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Engineering Chemistry
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Foreword v
Preface vii
1. General Chemistry 1
Learning Objectives 1
1.1 Valence Bond Theory 1
1.2 Hybridization and Shapes of Molecules 2
sp Hybridization 3
sp2 Hybridization 5
sp3 Hybridization 5
Lone Pair in Hybrid Orbitals 7
1.3 Molecular Orbital Theory 8
Linear Combination of Atomic Orbitals (LCAO) 9
MO Diagram of Homodiatomic Molecules 11
MO Diagram of Heteronuclear Diatomic Molecules 14
1.4 Metallic Bond 17
Theories of Metallic Bond 17
1.5 Hydrogen Bond 20
Types of Hydrogen Bond 21
Consequences of Hydrogen Bonding 22
1.6 van der Waals Forces 24
1.7 Solid State 25
Crystalline Solids 26
Amorphous Solids 26
Differences between Amorphous and Crystalline Solids 26
1.8 Space Lattice and Unit Cell 27
1.9 Types of Unit Cell 28
1.10 Cubic Lattice 30
Calculation of Number of Particles per Unit Cel 31
Density Computation 31
1.11 Crystal Structure 34
Packing Efficiency 36
Radius Ratio Rule 38
Relation between Void Radius and Atom Radius in Close Packing 39
1.12 Braggs Law X-Ray Structure of Crystals 42
X-Ray Structure of Crystals 42
1.13 Liquid Crystals and Their Applications 45
Classification of Liquid Crystals 46
Types of Mesophases 47
Liquid Crystalline Behavior in Homologous Series 50
Applications of Liquid Crystals 51
3. Stereochemistry 119
Learning Objectives 119
3.1 Stereoisomerism 119
Types of Stereoisomers 120
3.2 Chirality and Optical Activity 120
Concept of Chirality 120
Chirality and Symmetry Elements 121
Fischer Projections 123
Concept of Optical Activity 125
Measurement of Optical Activity 125
Relation between Chirality and Optical Activity 126
3.3 Optical Isomerism 130
Enantiomers and Optical Activity 130
Diastereomers and Optical Activity 131
Relation between Number of Optical Isomers and Stereogenic Carbons 132
3.4 Configuration 133
Relative Configuration (D and L System) 134
Absolute Configuration (R and S System) 136
3.5 Geometrical Isomerism 140
cis and trans Nomenclature 140
E and Z Nomenclature 142
Geometrical Isomerism in Cyclic Structures 143
3.6 Conformational Isomerism 144
Newman Projections 144
Conformations 144
Conformations of Ethane 145
Conformations of n-Butane 146
Conformations of Cyclohexane 146
Key Terms 148
Objective-Type Questions 149
Review Questions 152
Numerical Problems 155
Answers 156
5 Electrochemistry 199
Learning Objectives 199
5.1 Electrical Conductance 200
Types of Electrolytes 200
Conductivity of Solutions of Electrolytes 200
Specific Conductance 201
Equivalent Conductance 202
Molar Conductance 202
Ionic Conductance 202
Factors Affecting Conductance 204