Cinemtica qumica

Clculos y resultados:

1. Datos obtenidos en laboratorio

Tiempo(min) Gasto NaOH Gasto NaOH

(para 5 ml) (para 100ml)
0 4.7 94
10 5.3 106
20 5.5 110
30 6.3 126
40 6.8 136

2. Determinar concentraciones a distintos tiempos:

t=0 minutos:

NCH3COOC2H5 x 0.1 L = 1.05 N x 0.094 L

NCH3COOC2H5 = 0.987 N

t=10 minutos:

NCH3COOC2H5 x 0.1 L = 1.05 N x 0.106 L

NCH3COOC2H5 = 1.113 N

t=20 minutos:

NCH3COOC2H5 x 0.1 L = 1.05 N x 0.110 L

NCH3COOC2H5 = 1.155 N

t=30 minutos:

NCH3COOC2H5 x 0.1 L = 1.05 N x 0.126 L

 NCH3COOC2H5 = 1.323 N

t=40 minutos:

NCH3COOC2H5 x 0.1 L = 1.05 N x 0.136 L

NCH3COOC2H5 = 1.428 N

3. Cuadro resumen:

Tiempo(min) A Ln (A)
(concentracin NCH3COOC2H5 )
0 0.987 -0.0131
10 1.113 0.107
20 1.155 0.144
30 1.323 0.279
40 1.428 0.356

0.4

0.35

0.3

0.25

0.2
Ln(A)

y = 0.0091x - 0.0075
0.15 R = 0.9799

0.1

0.05

0
0 5 10 15 20 25 30 35 40 45
-0.05
tiempo

y = 0.0091x - 0.0075

Ln (A) = -kt + Ln (A0)

Ln (A0)= -0.0075

K= -0.0091