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Class : XII (All) (Jee Advanced) Paper 2 Date : 04.12.2016( M.M : 240 Subject : PCM

Part I (Physics)
Topic : Center of Mass + Collision + Rotation + KTG
Single Answer Type questions (+4, -1)
1. N molecules each of mass m of gas A and 2N molecules each of mass 2m of gas B are
contained in the same vessel at temperature T. The mean square of the velocity of
molecules of gas B is v 2 and the mean square of x component of the velocity of molecules
w2
of gas A is w 2 . The ratio is
v2
1 2
(a) 1 (b) 2 (c) (d)
3 3
2. A gas is filled in a cylinder, its temperature is increased by 20% on Kelvin scale and
volume is reduced by 10%. How much percentage of the gas will leak out
(a) 30% (b) 40% (c) 15% (d) 25%
3. 1
mole of helium gas is contained in a container at S.T.P. The heat energy needed to
2
double the pressure of the gas, keeping the volume constant (specific heat of the gas
3 J gm1 K 1 ) is

(a) 3276 J (b) 1638 J (c) 819 J (d) 409.5 J

4. If the molecular weight of two gases are M1 and M1, then at a temperature the ratio of root
mean square velocity v1 and v2 will be
M1 M2 M1 M 2 M1 M 2
(a) (b) (c) (d)
M2 M1 M1 M 2 M1 M 2

5. At room temperature, the r.m.s. speed of the molecules of certain diatomic gas is found to
be 1930 m/s. The gas is
(a) H 2 (b) F2 (c) O 2 (d) Cl 2
6.

7.

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8.

Multiple Answer Type questions (+4, 0)

9. A gas in container A is in thermal equilibrium with another gas in container B. both
contain equal masses of the two gases in the respective containers. Which of the
following can be true
PA P
(A) PA V A PB VB (B) PA PB , V A VB (C) PA PB , V A VB (D) B
V A VB
10.

11.

12.

13.

14.

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15.

16.

Comprehension Type questions (+4, -1)

Comprehension - 1

17.

18.

Comprehension 2

19.

20.

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 Part II (Chemistry)
Topic : Hydrocarbon + Gaseous state + Isomerism
Single Answer type question (+4, 1)
21. The rms velocity of the molecule of a diatomic gas is . When the temperature is doubled the
molecule dissociated into two atoms. The new rms speed is
(A) 2 (B) (C)2 (D) 4
22. The values of critical pressure and critical temperature for gas A are 34 atm and 126 K whereas
for gas B, they are 48 atm and 305 K respectively . Identify the correct statement
(A) Gas B has the smaller van der Waals constant,b.
(B) Gas A has the smaller van der Waals constant,a.
(C) Gas B exhibits the most nearly ideal behavior at 250C and 10 atm pressure
(D) Gas B has lower value for critical volume.
23. The value of van der Waals constant a for gases O2, N2, NH3 and CH4 are 1.360, 1.390, 4, 170
and 2.253 litre2 atm mol-2 respectively. The gas, which can most easily be liquefied, is:
(A) O2 (B)N2 (C) NH3 (D) CH4
24. If a real gas obey following equation P(V nb) = nRT, at very low pressure then the intercept and
d
slope of graph between vs P are respectively.
p
2
MR M RT M Mb Mb M RT b
(A) , (B) , (C) , (D) ,
T b RT RT 2 RT RT 2 M M RT 2

25. A small bubble rises from the bottom of a lake, where the temperature and pressure are 8C and
6.0 atm, to the waters surface, where the temperature is 25C and pressure is 1.0 atm. Calculate
the final volume of the bubble if its initial volume was 2 mL.
(A) 14 mL (B) 12.72 mL (C) 11.31 mL (D) 15 mL
26.

27. Which of the following compounds can show geometrical isomerism.

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28.

Multiple answer type : (+4, 0)

29. a
The real gas equation P 2 (Vm b) RT reduces to
Vm
(A) PVm = RT at low pressure and high temperature
(B) P(Vm b) = RT at very high pressure
a
(C) P 2 Vm RT at very low pressure
Vm

a
(D) 2 (Vm b) RT at very low pressure
Vm
30. Which of the following is correct for critical temperature?
(A) It is the highest temperature at which liquid and vapour can coexist.
(B) Beyond this temperature, there is no distinction between the two phases and a gas cannot be
liquefied by compression.
(C) At this temperature, the gas and the liquid phases have different critical densities.
(D) At this temperature, the gas can be called vapour
31. Following represents the Maxwell distribution curve for an ideal gas at two temperature T1 andT2.
Which of the following optioni(s) are true?
U mps1
T1 I A1 = Area of small rectangle I

U mps2 A2 = Area of small rectangle II

1 dN A1 T2
II
N dU A2

u
dU1 dU 2
(A) Total area under the two curves is independent of moles of gas
(B) If dU1 = f Umps1 and dU2 = f Umps2 then A1 = A2
(C) T1 T2 and hence higher the temperature, sharper the curve
(D) The fraction of molecules having speed = Umps decreases as temperature increases

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32. Which of the following graphs represents Boyles law
(A) (B)
PV P

P 1/V

(C) (D)
P
log P

V log V

33. On heating 1,3-dichlorocyclobutane compound (A) is formed. Find correct statement regarding
compound (A).
(a) Degree of unsaturation of compound (A) is 2.
(b) Dipole moment of compound (A) is zero.
(c) Compound (A) is a bicyclo compound
(d) Compound (A) is a spiro compound
34. Butane 1,4-dioic acid is decarboxylate via soda lime. Find correct statement/s regarding product.
(a) A gaseous hydrocarbon is generated
(b) The gaseous hydrocarbon has no bond
(c) Another gas (B) is formed which has zero dipole moment.
(d) The gas (B) is a linear gas
35. Find the hydrocarbons which on monochlorination can give only one product.
(a) Methane (b) Ethane (c) Propane (d) Neopentane
36. For which of the given gases, liquification process is easier than that of CO2.
(a) SO2 (b) H2O (c) H2 (d) Br2
Passage Type Questions : (+4, -1)
Passage- 1

37. Calculate the partial pressure of gas A (in cm of Hg) filled above Hg( )
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 (a) 55 (b) 43 (c) 33 (d)None of these
38. Calculate the partial pressure of Kr (in cm of Hg) filled above Hg( )
(a) 32 (b) 33 (c) 55 (d) 42
Passage II

39. Which of the above hydrogen can be abstracted most easily by halogen in presence of sunlight?
(a) P (b)Q (c) R (d) S
40. In the above reaction how many monobrominated products are possible ? (structural isomer only)
(a) 3 (b) 4 (c) 5 (d) 7

Part III (Mathematics)

Topic : Parabola
Single Answer type question (+4, 1)
41. If parabola y2 = x and 25[(x-3)2 + (y + 2)2] = (3x4y2)2 are equal then value of is :
(a) 9 (b) 3 (c) 7 (d) 6
42. Minimum area of circle which touches the parabolas y x 2 1 and y 2 x 1 is:
9 9 9 9
(a) sq.unit (b) sq.unit (c) sq.unit (d) sq.unit
16 32 4 8
43. Two tangents on a parabola are x y 0 and x y 0 . If (2,3) is focus of the parabola , then
The equation of tangent at vertex is :
(a) 4x 6y 5 0 (b) 4x 6y 3 0 (c) 4x 6y 1 0 (d) None of these
44. The maximum numbers of common chord between two parabolas can be
(a) Exactly 1 (b) at most 2 (c) 4 (d) 6
45. Tangents PA and PB are drawn from point P on the directrix of the parabola
2 2 2
169 x 2 y 3 5 x 12 y 3 then the least radius of the circumcircle of the triangle

PAB is
23 23 13 9
(a) (b) (c) (d)
26 13 23 23
46. The mirror image of the parabola y 2 4 x with respect to the tangent to the same parabola at
the point (1, 2) is
2 2 2
(a) x 1 4 y 1 (b) x 1 4 y 1 (c) x 1 4 y 1 (d) None of these
47.

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 (a) 1 (b) 2 (c) 3 (d) 4
2 2
48. For the parabola x y 2xy 6x 2y 3 0 the focus is :
(a) 1, 1 (b) 1 , 1 (c) 3 , 1 (d) None of these
Multiple answer type (+4, 0)
49. If equation of tangent at P, Q and vertex A of a parabola are 3x+4y7=0, 2x+3y10=0 and
xy=0 respectively then which of the following is not correct
(a) focus of the parabola is (4, 6) (b) length of latusrectum is 2 2
(c) Equation of axis must be x+y=10 (d) vertex of the parabola is (5, 5)
50.

51. The equation of common tangent(s) to the parabola y x 2 and y x 2 4x 4 is /are

(a) y 4 x 1 (b) y 0 (c) y 4 x 1 (d) y 30x 50
52.

53. Parabola y 2 4x and the circle having its centre at (6, 5) intersect at right angle. Possible point of intersection of
these curves can be
(A) (9, 6)
(B) 2, 8 (C) (4, 4)
(D) 3,2 3
54. A square has one vertex at the vertex of the parabola y 2 4ax and the diagonal through the vertex lies along the axis
of the parabola. If the ends of the other diagonal lies on the parabola, the coordinates of the vertices of the square are
(A) 4a,4a (B) 4a, 4a (C) (0, 0) (D) 8a,0

55. If 4(x 2y + 1) + 9(2x + y + 2)2 = 0 represents a parabola then

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(A) centre is (0, 1) (B) length of latusrectum =
9 5
(C) tangent at vertex is x 2y + 1 = 0 (D) equation of axis is 2x + y + 2 = 0
56.

Passage Type Questions : (+4, -1)

Passage- 1
Consider the parabola P which touches y = 0 at (1, 0) and x = 0 at (0, 2)
57. The vertex at P is :
16 2 4 2 12 6
(a) , (b) , (c) , (d) None of these
25 25 5 5 25 25

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58. Length of latusrectum of P is :
9 16 5 16 8
(a) (b) (c) (d)
5 5 25 25 25
Passage II
If l,m are variable real numbers such that 5l 2 6m 2 4lm 3l 0 , then variable line lx my 1
always touches a fixed parabola, whose axes is parallel to x-axis.
On the basis of above information answer the following questions
59. Vertex of the parabola is :
5 4 7 3 5 7 1 3
(a) , (b) , (c) , (d) ,
3 3 4 4 6 6 2 4
60. Focus of the parabola is :
1 7 1 4 3 3 3 3
(a) , (b) , (c) , (d) ,
6 6 3 3 2 2 4 4

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