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REDOX
Oxidation and reduction in terms of oxygen transfer
Definitions
Oxidation is gain of oxygen.
Reduction is loss of oxygen.
CH3CH2OH CH3CHO
Oxidation by loses of hydrogen
Another definition
Oxidation and reduction in terms of electron
transfer
This is easily the most important use of the
terms oxidation and reduction at A' level.
Definitions
Oxidation is loss of electrons.
Reduction is gain of electrons.
OIL RIG oxidation is loss, reduction is gain
CuO + Mg Cu + MgO
Cu2+ + Mg Cu + Mg2+
OXIDATION STATES (OXIDATION
NUMBERS)
soluble insoluble
Natural methods of precipitation include settling or
sedimentation, where a solid forms over a period of time due to
ambient forces like gravity or centrifugation
CHEMICAL PRECIPITATION
(Applications)
Removal of metals from waste stream
e.g. plating and polishing operations, mining, steel
manufacturing, electronics manufacturing
include arsenic, barium, chromium, cadmium, lead,
mercury, silver
Treatment of hard water removal of
Mg2+ and Ca2+
Phosphorus removal
Removing salts from water in water
treatment
CHEMICAL PRECIPITATION
(Theoretical Background)
Solubility equilibria
A chemical reaction is said to have reached
equilibrium when the rate of forward reaction is
equal to the rate of the reverse reaction
ABs A+ + B-
Eg.
A + + B- Solubility
Compound (mg/L) Ksp
CaCO3 18 5 x 10-9
=1
Ksp = equilibrium solubility product constant
26 TL-
61
CHEMICAL PRECIPITATION
(Basic Principles)
A. Add chemical
precipitants to
waste stream
B. Mix thoroughly
C. Allow solid
precipitates to
form floc by
slow mixing
D. Allow floc to
settle in clarifier
CHEMICAL PRECIPITATION
(Types of Precipitation)
Phosphorus removal
Phosphate precipitation (PO42-)
CHEMICAL PRECIPITATION
Reaction rate
Change in concentration
Change in time
Chemistry Notation
Time A B
(min) mol/L mol/L
0.0 1.000 0.000
3.0 0.400 0.600
6.0 0.250 0.750
We could measure the rate of the reaction either by measuring how
the concentration of reactant A changes or how the concentration of
product B changes. Let's measure A's average rate of change first:
Compare this rate to the rate of just the first three minutes of the
reaction:
Calcium Hydroxide,
Ca(OH)2
Hydrated Lime
Sodium Hydroxide
Caustic Soda, Soda Lye
Available in Liquid or Dry Form
Liquid:
Commercial Strength
50 % , 73 % NaOH
Often Stored at 20 %
50 % Crystallizes at 53 Deg. F
Dry:
99.9 % NaOH
Safety Bag, Drum, or Bulk
Caustic Poison
Dangerous to Handle, Corrosive
Prevent All Body Contact
Protect Eyes
Calcium Hydroxide
Ca(OH)2
Hydrated Lime, Slaked Lime
Available in Dry or Liquid Form
VS
Hydrated Lime
Less Expensive
Solids Settle Faster
Higher Sludge Solids Conc
Sludge Easier to Dewater
Takes Longer to Neutralize
More Complicated Feed System
A Lot More Sludge
CARBONATE PRECIPITATION
PHOSPORUS REMOVAL
pH : 5.5-7.0 requires
water alkalinity
Chemical
Process Water Treatment
..
Back To
Filter Press
Equalization Tank
Sludge Tank
Sludge Bin