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Technical Paper

BR-1878

Electrostatic Precipitator Upgrade


Opportunities Through a Review of Best
Performers in Coal-fired Power Plants

Authors:
K.S. Kumar
J.A. Knapik

Babcock & Wilcox


Power Generation Group, Inc.
Barberton, Ohio, U.S.A.

D.S. Hartman

FirstEnergy
Akron, Ohio, U.S.A.

Presented to:
Power Plant Air Pollutant
Control MEGA Symposium

Date:
August 20-23, 2012

Location:
Baltimore, Maryland, U.S.A.
Electrostatic Precipitator Upgrade Opportunities Through a
Review of Best Performers in Coal-fired Power Plants

K.S. Kumar
D.S. Hartman
J.A. Knapik
FirstEnergy
Babcock & Wilcox Power Generation Group, Inc.
Akron, Ohio, USA
Barberton, Ohio, USA

Presented at: BR-1878


Power Plant Air Pollutant Control MEGA Symposium
Baltimore, Maryland, U.S.A.
August 20-23, 2012

Abstract accepted the premise that filterable particulates are surro-


This paper discusses the results of stack emissions testing gates for virtually all trace metals. In the final MATS rule,
conducted by several coal-fired power plants during the last EPA determined that limiting the stack filterable particulate
three years to determine if additional steps need to be taken emissions below 0.03 lb/MBtu based on EPA Test Method
for meeting the upcoming federal regulations for particulate 5 should adequately safeguard public health.
matter (PM), the hazardous air pollutant (HAP) surrogate The specification of filterable PM limits, instead of total
for metals. The population of these plants is quite diverse. particulate matter that included the highly variable con-
The coals utilized include both Eastern bituminous (Eastern) densable fractions, has provided additional flexibility for
high sulfur and Powder River Basin (PRB) low sulfur coals. achieving compliance with existing electrostatic precipita-
One plant utilizes a blend of PRB and Eastern coals. Two tors. Fortunately, during the last fifty years, a considerable
plants utilized wet flue gas desulfurization (FGD) systems body of literature has been generated describing research and
for sulfur dioxide (SO2) control downstream of the dry full-scale operating experience with ESPs. Our approach in
electrostatic precipitators (ESP). The nitrogen oxides (NOx) this paper is to draw from this literature and provide the plant
control strategies on these plants include overfire air (OFA), operators empirical means to assess their ESP performance.
low NOx burners (LNB), selective non-catalytic reduction We review the important literature on the various parameters
(SNCR), and selective catalytic reduction (SCR) systems. affecting ESP outlet emissions. This literature review aims
Two factors stand out from these test results: 1) the to help guide the discussions that follow on the interpreta-
continuing efforts of plant operators to maintain ESP per- tion of results from recent testing at several coal-fired power
formance, and 2) the co-benefits of wet FGDs in reducing plants. Areas for further research on reducing stack filterable
stack filterable emissions. emissions are also identified.
Test results are compared with published reports from
past practice. It is hoped that this paper allows other plant
operators with ESPs to consider similar strategies for filter- Fundamentals of ash properties and
able particulate emission control. ESP corona power a review

Inroduction Interrelationship between gas and ash properties


New EPA rules for the control of mercury and air tox- Sulfuric acid is an excellent fly ash conditioning agent.1
ics, also known as the Mercury and Air Toxics Standards Adequate amounts of this acid can control the ash resistiv-
(MATS), were established in 2012. The air toxics portion ity to manageable levels, in the optimal range of 108 to 1010
of the rules includes control of hydrochloric acid (HCl) and ohm cm. It is known that some Eastern high sulfur coals
several trace metals. After several years of research, propos- with high iron content in the ash can generate elevated
als, industry comments, and stakeholder reviews, EPA has levels of sulfur trioxide (SO3) in the flue gas. Depending

Babcock & Wilcox Power Generation Group 1


on the air heater operation, it is quite possible for these As an example, for an ESP operating at 40 kV average,
plants to operate the ESPs at a flue gas temperature that and at a corona current density level of 50 mA/1000 ft2, the
is below the sulfuric acid dew point. The flyash can then average corona power density would be 2.0 watts/ft2. If this
become too conductive for proper control in the ESP, with level of energization was powered in an ESP with a specific
these particles being subjected to the pith ball effect, an collecting area (SCA) of 200 ft2/1000 acfm, then the specific
electrostatic phenomenon through which the particles lose corona power would be 400 watts/1000 acfm. If the SCA was
their charge at collector plates and are repulsed back into twice as large, at 400 ft2/1000 acfm, then a corona current
the gas stream. The resultant electrical re-entrainment can density of 25 mA/1000 ft2 would produce the same specific
greatly diminish the ESP collection efficiency even if there corona power of 400 watts/1000 acfm.
are no limitations to the introduction of proper corona cur- For a given power plant operating at a given load, and
rent density in the ESP. a given ESP configuration reduced corona current density,
On the other hand, it is also possible for the flyash in changes in coal chemistry, for example, can lead to much
flue gas to get insufficiently conductive.2 This has been reduced specific corona power. This lowering of corona cur-
known to lead to premature flue gas breakdown inside the rent density has the potential to cause an increase in stack
ESP due to the incipient back corona effect. Back corona emissions. A given ESP operating with proper mechanical
severely limits the amount of corona current density that can integrity can shift from days and months of very well ener-
be received by a given electrically energized section of the gized operation to sudden episodes of ESP electrical sections
ESP. Low ash conductivity (or high ash resistivity) has been operating with low corona current. While the worsening of
found to be caused by a combination of reasons: ESP collection can generally be seen as increased opacity, as
Inadequate amounts of free SO3 in flue gas due to the monitored through a continuous opacity monitor at the ESP
highly alkaline nature of the flyash outlet, caution needs to be exercised. Stack opacity is not
Combination of insufficient amounts of SO3 in flue always a good indication for increasing PM rates since it is
gas and alternate conductive species, such as sodium greatly dependent on particle size. Smaller PM tends to have
sulfate, in the flyash less impact on PM rate while it has a large impact on refract-
Combination of high acidity in the flyash, high flue gas ing and attenuating the light, which is then seen as higher
temperature, and low flue gas moisture. That can result opacity. Conversely, larger PM (such as re-entrainment from
in much of any SO3 present in the flyash to be ineffective hopper leakage) may not impact the opacity monitor, but it
in its tendency to adsorb on to flyash particles, render- can have a significant impact on the PM rate.
ing it ineffective for providing the needed conductivity There is a wide variability in plate-to-plate spacing in
the collector electrode designs. Historically, ESP size was
reported in terms of SCA, and typically reported in the units
Corona current and specific corona power of square feet per 1000 acfm. It is customary in todays ESP
Corona current density is defined as the maximum corona evaluation practice to report the ESP size in terms of total
current that can be introduced by a power supply per square residence time. This will avoid the misinterpretation of a
foot of collecting surface of a given ESP electrical section. lower SCA precipitator at higher plate spacing as a smaller
The inlet fields of the ESP experience the maximum dust size unit, even though the treatment times for both may be
concentrations, and are subjected to flue gas breakdown at identical. Engineering evaluations and research on the ap-
lower current density levels as compared to cleaner outlet plication of wider plate spacing technology have revealed
fields. Even in the absence of ash resistivity-induced limi- that collection efficiencies of ESPs with two different plate
tations, it is not unusual for the inlet field corona current spacings and SCAs can be the same, as long as other param-
density levels to be lower by a factor of four as compared eters such as specific corona power are equivalent.5
to the outlet fields.
The relationship among corona current density (mA/1000
ft2), specific corona power (watts/acfm), and collection ef- Performance variability at a given specific
corona power
ficiency across an ESP has been well researched.3,4 It has
been found that when operating an ESP at ash resistivity ESP filterable emissions can vary considerably for a given
levels higher than 5 x 1010 to 5 x 1011 ohm cm, high ash specific corona power. This is a result of several factors:
resistivity-related premature gas breakdown impacts begin Ash cohesivity can vary depending on the nature of
to be noticed. ESP corona current density starts dropping flue gas and ash constituents. It is well known that am-
rapidly and, depending on the size of the ESP, filterable monia conditioning has reduced filterable emissions
emissions may start to increase. considerably, due to control of sulfuric acid concentra-
In most cold-side ESP applications, corona current den- tions, and the introduction of a cohesive agent which
sity levels could vary from values as low as 5 mA/1000 ft2 is a byproduct of the ammonia-sulfur compounds. Cot-
for highly resistive ashes, to levels as high as 75 mA/1000 tingham specifically refers to injection of ammonia for
ft2 for highly conductive ashes. Operating voltages will control of particulate re-entrainment from carbonaceous
vary, depending on plate spacing and discharge electrode particulates.6 Reese and Greco report on the ESP per-
geometry, between 40 to 75 kV, on average. formance enhancement through ammonia injection on

2 Babcock & Wilcox Power Generation Group


high SO3-laden flue gas on Eastern coals.7 Operation cause re-entrainment of ash collected on the plates.
above the sulfuric acid dew point has been maintained These controllers typically allow the precipitator
through sufficient mitigation of SO3 by ammonia injec- power to dwell for excessive periods in the de-ener-
tion. Figure 1, from Reese and Greco, illustrates the gized state, before automatically ramping the power
described effects. Considerable research with novel back to the sparking voltage level. While the average
additives, showing similar results, has also been con- ESP power in these electrical sections would appear
ducted for the purposes of reducing ash resistivity and normal, the ESP particulate collection can suffer from
increasing ash cohesivity.8 re-entrainment due to improper automatic control of
Fine particulate matter may vary from plant to plant ESP energization.
depending on fireside conditions. A significant number d. Excessive collector plate rapping in the outlet fields
of coal-fired power plants have introduced some form will release the collected ash back into the flue gas
of fireside management to reduce flame temperature, stream. Typically, these situations are created by rap-
and thus reduce NOx emissions. It is relevant to de- ping an abnormally high number of collector plates
scribe the correlation between fireside NOx emissions with a single rapper. When rapper intensity levels are
and submicron particulate content as researched by set too high, the ESP corona power may continue to
McElroy through a program funded by the Electric show good levels, while the stack filterable emissions
Power Research Institute (EPRI).9 Figure 2 shows could still suffer due to ash re-entrainment.
the relationship between nitrogen oxide (NO) content
and submicron particulate concentration for coal-fired
boilers of different designs and differing flame tempera- Wet FGD co-benefits
tures. As illustrated in Figure 2, submicron particulate The particulate control co-benefits of operating a wet
matter decreases by more than a factor of three, in di- FGD system after a dry ESP has been documented by Bhat,
rect proportion to the decrease in NO emissions. Both Johnson and Cushing through pilot-scale experiments.11
Hall and White3,4 have shown that, for a given specific Table 1 illustrates the relatively stable total PM outlet load-
corona power in the ESP, filterable outlet emissions ings for a highly varying set of inlet filterable particulate
will decrease if the inlet ESP fine particulate content loadings. A further analysis of this pilot-scale data indicates
is decreased considerably. filterable particulate collection can reach 90% at wet FGD
Ash re-entrainment from ESPs can vary and affect the ash inlet loadings in the 0.10 lb/MBtu range. Additional
filterable emissions considerably. Re-entrainment can
occur due to several factors:10
a. Poor gas flow quality in the ESP, resulting in high
local peak gas velocities. These high local velocities
in the ESP can scour the particulate from collector
plates and increase stack emissions.
b. In another example of poorly distributed gas flow,
even a small component of flue gas flow and entrained
ash directed to the hopper area can find its way to the
stack practically untreated by the ESP.
c. Excessive sparking in the outlet fields of an ESP,
mostly due to outdated power supply controls, can

Fig. 1 Control of ash re-entrainment through ammonia Fig. 2 Flyash fine particulate content versus NO emis-
injection. sions at several coal-fired power plants.

Babcock & Wilcox Power Generation Group 3


Table 1 to be conducted at 250F on an unscrubbed unit, assuming that
Relationship Between Wet FGD Inlet and 10 ppm SO3 is present at the ESP outlet, Figure 3 indicates
Outlet Particulate Emissions at a Pilot Plant that about 8.5 ppm SO3 would have condensed as sulfuric
Total
acid aerosol. The extent of positive bias from condensed SO3
Total Inlet
Outlet
Scrubber SO3 Inlet/Oulet will depend on how much of this aerosol gets retained on the
Date Loading
Loading
Flux Tray* Concentration front half of the EPA Method 5 sampling train.
lb/MBtu
lb/MBtu
gpm/ft2 ppm** Research has shown that the extent of positive bias from
SO3 can vary, depending on the ash loading and alkalin-
2/28/92 0.0073 0.023 85 B -- ity of particulate being caught in the probe. Testing that
2/29/92 0.037 0.017 85 B -- was done to measure the accuracy of SO3 measurements
3/2/92 0.042 0.037 35 B -- revealed that as much as 40% of the sulfuric acid can be
3/3/92 0.42 0.041 35 B -- captured on the filter probe.14 This amount of positive bias
3/4/92 0.22 0.026 35 B -- can have considerable impact on the reported test results. A
3/6/92 0.15 0.03 35 B -- 40% capture rate across the filter probe would amount to 4
3/8/92 0.012 0.027 35 B -- ppm SO3. If 4 ppm SO3 is captured on the probe, positive
4/3/92 0.021 0.022 60 B -- bias on filterable particulate as a result of condensation of
4/4/92 0.13 0.022 85 B --
SO3 on the filter catch can be as high as 0.015 lb/MBtu. For
4/5/92
ashes that are more alkaline, such as that derived from PRB
0.15 0.014 60 C 9/6-7
coals or produced as a result of alkaline sorbents added for
4/6/92 0.061 0.045 60 C 24-26/18-19
SO3 mitigation on Eastern coal applications, the capture ef-
4/7/92 0.046 0.044 60 No Tray 16/11
ficiency of the condensed acid aerosol on filter probes could
4/7/92 0.046 0.049 85 No Tray 16/11
be higher than 40%.
* Tray B has 30% more open area than Tray C
It is not uncommon for ESPs operating with SO3 condi-
** SO3 injection during 4/6 to 4/7/1993 tioning to experience the effects of over-conditioning from
time to time. Process control of SO3 injection can be difficult
reference to the filterable particulate collection in the 90%
if sulfur and alkaline levels in the coal change considerably.
range across wet FGD are made by Kumar and Feldman.12
Therefore, it is possible for flue gas at the ESP outlet to be
However, it is important to understand that one should
saddled with a substantial level of free SO3 in the vapor
not expect filterable particulate collection efficiency of 90%
phase. EPA certified PM continuous emission monitors
across the wet FGD under all conditions. The mechanisms
(CEMs) operate at a filter probe temperature specified by
of particulate collection through impaction and impinge-
Method 5B (320F, plus/minus 25F). At this temperature,
ment in a wet FGD are largely influenced by particulate size
for the stated example, condensed sulfuric acid aerosol is
distribution entering the absorber. The finer the particulate
unlikely to be present at the filter probe temperature. Op-
size of flyash entering the absorber, the lower the expected
eration of the filter probe at this temperature has the most
collection efficiency. Also, stack filterable emissions after the
probability of avoiding SO3-related positive bias on the
wet FGD will be influenced by the degree of re-entrainment
filterable test results.
of scrubber-generated gypsum particulate from the mist
eliminators located at the wet FGD outlet.

Positive bias from contribution of SO3 to filter-


able portion of the probe catch
ESP filterable outlet emissions data can vary widely, even
for a seemingly consistent level of electrical energization.
However, the contribution of artifacts from measurement
emissions test methods can introduce considerable positive
bias to a true filterable emission value. Figure 3, showing
sulfuric acid dew point curves, highlights this phenom-
enon.13 EPA Test Methods 5 and 17 (other than Method 5B),
generally stipulated for unscrubbed units, require the filter
probe temperature to be at 250F, or at the stack temperature
respectively. For units operating with a wet FGD system
ahead of the stack, EPA Method 5B is typically specified.
For an ESP operating at an outlet temperature of 325F,
and with a typical concentration of 10 ppm SO3 at a flue gas
moisture level of 10 %, the sulfuric acid dew point can be
estimated from Figure 3 to be 277F. In this example, the ESP
is operating well above the acid dew point. If stack testing is Fig. 3 SO3 dewpoint curve.

4 Babcock & Wilcox Power Generation Group


ESP performance estimation for various coals Plants 2 and 3 fire Eastern high sulfur coal. They both
Kumar & Feldman estimated ESP performance curves
15 utilize open tower wet FGD for SO2 control and LNB and
showing SCA (normalized at 9 in. plate-to-plate spacing) SCRs for NOx control. Both plants also utilize SO3 mitiga-
versus collection efficiency. Figure 4 demonstrates the tion techniques to control the increase in SO3 produced after
expected performance of ESPs when faced with a variety SCRs were installed. Plant 2 utilizes sodium-based injection
of different fuels. The prediction curves closely correspond ahead of the ESPs. Plant 3 utilizes ammonia injection ahead
with performance estimates reported in a study by Dahlin of the ESPs. Both these plants are equipped with PM CEMS
for EPRI.16 This early work projected that, for comparable to monitor stack filterable emissions.
filterable outlet emissions, ESPs treating flue gas from the Plant 4 is an unscrubbed unit firing 100% PRB coal. SO3
combustion of low sodium, low sulfur western PRB fuels injection is normally used. Considerable additional testing
would need to be more than twice as large as ESPs on plants was also conducted with injection of activated carbon for
firing higher sulfur coals. For reasons explained earlier, the mercury control, and sodium bicarbonate for HCl control
higher resistivity of ash resulting from the firing of PRB ahead of their ESPs. To prevent the adverse impact of SO3 on
coals limits the corona current density in each electrical activated carbon injection (ACI) effectiveness, a proprietary,
section to a much lower level. This would result in lower non-SO3 based alternative fly ash conditioning technique
specific corona power for an ESP of similar size designed was also evaluated.
for Eastern coals. The ESP size, therefore, would need to Plant 5 utilizes 100% PRB coal, but with slightly lower
be larger to achieve the necessary particulate collection, as sodium content in ash as compared to Plant 4. This plant
dictated by the specific corona power considerations. utilizes both OFA and LNB for NOx control. Plant 5 is also
The following sections report on the configuration of unscrubbed and does not use flyash conditioning.
six coal-fired power plants, as well as the associated ESP Plant 6 utilizes Eastern high sulfur coals. It also employs
configuration and operating data. Stack filterable emissions OFA. This plant utilizes ammonia injection to control the
from these plants are reviewed. The above discussion will increase in SO3 produced after SCRs were installed.
guide the review of reported information from these plants. Table 4 shows the relevant details of each ESP. Plants 1,
3, 4 and 6 utilize the North American style ESP design,
which consists of single-piece electrodes, weighted wire
Power plant configurations and opera- and rigid discharge electrode geometries. These designs
tion of the tested units utilize top-mounted rappers, located outside of the flue gas
stream, to dislodge ash collected on both collecting and
Table 2 shows the configuration of power plant boilers
discharge electrodes. Plants 2 and 5 utilize the European
utilized in the stack emissions review. Table 3 lists the prop-
style ESP design, with multiple-piece discharge electrodes
erties of coals being utilized at these plants.
hung between electrode supports in a bed-spring manner .
Plant 1 is an unscrubbed unit that fires a blend of PRB
Table 4 reflects the actual ESP operating information during
coal and Eastern high sulfur Pittsburgh #8 coal. For NOx
the testing period.
control, this plant employs LNBs and OFA. The plant also
The most important parameters affecting ESP perfor-
utilizes an SNCR as an additional NOx control. There is no
mance are presented in Tables 2, 3 and 4. These include:
dedicated fly ash conditioning system in use at this plant.

Table 2
Coal-fired Power Plant Configurations of Tested Units

Plant # 1 2 3 4 5 6

LNB, OFA, LNB, OFA,


NOx Control SCR OFA, SNCR LNB, SOFA OFA, SCR
SNCR SCR
SOx Control None Wet FGD Wet FGD None None None
Dry sorbent injection of
HCl Control None Wet FGD Wet FGD No None
SBC has been tested
Mercury Activated carbon injec-
None Wet FGD Wet FGD No None
Control tion
Opposed Wall- Opposed
Boiler Type Cyclone-fired Tangential-fired None
Fired Wall-fired
Yes, > 20 ppm injection
SO3 rate for ash conditioning.
No No No No None
Conditioning Non-SO3 conditioning
also tested.
Ammonia Yes, for SO3
Conditioning/ Yes, for SO3 mitigation Yes, for SO3 mitigation
No No No
Other SO3 mitigation following SCR following SCR addition
mitigation addition

Babcock & Wilcox Power Generation Group 5


Plants 2 and 5 show operating corona current densities
of 15 to 18 mA/1000 ft2. This is at least a factor of two less
than the values reported for Plants 1, 3, 4 and 6, indicative
of process differences that could result in less conductive
ash limiting the corona current input to the ESPs. The ESP
behavior of Plant 5 can be generally explained as due to a
combination of variations in sodium content of coal, and a
relatively high operating inlet temperature. However, the
reasons for Plant 2 performing at a relatively low operating
corona current density level on Eastern high sulfur coal ap-
plication has not yet been fully researched.

ESP specific corona power versus stack filter-


able emissions
Based on operating voltage and current density data on
ESPs from these six plants, and their respective SCA, ESP
specific corona power values were developed for each of
these plants, utilizing the approach discussed earlier in the
literature review section.
Fig. 4 ESP collection efficiency versus SCA for various coals.
Figure 5 plots the stack filterable emissions data from
1) the average operating corona current density, 2) the ESP these plants. Figure 6 shows the long-term stack filterable
inlet temperature, 3) the ESP residence time, 4) whether emissions performance in 2011 on Plant 2 utilizing EPA
ash conditioning or SO3 mitigation techniques have been Method 5 based certified continuous particulate monitors.
employed, 5) the fireside NOx control techniques, and 6) To better understand the relationship between ESP spe-
the specific ESP corona power. cific corona power and filterable emissions, three separate
curves are plotted and shown in Figure 5: 1) a predicted
curve based on SCA versus collection efficiency relationship
Review and analysis of ESP perfor- developed from research by Dahlin and Kumar and Feldman,
mance and filterable stack testing data 2) a trend line based on data from Plants 1, 4, 5 and 6 all
of which are all unscrubbed units, and 3) a trend line based
on data from Plants 2 and 3, both of which have a wet FGD
ESP corona current density performance system following a dry ESP.
Plants 1, 3, 4 and 6 show operating corona current den- Observations of ESP Performance on Unscrubbed Units
sities between 32 and 54 mA/1000 ft2. This is indicative Though the predicted values of filterable emissions
of a well energized precipitator collecting ash that is well would be higher than 0.03 lb/MBtu in most cases based
conditioned and properly conductive. on the Kumar-Feldman curve, for ESPs operating spe-

Table 3
Coal-fired Power Plant Operational Information on Tested Units

Plant # 1 2 3 4 5 6

PRB/Eastern Eastern Eastern


Coal Type PRB PRB Eastern Bituminous
Coal Blend Bituminous Bituminous
Coal data, as
recd, avg. Similar to Plant
10,225 12,070 8,800 8,800 Similar to Plant # 2
values, #2
Btu/lb
Ash, % 6.6 10.70 - 5.4 5.3 -
Moisture,
20 8 - 27 27 -
%
Sulfur, % 0.9 3.3 - 0.3 0.3 -
5.3
9 to 10 Lower sodium
9 to10 after installation
Ash, LOI, % 2 NA NA Moderate sodium in ash in ash (1.30%
of OFA
(1.3 to 1.7% as Na2O) as Na2O) than
plant # 4

6 Babcock & Wilcox Power Generation Group


Table 4
ESP Operational Data on Tested Units
Plant 1 -- Plant 3 -- Plant 5 --
Plant 2 -- Plant 4 -- Plant 6 --
Weighted Weighted wire and Bed frame
ESP Design Rigid mast bed Weighted wire Weighted wire and
wire discharge rigid discharge discharge elec-
Arrangement frame with twisted electrodes, top discharge electrodes, rigid discharge elec-
electrodes, top trodes, bottom
wires, top rapped rapped top rapped trodes, top rapped
rapped rapped
ESP Inlet
297 319 315 315 358 295
Temp., F
Gas Velocity,
6.1 4.3 NA 6.6 5.3 NA
ft/sec
Aspect Ratio 0.83 0.6 NA 0.8 1.72 0.9
Treatment Time,
4.9 5.5 NA 3.6 14 NA
seconds
Average Corona
Current Density, 54 15.8 32 52 17.5 33
mA/1000 ft2
Stack Filterable
Emissions, 0.019 0.015 0.003 0.028 0.014 0.015
lb/MBtu
Filterable Method 5 w/certified Method 5 w/certified
Emissions Test 5 PM CEMS PM CEMS 5 5 5
Method (after wet FGD) (after wet FGD )

cific corona power densities of 350 to 400 watts/1000 At Plant 3, the dry ESP was operating at a specific
acfm, all of the dry ESPs were able to operate below the corona power level of 320 watts/1000 acfm. The stack
MATS filterable emissions standard of 0.03 lb/MBtu. filterable emissions after the wet FGD showed values
Among the unscrubbed units, Plant 4 shows significant of 0.003 lb/MBtu from PM CEMS data (utilizing a
additional filterable reductions of 0.015 lb/MBtu when certified method based on EPA Method 5B). Based on
the ESP was operating with an alternative, non-SO3 the Kumar-Feldman prediction, a standalone dry ESP
flyash conditioning system. would perform at levels much higher than 0.03 lb/MBtu.
Plant 4 was able to retain the same low emission levels
with non-SO3 ash conditioning system even when acti-
vated carbon injection and sodium bicarbonate injection Interpretation of the observations on stack
filterable emissions
testing were conducted at this plant, and without loss
of the high ESP specific corona power. 1. Based on the Kumar-Feldman predictions of stand-
Stack filterable emissions of Plant 2 at the wet FGD alone dry ESP performance, stack filterable emissions
outlet following a small, two-field dry ESP operating data after wet FGD systems on Plants 2 and 3 cannot
at specific corona power in the 150 watts/1000 acfm be explained without significant additional collection
range consistently showed filterable emissions below occurring across the wet FGD. Though this co-benefit
0.02 lb/MBtu. For an ESP-only configuration, the phenomenon is not altogether surprising given the
Kumar-Feldman curve predicts filterable emissions cited literature, currently there is a dearth of publicly
in excess of 0.05 lb/MBtu for the operating specific
corona power level.

Fig. 5 Filterable emissions versus ESP specific corona


power. Fig. 6 Stack filterable emissions in 2011 on Plant 2.

Babcock & Wilcox Power Generation Group 7


available literature validating the particulate collection Summary
mechanisms that are possible across a relatively low
Test data on stack filterable emissions have shown that
pressure drop device such as an open tower wet FGD.
well operating ESPs can handle both Eastern high sulfur
2. The trend line of ESP performance on unscrubbed units
coals and PRB coals. Proper flyash conditioning seems es-
in Figure 5 indicates a consistent under-prediction by
sential for achieving this result. Additional testing will be
a value between 0.010 to 0.015 lb/MBtu as compared
necessary to determine if fireside modifications to reduce
to the Kumar-Feldman line. While this represents no
NOx could also result in reductions of fine particulate matter
more than a 15% difference for older units operating
in fly ash. Most promisingly, the stack filterable emission
at filterable emissions of 0.10 lb/MBtu, it could have
testing on stations where ESPs are followed by wet FGDs
much greater significance for plants operating near the
indicate that considerable additional particulate collection
0.03 lb/MBtu level.
can be realized. Additional research seems necessary to
3. Since most of the plants under consideration utilize
determine the mechanisms controlling this important par-
some form of fireside modification technique to reduce
ticulate control co-benefit. We urge a proper consideration of
flame temperature, would these plants also be reducing
the potentially damaging issues of particulate bias on probe
the fine particulate concentrations in flyash during the
filters resulting from condensed sulfuric acid. Proper confor-
practice of NOx reduction techniques?
mances to appropriate test methods and/or implementation
4. It seems important to consider any possible clues from
that overcome the effects of SO3 are recommended. In this
data from Plant 4 indicating a factor of two difference
regard, all SO3 mitigation techniques will tend to avoid the
in filterable emission results between ESP operation
bias that acid mist aerosols can introduce into test results.
with SO3 and non-SO3 conditioning agents.
5. To further explain the optimistic ESP performance
based on stack testing and evaluation at the six power
plants, what does the literature search teach us? Could
the positive bias from condensed SO3 be a factor in the
over-prediction by the Kumar-Feldman curve? Could
the past curves of over-prediction be directly a result of
sub-optimum control of ash re-entrainment from ESPs?
6. Could the emphasis on the ESP specific corona power
approach in this paper lead us towards further research
and innovation in the quality of applied power to ESPs
to improve filterable emissions? Opportunities for novel
application exist through techniques of pulsed energiza-
tion, high frequency power supplies, and three-phase
power supplies.

8 Babcock & Wilcox Power Generation Group


References 9. McElroy, M.W., Carr, R.C., Markowski, G.R., Size
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