568 Chapter Twelve Chemical Kinetics

was studied at 10C. The following results were obtained where c. Calculate the rate constant when concentrations are given in
moles per liter.
3 Cl2 4
Rate 28. The following data were obtained for the gas-phase decomposi-
t
tion of dinitrogen pentoxide,
2N2O5 1g2 4NO2 1g2
Initial Rate O2 1g2
[NO]0 (mol/L) [Cl2]0 (mol/L) (mol/L min)
0.10 0.10 0.18
[N2O5]0 Initial Rate
0.10 0.20 0.36 (mol/L) (mol/L s)
0.20 0.20 1.45
4
0.0750 8.90 10
3
0.190 2.26 10
3
a. What is the rate law? 0.275 3.26 10
3
b. What is the value of the rate constant? 0.410 4.85 10
26. The reaction
Dening the rate as [ N2O5 ] t, write the rate law and
2I 1aq2 S2O82 1aq2 I2 1aq2 2SO42 calculate the value of the rate constant.
1aq2
29. The rate of the reaction between hemoglobin (Hb) and carbon
was studied at 25C. The following results were obtained where
monoxide (CO) was studied at 20C. The following data were
3 S2O82 4
Rate collected with all concentration units in mol/L. (A hemoglobin
t
concentration of 2.21 mmol/L is equal to 2.21 10 6 mol/L.)
[I ]o [S2O82 ]o Initial Rate
(mol/L) (mol/L) (mol/L s) [Hb]0 [CO]0 Initial Rate
( mol/L) ( mol/L) ( mol/L s)
6
0.080 0.040 12.5 10
0.040 0.040 6.25 10 6 2.211.00 0.619
0.080 0.020 6.25 10 6 4.421.00 1.24
0.032 0.040 5.00 10 6 4.423.00 3.71
6
0.060 0.030 7.00 10
a. Determine the orders of this reaction with respect to Hb and
a. Determine the rate law. CO.
b. Calculate a value for the rate constant for each experiment and b. Determine the rate law.
an average value for the rate constant. c. Calculate the value of the rate constant.
d. What would be the initial rate for an experiment with
27. The decomposition of nitrosyl chloride was studied: [ Hb] 0 3.36 mmol/L and [ CO] 0 2.40 mmol/L?
2NOCl1g2 30. The following data were obtained for the reaction
2NO1g2 Cl2 1g2
2ClO2 1aq2 2OH 1aq2 ClO3 1aq2 ClO2 1aq2 H2O1l2
The following data were obtained where
3 ClO2 4
3 NOCl 4 where Rate
t
Rate
t

[NOCl]0 Initial Rate [ClO2]0 [OH ]0 Initial Rate

(molecules/cm3) (molecules/cm3 s) (mol/L) (mol/L) (mol/L s)
2
3.0 1016 5.98 104 0.0500 0.100 5.75 10
1
2.0 1016 2.66 104 0.100 0.100 2.30 10
1
1.0 1016 6.64 103 0.100 0.0500 1.15 10
4.0 1016 1.06 105

a. Determine the rate law and the value of the rate constant.
a. What is the rate law? b. What would be the initial rate for an experiment with [ClO2] 0
b. Calculate the rate constant. 0.175 mol/L and [OH ] 0 0.0844 mol/L?