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MOLECULAR GEOMETRY
NOTE: Print out the table at the end of this document. This is the worksheet
that you will fill in during lab and turn in at the end of class.
Introduction:
TABLE #1
2 Linear
3 Trigonal planar
4 Tetrahedral
5 Trigonal Bipyramidal
6 Octahedral
EXAMPLE:
Electron Domains = 4: (Each bond counts as one domain, and each unshared pair
counts as one).
Molecular Geometry = Bent (The E.D. geometry is a tetrahedral with each angle equal
to approximately 109 degrees. But two of the region do not have bonds therefore the
overall shape is bent.)
Polarity: (Since oxygen is much more polar than hydrogen and the
molecule is not symmetrical there is a dipole moment with the most electronegative
region around the oxygen atom.)
Procedure:
Students will be divided into groups. Each group will be assigned one of the lists
on the following page. Groups will complete data sheet #1 and build a model for each
assigned molecule. The lab instructor will approve each model. There will be no formal
lab report required for this lab. Turn in completed data sheet prior to leaving.
Remember:
Elements below and to the right of P may or may not obey the octet rule.
Hydrogen and halogens will not form multiple bonds.
Oxygen is seldom the central atom.
C is almost always the central atom.
There are no ring compounds in the list
AsCl3 CO2
PBr5 PBr3
BCl3 NO2-1
AlF6-3 XeF2
SO2 SF6
TeCl4 BF3
ClF3 ClO4-1
PO4-3 ICl4-1
I3-1 H2CO ( no O-H bond)
CH3+1 AsO4-3
LIST C LIST D
H2S CCl4
NH4+ H3O+
PCl6-1 COCl2
GaI3 PCl5
SbCl5 POBr3
IF5 ClO3-1
SeF4 XeF4
CO3-2 BrF3
SeO3-2 SO3
HgCl2 NH3