ANGGIARINI NURTHASEPTYA M.

1531010196

Question problem 11.

11.19. Estimate the fugacity of one of the following

a. Cyclopentane at 110 oC and 275 bar. At 110 oC the vapour pressure of cyclopentane is 5.267
bar.
b. 1-butene at 120 oC and 34 bar. At 120 oCthe vapour pressure of 1-butene is 25.83 bar.

Answer:

The following vectors contain data for Parts (a) and (b):

(a) = Cyclopentane; (b) = 1-butene

511.8 45.02 0.196 0.273 258 3

= ( ) = ( ) =( ) = ( ) = ( )
420.0 40.43 0.191 0.277 239.3
322.4 383.15 275 5.267
= ( ) =( ) =( ) = ( )
266.9 393.15 34 25.83

0.7486
0.117
= = ( ) = = ( )
0.9361 0.6389

Calculate the fugacity coefficient at the vapour pressure by Eq.(11.68):

(a) PHIB (1 , 1 , , 1) = 0.900

(b) PHIB (2 , , , 2) = 0.76

2

Eq. (3.72), the Racket equation:

0.749
= = ( )
0.936

Eq. (11.44):

2 3
107.546
= [ . (1) ]
7
= ( )
133.299

. ( ) 11.78
= [ ( , , . . [ ])] =( )
. 2029