Professional Documents
Culture Documents
Product identifier
Relevant identified uses of the substance or mixture and uses advised against
Manufacturer/Supplier
Thermo Fisher Scientific Baltics UAB
V.Graiciuno 8
LT-02241 Vilnius
Lithuania
Tel.: +370 5 2602131
Fax.: +370 5 2602142
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www.thermofisher.com
SECTION 2: Hazards identification
Physical hazards
Not classified
Health hazards
Acute oral toxicity Category 3
Acute dermal toxicity Category 3
Acute inhalation toxicity Category 3
Skin corrosion/irritation Category 1B
Serious eye damage/eye irritation Category 1
Specific target organ toxicity - Single exposure Category 3
Specific target organ toxicity - Repeated exposure Category 2
Environmental Hazards
Chronic aquatic toxicity Category 3
Label elements
Hazard pictograms
Signal word
Danger
Hazard Statements
H301 + H311 + H331 - Toxic if swallowed, in contact with skin or if inhaled
H314 - Causes severe skin burns and eye damage
H335 - May cause respiratory irritation
H341 - Suspected of causing genetic defects
H373 - May cause damage to organs through prolonged or repeated exposure
H412 - Harmful to aquatic life with long lasting effects
Precautionary Statements
Prevention
P261 - Avoid breathing dust/fume/gas/mist/vapours/spray
P264 - Wash hands thoroughly after handling
P280 - Wear protective gloves/protective clothing/eye protection/face protection
P201 - Obtain special instructions before use
P260 - Do not breathe dust/fume/gas/mist/vapours/spray
Response
P303 + P361 + P353 - IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with
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water/shower
P301 + P310 - IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician
P302 + P352 - IF ON SKIN: Wash with plenty of soap and water
P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing
P304 + P340 - IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
Storage
P403 + P233 - Store in a well-ventilated place. Keep container tightly closed
Disposal
P501 - Dispose of contents/ container to an approved waste disposal plant
Skin contact Rinse with plenty of water. Immediate medical attention is not required.
Eye contact Rinse cautiously with water for several minutes. Remove contact lenses, if present
and easy to do.
INGESTION Not expected to present a significant ingestion hazard under anticipated conditions
of normal use. If you feel unwell, seek medical advice.
Inhalation Not expected to be an inhalation hazard under anticipated conditions of normal
use of this material. Consult a physician if necessary.
Notes to Physician Treat symptomatically.
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SECTION 5: Firefighting measures
Extinguishing media
Suitable Extinguishing Media Water spray. Carbon dioxide (CO2). Foam. Dry chemical.
Unsuitable Extinguishing Media No information available.
Environmental precautions
No special environmental precautions required. Avoid discharge into drains and waterways whenever possible.
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SECTION 8: Exposure controls/personal protection
Control parameters
Chemical Name Austria Belgium (TWA) Denmark (TWA) Finland OEL (TWA)
Phenol 2 ppm 2 ppm 1 ppm 20 mg/m
108-95-2 8 mg/m3 8 mg/m3 4 mg/m3 5 ppm
Ammonium thiocyanate None None None None
1762-95-4
Thiocyanic acid, compound None None None None
with guanidine (1:1)
593-84-0
Chemical Name France OEL (VME) Germany OEL (TWA) Ireland (TWA) Italy OEL (TWA)
Phenol 2 ppm 2 ppm exposure factor 2 2 ppm 2 ppm
108-95-2 7.8 mg/m3 8 mg/m3 exposure factor 2 8 mg/m3 8.0 mg/m3
Ammonium thiocyanate 5 mg/m3 None None None
1762-95-4
Thiocyanic acid, compound None None None None
with guanidine (1:1)
593-84-0
Chemical Name Sweden - Occupational Netherlands OEL (MAC) Spain OEL (TWA) United Kingdom
Exposure Limits - TLVs
(LLVs)
Phenol 1 ppm LLV; 4 mg/m3 LLV 8 mg/m3 2 ppm 2 ppm TWA; 7.8 mg/m3 TWA
108-95-2 8 mg/m3
Ammonium thiocyanate 2 mg/m3 LLV (total inhalable 1 mg/m3 None 5 mg/m3 TWA (except HCN;
1762-95-4 dust, as CN) Cyanogen; Cyanogen
chloride, as CN)
Thiocyanic acid, compound None None None None
with guanidine (1:1)
593-84-0
Chemical Name European Union France OEL (VME) Germany OEL (TWA)
Phenol None 2 ppm 2 ppm exposure factor 2
108-95-2 7.8 mg/m3 8 mg/m3 exposure factor 2
Ammonium thiocyanate None 5 mg/m3 None
1762-95-4
Thiocyanic acid, compound with guanidine (1:1) None None None
593-84-0
Chemical Name Italy OEL (TWA) Portugal Netherlands OEL (MAC) Finland OEL (TWA)
Phenol 2 ppm None 8 mg/m3 20 mg/m
108-95-2 8.0 mg/m3 5 ppm
Ammonium thiocyanate None None 1 mg/m3 None
1762-95-4
Thiocyanic acid, compound None None None None
with guanidine (1:1)
593-84-0
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Thiocyanic acid, compound None None None None
with guanidine (1:1)
593-84-0
Chemical Name Ireland Norway Lithuania OEL (TWA) Spain OEL (TWA)
Phenol None None 2 ppm 2 ppm
108-95-2 8 mg/m3 8 mg/m3
Ammonium thiocyanate None None None None
1762-95-4
Thiocyanic acid, compound None None None None
with guanidine (1:1)
593-84-0
Exposure controls
Respiratory protection In case of insufficient ventilation wear respirators and components tested and
approved under appropriate government standards.
Hand Protection Wear suitable gloves. Glove material: Compatible chemical-resistant gloves.
Hygiene measures Handle in accordance with good industrial hygiene and safety practice.
Appearance Liquid
Odour medicinal, sweet, Tar like
Melting point / melting range C Mixture has not been tested F Mixture has not been tested
Boiling point / boiling range C Mixture has not been tested F Mixture has not been tested
Flash point C Mixture has not been tested F Mixture has not been tested
Autoignition temperature C Mixture has not been tested F Mixture has not been tested
Decomposition temperature C Mixture has not been tested F Mixture has not been tested
Evaporation rate No data available
Flammability (solid, gas) No data available
Upper explosion limit Mixture has not been tested
Lower explosion limit Mixture has not been tested
Vapour Pressure Mixture has not been tested
Relative density Mixture has not been tested
Specific gravity No data available
Solubility No data available
Partition coefficient: No data available
n-octanol/water
Explosive properties Mixture has not been tested
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SECTION 10: Stability and reactivity
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SECTION 12: Ecological information
Toxicity
The environmental impact of this product has not been fully investigated.
Chemical Name Freshwater Algae Water Flea Data Freshwater Fish Microtox Data log Pow
Data Species Data
Phenol Desmodesmus Daphnia magna EC50 No data available No data available logPow1.5
subspicatus EC50 187 4.24 - 10.7 mg/L (48
- 279 mg/L (72 h) h) Daphnia magna
Pseudokirchneriella EC50 10.2 - 15.5 mg/L
subcapitata EC50 (48 h)
46.42 mg/L (96 h)
Ammonium thiocyanate No data available No data available No data available No data available No data available
Thiocyanic acid, compound No data available No data available No data available No data available No data available
with guanidine (1:1)
UN Number UN1760
UN proper shipping name Corrosive liquid, n.o.s. (phenol - guanidine thiocyanate solution)
Packing group II
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not Applicable.
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SECTION 15: Regulatory information
Safety, health and environmental regulations/legislation specific for the substance or mixture
Substances under Regulation (EC) No 850/2004 of the European Parliament and of the Council of 29 April
2004 on persistent organic pollutants and amending Directive 79/117/EEC
None.
Chemical Name Weight percent Germany - Water Germany - Water Germany - Water
Classification (VwVwS) - Classification (VwVwS) - Classification (VwVwS) -
Annex 1 Annex 2 - Water Hazard Annex 3
Classes
Phenol 30-60 hazard class 2 - hazard to
waters
Ammonium thiocyanate 7-13 hazard class 1 - low hazard
to waters
Thiocyanic acid, compound 15-40 hazard class 2 - hazard to
with guanidine (1:1) waters
Chemical Name EINECS (European ELINCS (European ENCS (Japan) PICCS (Philippines)
Union) List of Notified
Chemical
Substances)
Phenol Listed - Listed Listed
Ammonium thiocyanate Listed - Listed Listed
Thiocyanic acid, compound with guanidine (1:1) Listed - Listed Listed
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SECTION 16: Other information
References
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/echa.europa.eu/
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toxnet.nl
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LOLIdatabase:ht tps:
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-dat
abase
Classification and procedure used to derive the classification for mixtures according to Regulation (EC)
1272/2008 [CLP]:
"The above information was acquired by diligent search and/or investigation and the recommendations are based on
prudent application of professional judgment. The information shall not be taken as being all inclusive and is to be
used only as a guide. All materials and mixtures may present unknown hazards and should be used with caution.
Since the Company cannot control the actual methods, volumes, or conditions of use, the Company shall not be held
liable for any damages or losses resulting from the handling or from contact with the product as described herein.
THE INFORMATION IN THIS SDS DOES NOT CONSTITUTE A WARRANTY, EXPRESSED OR
IMPLIED,INCLUDING ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR ANY PARTICULAR
PURPOSE"
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