1.

Mgcl2 Mg2++2cl- Basis=100ml

1
0,000102mol MgCl2 Mg2+ + 2Cl BASIS = 100ml
1

Mg 2+ = 25 ppm
Mg 2+ = 25 mg X 0,1 L
L
= 2,5 mg X 1 gr
1000mg
= O,OO25 gr

Mol Mg 2+ = 0,0025 gr
24,3
= 0,000102 mol

2
Cl = 1 X 0,0001020 mol
= 0.0002057 mol

Gr Cl = 0,0002057 mol X 71 gr/mol

= O,O146 gr

1
MgCl = 1 0,000102 mol
gr MgCl = 0,000102 mol X ( 71 + 24,3 ) gr/mol
= 0,000102 mol X 95,3 gr/mol
= 0,00972 gr

a) % W/W Mg2+ =0,0025 gr X 100 %

100 ml X 1 gr/ml
= 0,0025 %

b) % W/W Cl2 = 0,0146 gr X 100%

100 ml X 1gr/ml
= 0,0146 %
 KALAU Cl- = 0,0146 % =7,3 X 10 -3 %
2

c) % W/W MgCl2 = 0,00972 gr X100%

100ml X 1gr/ml
= 0,00972 %

d) M MgCl2 = 0,00972 gr X 100 ml/L

95,3 gr/ml 100 ml
= 0,001019 M

e) M Mg2+ = 0,000102 mol

0,1 L
= 0,00102 M

f) M2Cl- = 0,0002057 mol

0,1 L
= 0,002057 M

g) M MgCl2- = 0,000102 mol % = 100% % larutan

0,09999 kg = 100% - 0,00972%
= 0,00102 M = 99,99028 ml X 1 gr/ml
= 99,99028 gr
= 0,09999 kg

2. Ar
PxV=nxRxT
1,50 atm x 0,35 L = n x 0,082 L.atm/molK x 303K
0,525 mol= n x 24,846
n = 47,3257 mol
N2
PxV=nxRxT
0,80 atm x 0,54 L = n x 0,082 L.atm/ molK x 323K
n = 61,301 mol

n total = (47,3257 mol + 61,301 mol )

= 108,6558 mol
P total
 PxV=nxRxT
P x 2,50 L = 108,6558 molx 0,082 L.atm/ molK x 353K
3144,5718
P= 2,50 atm
P= 1257,8287 atm

3. a. RE = nC : nH : nO
60 4,48 2,22
12
: 2
: 1

RE= C2H2O

b. Mr = 2C + 2H + O

= (2(12)+2(1)+16) gr/mol

= 42 gr/mol

RM = (RE)n

Mr RM = Mr (RE)n

180 = (C2H2O)n

180 = (42)n

180
n= 42

n=4,2 = 4

RM= (RE)n

=( C2H2O)4

= C8H8O4

4. V1 x P1 = V2 x P2

24 mlx 58,8 inHg= V2 x 62,5inHg

1411,2
V2 = ml
62,5

V2 = 22,57 ml
5. a. ArCo = 58,933 gr/mol

gr =

1
=
58,933/

= 0,0166 gr
b. 1 Atom Co = 58,933 gr/mol
gr =1/12 x 58,933 gr/mol
=4,9110 amn
c. Massa 1 atom Co = 58,933 gram

6. Mr C6H6O = (6(12) + 6(1) +16) gr/mol

= (72 + 6+16) gr/mol

= 154 gr/mol

7. V1 x M1 = V2 x M2

0,008L x 15 M = 0,50 Lx M2
0,12
M2 =
0,50

M2 = 0,24 M