our packages play a role in our OBPPC
packaging. It has, in fact, started trials for packing liquid milk (occasion, brand, price, pack and channel) plans. Returnable
in PET bottles apart from flavoured milk. Devendra Shah, glass bottles are a big part of this plan and serves as a
chairman and managing director of Parag says that demand recruitment pack," said a CocaCola India spokesperson.
for PET bottle packaging is growing fast. "At present, it is "So, doing away with glass bottles is not a possibility. As a
still a negligible portion of our milk packaging. We mostly part of providing choice, we are launching several single-
pack our flavoured milk in such packs, however, the demand serve packs this season -Tetra Pak, 250 ml juice PET and the
is growing at a tremendous rate in metros," he said. 300 ml sparkling PET."
Industry insiders feel that demand for PET bottle Recently, Coca-Cola and PepsiCo, the largest beverage
packaging of milk and milk products is clocking a 25-30 per makers in the country, have come under threat from small
cent CAGR. Herein lies the opportunity for packaging local players, who have managed to wrest away around 10%
players like Manjushree Technopack, which are packer for market share from the Rs 14,000 crore aerated drinks
some of the top beverage companies in the country including industry.
Pepsico and Coca Cola. Currently water, juice and "At least 20 new players including Delhi-based Xalta,
carbonated beverages contribute almost 45 per cent to its Alwar-based Jayanti Beverages and Bareilly's Boss Beverages
turnover. have been nibbling away at the biggies' market shares with
VimalKedia, managing director of Manjushree said that cheaper products packaged in small plastic bottles," said a
Parag is working with them for PET bottle packaging. The soft drink bottler.
company has invested over $5 million to bring in the high- Even packaged water maker Bisleri entered the segment
speed aseptic line to India, with an eye to tap the dairy this year with four ? zzy beverages priced at Rs 10. "Glass
market. Parag has introduced its 'Farm-to-Home' fresh milk bottles are a nuisance for a beverage maker," said Ramesh
in select cities in PET bottles. Dairies in South India are using Chauhan, founder of Bisleri.
PET packaging for products like ghee. "First, you have to sell them many times to recover cost of
Today, 60 per cent of PET consumption comes from the the bottle. Secondly, their cleaning process is a big headache.
beverage sector and it is believed that by 2020 liquor and milk Add tothat their weight that increases logistics cost.
alone will account for 20 per cent of the consumption. Kedia
said, "Until now PET bottles were used to pack value added
dairy products only. Fresh milk has a shelf life of four to
Introduction to PET
seven days and needs to be in the cold chain compulsorily. PET, which stands for polyethylene terephthalate, is a
Since we do not have the requisite infrastructure in place, form of polyester.It is moulded into rigid bottles and
PET bottle is not yet popular for fresh milk. However things containers for packaging foods and beverages, home care,
are changing quickly; Parag Milk from Pune has given us a go personal care products, edible oil, pharmaceutical
ahead for packaging milk in PET bottles across Pune and preparations etc.
Mumbai." He added that Manjushree is also working with
state run co-operatives like KMF (Karnataka Milk Manufacturing routes for PET
Federation), MILMA (Kerala) and AAVIN (Tamil Nadu) in
PET resins are produced commercially from ethylene
the dairy sector.
glycol (EG) and either dimethyl terephthalate (DMT) or
For that matter, the company, which is using about 66,000
terephthalic acid (TPA). DMT and TPA are solids. DMT has
tonnes per annum capacity out of its 80,000 tonnes per
a melting point of 140C (284F), while TPA sublimes (goes
annum installed capacity, is now planning to add another
directly from the solid phase to the gaseous phase).Both
manufacturing unit at Harohalli near Bangalore to increase
processes first produce the intermediate bis-(2-
the capacity to 1 lakh tonnes per annum in the coming years.
hydroxyethyl)-terephthalate (BHET) monomer and either
methanol (DMT process) or water (TPA process). The
News flash BHET monomer is then polymerized under reduced
CocaCola may stop glass bottles Times of India pressure with heat and catalyst to produce PET resins. The
primary reaction for the DMT process is:
http://timesofindia.indiatimes.com/business/india-
business/CocaColamaystopglassbottles/articleshowprint/
Coca-Cola may stop selling soft drinks in glass bottles as

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Rigid PET Bottles

The primary reaction for TPA process is: Sparkling PET bottles attract attention. Brilliant glass-
clear presentation of your products
lPure products taste good. PET complies with
international food contact regulations.
In chemical terms, ethylene glycol is a diol, an alcohol with lSafe PET bottles are tough and virtually unbreakable
a molecular structure that contains two hydroxyl (OH) during production, storage and transportation. If they
groups, and terephthalic acid is a dicarboxylic aromatic acid, do fail, they split, not shatter. Their high impact and
an acid with a molecular structure that contains a large, six- tensile Strength makes them ideal for carbonated
sided carbon (or aromatic) ring and two carboxyl (CO2H) products.
groups. Under the influence of heat and catalysts, the lGood barrier the low permeability of PET to oxygen,
hydroxyl and carboxyl groups react to form ester (CO-O) carbon dioxide and water means that it protects and
groups, which serve as the chemical links joining multiple maintains the integrity of products giving a good shelf
PET units together into long-chain polymers. Water is also life. PET also has good chemical resistance.
produced as a by-product. lLightweight 10% weight of an equivalent glass pack,
The presence of a large aromatic ring in the PET repeating PET bottles reduce shipping costs by about 30%, and
units gives the polymer notable stiffness and strength, because the material in the wall is thinner, shelf
especially when the polymer chains are aligned with one utilization is improved by 25% on volume compared to
another in an orderly arrangement by drawing glass. High strength, low weight PET bottles can be
(stretching).After polymerization in the melt phase, the stacked as high as glass.
molecular weight of polyester can be further increased by lNo Leakage Absolute closure integrity is possible
polycondensation of PET chips in the solid state and this because of the injection molded neck finish. The
process is called solid state polymerization (SSP). absence of a weld line in the base means that PET bottles
Polycondensation reaction is exothermic, therefore, it can don't leak.
also be driven forward to give polymer with higher molecular lGood Resistance PET offers the best chemical
weight if the reaction is carried out at a lower temperature. At resistance performance of any mainstream polymer
lower temperatures of polycondensation, equilibrium shifts used in packaging today.
forward to higher completion enabling formation of higher lLong Shelf-life very good shelf-life performance,
molecular weight of the product. Since temperatures cannot especially with the new higher barrier formulations.
be lowered in melt polymerization, the best solution is to lRecyclable excellent environmental profile due to single
carry out the reaction in solid state, wherein temperatures material. Used PET bottles can be washed, granulated
lower than melting point of the polymer can be used. At these into flakes and reshaped as PET bottles or employed as
temperatures, the kinetics of the reaction is slow and it takes a material for strapping, carpeting, fibre filling, etc.
long time to complete the reaction. Specially designed thick-wall bottles can be washed,
The SSP is performed at temperatures between 220 and refilled and reused. PET is made from the same three
235C for PET, which lie above the glass transition elements (carbon, oxygen, and hydrogen) as paper, and
temperature and below the crystalline melting point of PET. contains no toxic substances. When burned, it produces
Under these conditions, polymer chain end groups are carbon dioxide gas and water, leaving no toxic residues.
mobilized sufficiently to undergo polycondensation. The lDesign flexibility suitable for containers of all shapes,
annealed chips are heated in a stream of hot inert gas or by sizes, neck finishes, designs and colours.
agitating in a vacuum drier to remove small traces of EG and
other volatile by-products. As the reaction is carried out in Manufacturing process of PET preform and
the solid phase, volatile by-products can diffuse easily to the
surface of each polymer chip and are instantly carried away
bottles
by the gas flow or high vacuum. lPET bottles are produced by a two-stage process
The molecular weight can be increased up to IV 0.90 for known as Injection Stretch Blow Moulding (ISBM).
bottle grade and as high as IV 1.20 for technical applications The process depicted in figure involves the production
such as tyre cord, seal belts and air bags. of an injection moulded PET bottle blank or preform
followed by subsequent reheating, stretching and blow-
Key attributes of PET moulding to produce a full-sized bottle. PET naturally
absorbs water from its surroundings. Before processing
lPET is a virtually unbreakable, colourless, lightweight, it is usually heated to reduce its moisture content to less
transparent polymer. than 50 parts per million to avoid hydrolytic reactions
lAs PET is transparent, it allows the content of the which reduces its quality by generation of acetaldehyde.
container to remain visible. The robustness of PET is After about 4 hours of drying at a temperature of not
vitally important for beverage packaging since it makes more than 160C (to avoid thermal degradation), the
the bottles completely safe for on-the-go or sports use. PET is melted and injected into the preform mould,
lCrystal clear products look good, pure and healthy. resulting in the production of the PET bottle preform.

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Rigid PET Bottles

The PET bottle preform is heated to the correct profile recommended. The IV of PET is determined from the
for blowing, after which it is introduced into the blow flow times of polymer solution and pure solvent in a
mould. The hot preform is simultaneously stretchedand viscometer at a designated temperature. The IV value
blown inthe blow mould to form the bottle. will vary depending on the type of solvent used and
temperature conditions.
Role of machine builders in producing IV is measured in an Ubbelohde Viscometer using
Phenol + 1, 1, 2, 2-Tetrachloroethane (60:40 w/w)
quality PET bottles solvent at 30C as per ASTM D 4603.
The role of machine builder in the success of PET as an
alternative to glass as a packaging material of choice cannot lMIV (Melt intrinsic viscosity):
be underplayed. A microprocessor controlled, capillary Melt
The type of dryers, preform injection moulding units & Viscometer, is specifically designed to test the flow
blowing stations all combine to deliver top quality bottles at properties of PET. The system can be used to test other
very high production speeds. polymers and because it does not require solvents, it can
Machine builders like SIDEL, Husky, Ferromatik also be used to test insoluble polymers.
Milacron, Windsor, etc. are a part & parcel of the PET It consists of a heated vertical barrel, a calibrated die, a
success story. small piston called a "follower", a displacement
transducer called a "probe" and control systems for the
nitrogen gas flow and extruder temperature.
Technical Characteristics of PET Resin
The equipment is based on a system developed by ICI.
Preforms& Bottles and their significance It is designed for both research and quality control of
The key to produce a good preform & have it converted in polyethylene terephthalate (PET), which is hygroscopic
to a usable bottle, meeting the specifications of the end user and liable to degrade due to oxidation in the melt phase.
industry,is a technology, comprising intimate knowledge of The apparatus is recommended for use in the quality
material attributes, machine & the ability to control the control of polyester polymers to measure the intrinsic
journey of the PET material from raw material to a viscosity and degradation rates.
dimensionally accurate rigid packaging format. The Viscometer extrudes molten PET similar to an MFI
but is specially developed to prevent the polymer from
These attributes are discussed in detail below degrading due to contact with the atmosphere. The
polymer is isolated from moisture and oxygen because
lIntrinsic Viscosity (IV): the barrel is sealed and the polymer is extruded through
PET resins are classified on the basis of IV which is a the die using pure nitrogen at high pressure.
measure of average length of polymer molecular chains Therefore, an external supply of Nitrogen gas of 30 Bar
or molecular weight. It influences the melt viscosity and pressure is required. This nitrogen gas not only
processing behaviour of PET and properties of the end provides an oxygen and moisture free environment for
products. It is used by most PET producers to control the sample but also applies the extrusion force.
the polymerization process, to assist customers in the The quantity of polymer extruded is calculated similar
selection of polymers for specific Application and to to the MFI method B using an LVDT "probe" to
control the preform moulding process. Generally, if an measure the movement of the "follower". The rate of
application requires higher strength, a high IV is extrusion is accurately measured by the "probe", which
is designed to operate under the highpressure conditions
within the barrel during extrusion.
The system calculates the total thermal and hydrolytic
degradation.
Therefore, a "Melt" test can show the degradation due
to the presence of moisture in the polymer so can be used
to check the performance of the production drying
system. A "Melt" test can also be used to measure the
thermal degradation factor caused by the production
extruder.
PET has historically been measured using the solution
method and this indicates the potential Intrinsic
Viscosity (IV) of the polymer but does not show how
the polymer will behave or degrade during extrusion.
The solution technique is being phased out due to the
insoluble nature of highly crystalline polymer plus high
FIG: Manufacturing process of Preforms and Bottles
environmental and disposal costs of solutions. It is also

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not so suitable for testing reground or recycled material by a sample and uses this to calculate comparative colour
because the quantity tested is very small and may not values. PET bottle producers are constantly striving to
show the "Average IV" of the mixed granules. manufacture high quality products where appearance is
The instrument is designed to replace the solution an equally critical factor like any other property.
method so directly reports the Intrinsic Viscosity (IV) of Reflected/ transmitted colour, yellowness and haze
the polymer and not the Melt Flow Rate. affect the appearance of a bottle. The colour should be
PET is hygroscopic and any water molecules present at as close to neutral as possible. The colour values are
melt temperatures > 250C will give an irreversible break generally measured on an L, a, b scale, by three
in the chain at the ester linkage, which gives a drop in the components, i.e. L*, a* & b*.
IV. Therefore, the PET Plus can ONLY give the same l 'L' denotes - Black to White. When L value is '0', it
IV as the solution method if ALL the moisture is indicates Black & '100' indicates White. Black to
removed from the polymer before it is tested (less than White goes through 'Grey'.
20ppm moisture). l 'a' denotes Red to Green. When 'a' value is '+ ve',
The instrument is a semi-automatic system so can be left it indicates Red & '-ve' indicates Green.
unattended after the sample has been loaded and l 'b' denotes Yellow to Blue. When 'b' value is '+
preconditioned. The test takes a total of 17 minutes after ve', it indicates Yellow & -ve' indicates Blue.
loading the sample. l The L, a, b values are controlled in such a way that
the preforms/bottles will have asclose to neutral
lResidual Acetaldehyde (AA) Content: colour as possible.
Acetaldehyde is a colourless, volatile substance with a
fruity smell. Although it forms naturally in some fruits, lOTR (Oxygen transmission rate) test:
it can cause an off-taste in bottled water. Acetaldehyde This test is used to determine the oxygen transmission
forms by degradation of PET through the mishandling rate (OTR) for total formed bottles or containers.
of the material. Oxygen transmission rate is a critical property in
High temperatures (PET decomposes above 300 C or understanding the shelf life of packaged foodproducts.
570 F), high pressures, extruder speeds (excessive shear Transmission rates are dependent on surrounding
flow raises temperature), and long barrel residence times environmental conditions such as relative humidityand
all contribute to the production of acetaldehyde. temperature. Different packaging materials have
When acetaldehyde is produced, some of it remains different transmission rates. Low barrier materials
dissolved in the walls of a container and then diffuses suchas HDPE have high transmission rates compared to
into the product stored inside, altering the taste and high barrier materials such as PET or EVOH.
aroma. This is not such a problem for non-consumables
(such as shampoo), for fruit juices (which already lCrystallinity:
contain acetaldehyde), or for strong-testing drinks like It is a measure of the degree of crystalline order in PET
soft drinks. But for bottled water, low acetaldehyde molecule. The crystallinity is directlyrelated to the
content is quite important, because, if nothing masks the density of polyester and is normally derived from the
aroma, even extremely low concentrations (1020 parts density value. Crystallinity should be above 50%, so
per billion in the water) of acetaldehyde can produce an that the chips do not soften and form agglomerates
off-taste. during drying prior to moulding.
ASTM F 2013 used for measuring the content of
acetaldehyde in PET. lMoisture content in resin:
The important points to note about AA formation are: PET is a hygroscopic material; it absorbs moisture from
l It is generated under heat, when PET is in molten the atmosphere. The amount of moisture within a PET
condition. sample is measure using the coulometeric Karl Fischer
l It is product of Thermo-chemical degradation and, technique.
to a lesser extent of oxidative degradation.
l The rate of formation at a particular temperature is lFinish dimension or Neck dimension for bottle and
dependent on resin formulation. preform:
l Three different types of AA are analysed in PET The test is designed to ensure that all thread finishes on
resin and containers are Residual AA measured in bottles or preforms comply with the dimensions and
Resin, Preform AA- Preforms, Headspace AA allowable tolerances specified on the respective bottle
Bottles, Lower the AA content of the preform, the finish design drawings.
better it is for the contents.
lWeight and Capacity:
lColour: Plastic bottles must meet the capacity requirements of
The most widely used technique in PET industry is the the country in in which the bottles will be used. Bottle
colorimetric spectrophotometer, which measures the weight can impact a number of performance attributes.
wavelength distribution of light reflected or transmitted The purpose of this test is to determine the weight of a
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bottle along with fill point and overflow capacity. lCarbonation retention testing:
Maintaining CO2 content within specified limits is
lWall thickness of bottle/preform: essential to ensuring product shelf life quality. This
The purpose of this test is to measure wall thickness in testing used to determine the ability of filled and capped
distinct regions of plastic bottles or containers in order bottles to retain carbonation. Plastic bottle carbonation
to monitor and compare with physical performance. levels vary with time due to volume expansion (creep),
Successful bottle or container performance is related to sorption, and permeation. Carbonation loss may also
several critical properties that are dependent on the wall result from improperly applied closures.
thickness profile consistency such as CO2 permeation
rate, O2 ingress, water vapor transmission rate, volume lSection weight for bottle testing:
change, and top-load strength. Weight distribution consistency is an important factor
in bottle performance. Each bottle type has a unique
lConcentricity of the preform: material distribution profile depending on the gram
Various factors of package quality, wall thickness weight and processing technique.
uniformity throughout the preform periphery are
dependents on the quality of the Preform. The purpose lEnvironmental Stress cracking test for CSD bottles:
of this test is to verify that preform wall thickness This procedure evaluates the performance of bottle
according to specifications. bases when they are exposed to a 0.2% solution of
NaOH (Sodium Hydroxide) to simulate the failure
lPerpendicularity of PET bottle: associated with Stress Cracking.
This test method is used to measure plastic bottle,
container, and preform finish Perpendicularity. Bottles The hydroxide ion is the main catalyst of stress cracking
and containers must stand upright, perpendicular to in PET bottles. A bottle that has more resistance to
their bearing surface for filling. PET preform finishes Sodium Hydroxide attack should be more resistant to
must be perpendicular for the blow molding operation. stress crack initiators that a bottle may be exposed to
during its lifetime. This procedure evaluates the
lDrop test on PET bottles performance of bottle bases when they are exposed to a
This test is used to determine the ability of a filled bottle 0.2% solution of NaOH (Sodium Hydroxide) to
or container to withstand a free-fall drop. The bottles simulate the failure associated with Stress Cracking.
or containers must survive the drop heights specified in
this test method. The minimum drop height survival BIS standards for PET
ensures customer satisfaction and acceptable
production and distribution environmental lIS 14764: PET containers for packaging of
performance. VANASPATI-specification. This standard covers the
requirements, methods of sampling and tests for stretch
lTop load test of PET bottle: blow moulded polyethylene terephthalate (PET)
This test is used to measure the top load compression containers for packaging of Vanaspatiin quantities of I
force of empty bottle, filled bottle, Hotfill plastic kg, 2 kg and 5 kg or 1 litre, 2 litres and 5 litres.
bottles or containers. The samples must withstand top lIS 14537: PET bottles for packaging of alcoholic
load forces during use. The top load force survival liquors-specification.Thisstandard prescribes the
ensures the empty bottles or containers withstand a requirements and the methods of sampling and test for
compression from lift cylinders in filling and capping polyethylene terephthalate (PET) bottles for packaging
operations. Top load results may be used to calculate of alcoholic liquors.
the finishedproduct pallet stack heights during storage. lIS 12252: This standard covers Specification for PET
and PBT for their safe use in contact with food stuffs,
lHot fill finish stability: pharmaceuticals and drinking water.
Hot fill is used to evaluate the bottle finish distortion lIS 12887: PET bottles for packaging of edible oils-
resistance from liquid hot filling. The manufacturing specification. This standard prescribes the requirement
process, container material, crystallinity level, and and the methods of sampling and testing for
preform design affect the hot fillprocess distortion polyethylene terephthalate (PET) bottles for packing of
resistance of the finish. 1 kg and 2 kg edible oils.
lIS 13123: Packing of liquid pesticides PET bottles up to
5 litter capacity. This standard prescribes the
lBottle burst testing:
requirement and the methods of sampling and testing
This test is used to determine the bottle failure-point
for polyethylene terephthalate (PET) bottles for
from rapid pressurization. Plastic bottles are rapidly
packing of 5 litter liquid pesticides.
pressurized during the filling operation and a low
lIS 11298: Plastic films for electrical purposes. This
failure point could cause major production issues.

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Rigid
Rigid PET
PET Bottles
Bottles

Standard gives the requirements for balanced biaxially the complexities involved in the manufacture of Quality PET
oriented poly-ethylene terephthalate (PET) film for use bottle for beverage packaging.
as electrical insulation.
References:
In conclusion 1. Business standard online edition
It is evident that PET is fast emerging as an effective 2. Times of India online Edition
option to glass in the packaging sector. It is therefore, 3. Various internet resources
imperative to understand every aspect of this wonder 4. Published data from various PET raw material suppliers,
polymer, including raw material, processing & testing to Machinery & PET Testing instrument suppliers from
produce a Quality Bottle for the end use application. The various company websites n
review paper is intended to provide the reader an overview of

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