1.

The ICl molecule is

(a)Purely covalent (b) Purely electrovalent
(c)Polar with negative end on chlorine (d)Polar with negative end on iodine
2. Which of the following substance when dissolved in water will give a solution that does not conduct electricity
(a) HCl (b) KOH (c) CH3COONa (d) NH2CONH2
3. Which of the following compounds has a 2 electron 3 centre bond
(a) BF3 (b) NH3 (c) B2H6 (d) CO2
4. Which one of the following has a co-ordinate bond
(a) NH4Cl (b) AlCl3 (c) NaCl (d) Cl2
5. The number of dative bonds in sulphuric acid molecule is
(a) 0 (b) 1 (c) 2 (d) 4
6. Which of the following has the highest dipole moment
(a) AsH 3 (b) SbH 3 (c) PH 3 (d) NH 3
7. Dipole moment of NF3 is smaller than
(a) CO (b) CO 2 (c) BF3 (d) NH 3
8. The dipole moment of chlorobenzene is 1.73 D. the dipole moment of p -dichlorobenzene is expected to be
(a) 3.46 D (b) 0.00 D (c) 1.73 D (d) 1.00 D
9. Cathode rays are produced when the pressure in the discharge tube is of the order of
(a) 76 cm of Hg (b) 10 6 cm of Hg (c) 1 cm of Hg (d) 10 2 to
3
10 mm of Hg
10 .The charge of an electron is 1.6 10 19 C . The value of free charge on Li ion will be
(a) 3.6 10 19 C (b) 1 10 19 C (c) 1.6 10 19 C (d) 2.6 10 19 C
11. The number of atoms in 0.004 g of magnesium are

(a) 4 10 20 (b) 8 10 20 (c) 10 20 (d) 6.02 10 20

12. A transition metal X has a configuration [ Ar ] 3d 4 in its + 3 oxidation state. Its atomic number is
(a) 25 (b) 26 (c) 22 (d) 19
13. CO 2 is isostructural with
(a) SnCl 2 (b) SO 2 (c) HgCl2 (d) All the above
14.The radius of the nucleus is related to the mass number A by
(a) R R0 A1 / 2 (b) R R0 . A (c) R R0 .A 2 (d)
R R0 .A1 / 3
15. Who modified Bohrs theory by introducing elliptical orbits for electron path
(a) Hund (b) Thomson (c) Rutherford (d)Sommerfeld
16. The expression for Bohrs radius of an atom is
n 2h2 n 2h 2 n 2h 2
(a) r (b) r (c) r (d)
4 me z
2 4 2
4 me z
2 2
4 2me 2 z 2
n 2h2
r
4 2m 2 e 2 z 2
17. The third line in Balmer series corresponds to an electronic transition between which Bohrs orbits in hydrogen
(a) 5 3 (b) 5 2 (c) 4 3 (d) 4 2
18. The frequency of yellow light having wavelength 600 nm is
(a) 5.0 1014 Hz (b) 2.5 10 7 Hz (c) 5.0 10 7 Hz (d)
2.5 10 14
Hz

19. If change in energy, (E) 3 10 8 J, h 6.64 10 34 J s and c 3 10 8 m / s, then wavelength of the light is

(a) 6.36 10 3 (b) 6.36 10 5 (c) 6.64 10 18 (d)

6.36 10 18

20. The frequency of a wave of light is 12 10 14 s 1 . The wave number associated with this light is
(a) 5 10 7 m (b) 4 10 8 cm 1 (c) 2 10 7 m 1 (d)
4 10 4 cm 1
21. The deBrolglie wavelength of a particle with mass 1 g and velocity 100 m/s is

(a) 6.63 10 33 m (b) 6.63 10 34 m (c) 6.63 10 35 m (d)

35
6.65 10 m

22. Uncertainty in position of a 0.25 g particle is 10 5 m . Uncertainty of velocity is ( h 6.6 10 34 J s)

(a) 1.2 10 34 (b) 2.1 10 32 (c) 1.6 10 20 (d) 1 .7 10 9
23. 81.4 g sample of ethyl alcohol contains 0.002 g of water. The amount of pure ethyl alcohol to the proper number of
significant figures is
(a) 81.398 g (b) 81.40 g (c) 81.4 g (d) 81 g
24. Two elements X and Y have atomic weights of 14 and 16. They form a series of compounds A, B, C, D and E in which for
the same amount of element X, Y is present in the ratio 1 : 2 : 3 : 4 : 5. If the compound A has 28 parts by weight of X and 16 parts
by weight of Y, then the compound of C will have 28 parts weight of X and
(a) 32 parts by weight of Y (b) 48 parts by weight of Y (c) 64 parts by weight of Y (d) 80 parts
by weight of Y
25. A sample of pure carbon dioxide, irrespective of its source contains 27.27% carbon and 72.73% oxygen. The data support
(a) Law of constant composition (b) Law of conservation of mass
(c) Law of reciprocal proportions (d) Law of multiple proportions
26. Sulphur forms the chlorides S 2 Cl 2 and SCl 2 . The equivalent mass of sulphur in SCl 2 is
(a) 8 g/mole (b) 16 g/mole (c) 64.8 g/mole (d) 32
g/mole
27. What is the concentration of nitrate ions if equal volumes of 0.1 M AgNO 3 and 0.1 M NaCl are mixed together
(a) 0.1 M (b) 0.2 M (c) 0.05 M (d) 0.25 M
28. A 400 mg iron capsule contains 100 mg of ferrous fumarate, (CHCOO )2 Fe . The percentage of iron pasent in it is
approximately
(a) 33% (b) 25% (c) 14% (d) 8%
29. Vapour density of a metal chloride is 66. Its oxide contains 53% metal. The atomic weight of the metal is
(a) 21 (b) 54 (c) 27.06 (d) 2.086
30. Number of gm of oxygen in 32.2 g Na 2 SO 4 .10 H 2 O is
(a) 20.8 (b) 22.4 (c) 2.24 (d) 2.08

30. Calculate the ratio of rate of effusion of O2 and H2 from a container containing 16gm O2 and 2gm H2 :
(A) 1 : 8 (B) 8 : 1 (C) 1 : 4 (D) 4 : 1
Ans. (A)
31. Temperature at which most probable speed of O2 becomes equal to root mean square speed of N2 is [Given : N2 at 427C]
 (A) 732 K (B) 1200 K (C) 927 K (D) 800 K
Ans. (B)

32. The density of gas A is twice that of B at the same temperature the molecular weight of gas B is thrice that of A. The ratio of
pressure of gas A and gas B will be
(A) 1 : 6 (B) 7 : 8 (C) 6 : 1 (D) 1 : 4
Ans. (C)
33. Select the correct option for an ideal gas undergoing a process as shown in diagram.
(A) If 'n' is changing , 'V' must also be changing.
(B) If 'n' is constant , 'V' must be constant.
(C) If 'n' is constant , 'V' must be changing.
(D) If 'n' is changing , 'V' must be constant.

Ans. (AB)
34. The term that corrects for the attractive forces present in a real gas in the Vander Waals equation is

an 2 an 2
(A) nb (B) (C) (D) nb
V2 V2
Ans. (B)

35. Which one can act as oxidising & reducing agent both-
(A) HNO2 (B) H2O2
(C) H2SO3 (D) all [D]
36. If Kp for a reaction ,
A(g) + 2B(g) 3C(g) + D(g)
is 0.05 atm at 1000 K, its Kc in terms of R will be -
(1) 20000 R (2) 0.02 R
5 10 5
(3) 5105 R (4)
R
37.Which mixture of gases at room temperature does not obey Dalton's law of partial pressure- [B]
(A) NO2 and O2 (B) NH3 and HCl
(C) CO and CO2 (D) SO2 and SO3