48 2 Vol.48 No.

2
2011 2 TRANSFORMER February 2011

1 1 2 1 1 1
1. 834003
2. 710032

TM406 B 10018425201102003607

Research on Transformer Sulfur Corrosive Inhibition

with Metal Passivator
YU Hui-min1, MA Shu-jie1, MENG Yu-chan2, ZHANG Qi1,
ZHANG Ling-jun1, GUO Chun-mei1
1. Karamary Lubricating Oil Research Institute of Petro China, Karamay 834003, China;
2.Xi'an Thermodynamics Engineering Research Institute, Xi'an 710032, China

Abstract Based on tests of two metal passivators in transformer oil, the inhibition effect
on sulfur corrosion of power transformer is analyzed.
Key words Transformer Metal passivator Transformer oil

Ciba Irgamet 39
1


SFSZ11-180000/220
,


3 2
2007 3 2007 5
1947 ASTM D1275B
21 500kV 201
1954
174 85.6
29 1
2006 5 14.4
CIGRE WG A2-32

TTA
BTAIrgamet 39 100mg/kg

 2
37

80 ( )
90 15mL 20mL ,

150 72h


IEC 62535 IEC 62535


2.2
500kV
500kV 15
2 9 6
3 2 000t
2
4 30%
2.1 1
1
1 1 2 3
4 5
1 6 2
3
+ ASTM D1275A
DIN 5135 4 6
ASTM D1275B
IEC 62535
IEC 6235
0.08%
500kV
1
1 2
Fig.1 Diagram of technical path
1 2
ASTM D1275A 6 3
ISO 5662 SH/T 0304 4 5
140 19h


DIN 51353
SH/T 0804 100
18h 4


ASTM D1275B
DOBLE 2006 124- 1Ciba
150 Irgamet30 Ciba30
48h 2 T1
1Ciba
IEC 62535 Irgamet39 Ciba39
2 T2
38 48
1 500kV
Table 1 Oil properties of 500kV transformer


1 2 3 4 5 6 1 2 3
/% 0.260 0.286 0.240 0.021 0.286 0.018 2 0.347 0.500 0.402 IEC60666
20 /kgm -3
885.2 883.6 890.6 887.3 882.1 866.7 876.3 865.6 846.6 SH/T0604
40 9.648 8.378 8.603 9.333 9.150 8.309 9.641 8.294 9.646
GB/T265
/mm2s-1 100 2.159 2.256 2.297 2.362 2.289 2.282 2.407 2.256 2.671
-33 66 67 61 38 77 50 70 115 GB/T1995
/gg -1
288 130 180 140 122 221 474 622 244 SH/T0253
CA 9.9 9.5 10.2 8.8 8.4 15.1 6.3 8.5 4.9

CN 43.4 45.2 47.9 47.2 44.9 26.9 44.4 37.2 30.5 SH/T0725
/%
CP 46.7 45.3 41.9 44.1 46.7 58.0 49.3 54.3 64.6
ASTM

2a 1b 1b 3a 3a 1b 1b 2b 2e D1275A
ASTM

1b 1b 4a 4b 4b 2c 1b 2c 1b D1275B
IEC62535

2 500kV
Table 2 Data of corrosire sulfur in oil of 500kV transformer in a net

ASTM ASTM ASTM ASTM ASTM

IEC62533
D1275A D1275B D1275A D1275B D1275B

1 6

2 1

3 2

4 3

T3 3
T4 2.3
 2
39

3
Table 3 Main test devices
ASTM D1275B
1 OTS100AF/2 IEC 62535
2 CA100
3 2821-HB
4 ZHZ501
ASTM D1275B IEC 62535
5 ZHT803IK

6 WG01B
2.3.3 IEC62535

2.3.1
5

4
200mg/kg

4
IEC62535
4 SIEMENS
Table 4 Influence of metal passivators to transformer oil 7.51.530mm
1 2 4-
IEC 62535
Ciba30 T1 Ciba39 T2 T3 T4

/mgkg-1 0 200 200 200 200 200 200


1.35 1.44 0.78 1.48 1.207 1.260 1.8 DL421
/1012m

0.000 1 0.000 6 0.000 2 0.000 1 0.000 3 0.000 5 0.000 2 GB/T5654

/kV 69 70 71 70 63 66 63 GB/T507

6 7
50 51 48 49 49 49 49 GB/T6564
/mNm -1 200mg/kg 60
/mgkg -1
20 17 15 15 14 16 15 SH/T0207 30
IEC 62535
4 2
200mg/kg 6 7 2
2.3.2


4 30

5
5
4 ASTMD 1275A
DIN 51353 IEC 60296 ASTM
D3487 IEC 62535
ASTM D1275B IEC 62535
Ciba39

4
Ciba39
124 - 8
40 48
5
Table 5 Test scheme and resalts

/mgkg -1
0 20 50 100 200
ASTM D1275A
ASTM D1275B
Ciba30
DIN 51353

1 2 4- IEC 62535
ASTM D1275A
ASTM D1275B
T1
DIN 51353
IEC 62535
ASTM D1275A
ASTM D1275B
Ciba39
DIN 51353

IEC 62535
ASTM D1275A
ASTM D1275B
T2
DIN 51353
IEC 62535
ASTM D1275A

ASTM D1275B
T3
DIN 51353
IEC 62535
ASTM D1275A
ASTM D1275B
T4
DIN 51353
IEC 62535

6 50mg/kg
Table 6 Test scheme and resulat of 50mg/kg matal passivators

IEC 62535

7.51.830 mm 11.21.830 mm

60 / 0 3 30 0 3 30
0

50mg/kg T2

50mg/kg T3

50mg/kg T1

50mg/kg Ciba39

50mg/kg Ciba30

50mg/kg T4

8 Ciba39

3

Ciba39 1IEC 62535
2
41
7 200mg/kg
Table 7 Test scheme and results of 200mg/kg metal passivators

IEC 62535

7.51.830 mm 11.21.830 mm

60 / 0 3 30 0 3 30
0

200mg/kg T2

200mg/kg T3

200mg/kg T1

20mg/kg Ciba39

20mg/kg Ciba30

20mg/kg T4

7.51.830 mm 11.21.830 mm 7.51.830 mm 11.21.830 mm 7.51.830 mm 11.21.830 mm

a b +200mg/kg T3 c +200mg/kg T2

7.51.830 mm 11.21.830 mm 7.51.830 mm 11.21.830 mm 7.51.830 mm 11.21.830 mm

d +200mg/kg Ciba39 e +200mg/kg T1 f +200mg/kg Ciba30

2 200mg/kg
Fig.2 Test results of 200mg/kg metal passivators

8 Ciba39
Table 8 Test scheme and results of Ciba39 metal passivators for different copper line

/mm +100mg/kg Ciba39 +100mg/kg Ciba39

1.97.0

1.911.2

1.811.2

1.811.8

1.69.9
1.911.8

2.1211.8

2.46.3

2.612.1
3.010.2
2.07.0

2

 42 48

3 sulation[R]. Interim Report No. 1, 2006.

[2] . [J]].
2008 28 4 17-20.

[3] . [J].

2009 46 2 19-22.
4
IEC62535

1974-

5 IEC62535

[1] CIGRE WG A2-32 Copper sulphide in transformer in- 2009-10-22

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