Chemistry

1. (a)Whatvolumeof0.100MAgNO3shouldbeaddedto10.0mlof0.090MK2Cr2O4to
precipitateallthechromateasAg2Cr2O4?
(b)Whatistobedoneinordertoprepare0.40MNaClstartingwith100mlof0.030M
NaCl?(mol.Wt.ofNaCl=58.5)
( c ) For complete oxidation 60 ml of a ferrous sulphate solution with KMnO4 in acid
mediumtheamountof0.01MK2Cr2O7requiredforthesameoxidation.
( d ) An aqueous solution is 0.01 M CH3OH. The concentration of the solution is very
nearlyequalto

2. (a)6.02x1023oxygenmoleculesarepresentat130Cina1500mlvessel.Whatwould
bethepressureofthegas?(Avogadrosnumber=6.02x1038,R=0.082litatommol1K1)
(b)WhatisthenumberofmolesofFe(OH)3thatcanbeproducedbyallowing2.0mol.
Fe2S34.0molH2Oand6.0mol.O2toreact?
Fe2S3+H2O+O2Fe(OH)3+S(nobalanced)
(i)Writethegroundstateelectronicconfigurationof
Fe2+ion(at.No.ofFe=26)

3. (a)Writethesetsofquantumnumbersfora4delectron
(b)Writecorrect5electronorbitaldiagram
( c ) After the emission of an particle from the atom 92U238 what is the number of
neutronsleftintheatom?
( d ) After an hour the amount of a certain radioactive substance disintegrated was
15/16thoftheoriginalamount.Whatisthehalflifeofradioactivesubstance?
(e)OutofPF,FF,SFandClFbonds,whichbondistheleastionic?

4. (a)outofSiO2(s),Si(s),NaCl(s)andBr2(L)whichisthebestelectricalconductor.
(b)Whichofthefollowingreactiondonotinvolveoxidationreduction?
(i)2Rb+2H2O2RbOH+H2
(ii)NH4Cl+NaOHNaCl+NH3+H2O
(iii)2CuI2CuI+I2
(iv)4KCN+Fe(CN)2K4[Fe(CN)6]
(c)Balancethefollowingequation
CH3CHO+K2Cr2O3+H2SO4CH3COOH+Cr2(SO4)3+K2SO4+H2O
(d)WhichofthefollowingarenotLewisbases?
(i)Ag+(ii)H2O(iii)CN(iv)CH4
(e)Whichanionistheweakestbase?
(i)C2H5O(ii)NO3(iii)FI(iv)CH2COO

5. (a)A 100 W, 200 V incandescent lamp isconnectedin series with an electrolyticcell
containing copper sulphate solution. What weight of copper will be deposited by the
currentflowingfor5hours?(at.Wt.ofCu=63.54)
(b )Inareversiblereactiontwosubstancesare inequilibrium.Iftheconcentrationof
eachoneisdoubledtheequilibriumconstantwillbe.

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 Chemistry

(c)When[N2O]=0.22M,therateofdecompositionofN2O5is1.3x104mollit1s1.What
isthevalueofKforthefirstorderreaction?

6. (a)Whichofthefollowingstatementsiscorrectregardingtheslagobtainedduringthe
extractionofametallikecopperoriron
(i)theslaglighterandlowermeltingthanthemetal
(ii)theslagisheavierandlowermeltingthanthemetal
(iii)thehighermeltingthanthemetal
(iv)theslagisheavierandhighermeltingthanthemetal
(b)OutofF,Cl,BrandIwhichhasthehighestelectronaffinity?
(c)Inwhichofthefollowingcompoundsdoestheratioofanionsizetocationsizehave
lowestvalue?
(i)NaCl(ii)KCl(iii)MgCl2(iv)NaBr
(d)Towhichblock(s,p,dorf)doestheelementwithatomicnumber50belong?
(e)OutofAl,Zn,MgandFewhichisthedensestelement?

7. (a)Whichofthefollowinghasthemaximumnumberofunpairedelectrons?
(i)Zn(ii)Fe+(iii)Ni+3(iv)Cu+
(b)Givecompleteequationsforthefollowingequationsneednotbebalanced:
(i)Concentratedhydrochloricacidisreactedwithpotassiumpermanganate.
(ii)Phosphorusisreactedwithaqueoussodiumhydroxideproducingphosphine.
(iii)Iodineisproducedfromsodiumiodideusingsodiumbisulphate.
( iv ) Aluminium powder reacts with sodium nitrate in presence of excess of sodium
hydroxide.
8. (a)Arrangethefollowingasstated:
(i)F3,N2,O2,Cl2inorderoftheirincreasingbondstrength.
(ii)ZnO,MgO,P4O5,SO3inorderofincreasingacidicproperty.
(iii)Gasoline,keroseneanddieselinorderofincreasingvolatility.
(b)WritedowntheIUPACnameofthecompound
H2C=CHCH(CH3)2
(c)AcompoundisformedbysubstitutionoftwochlorineatomsfortwoHatomsin
propane.Whatisthenumberofstructuralisomerspossible?

9. (a)WhichofthefollowingcannotreduceFehlingssolution?
(i)Formicacid(ii)aceticacid(iii)formaldehyde(iv)acetaldehyde

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 Chemistry

(b)Writedownthestructureofthemainproductofeachofthefollowing:
(i)CH3CH2COCl/AlNO3
Benzene

(ii)
BleachingPowder
CH3COCH3


(iii)aq.NaNC2dilHCl
CH3CH2NH2

(iv)P2O5Heat

CH3COOH

10. (a)Whichofthefollowingisnotamixtureofhydrocarbons?
(i)candlewax(ii)kerosene(iii)vegetableoil(iv)paraffinoil.
(b)Statewhetherfollowingstatementsaretrueorfalse:
(i)Phenolisaweakeracidthancarbonicacid.
(ii)Anilineisastrongerbasethanammonia.
(iii)Formicacidisaweakeracidthanaceticacid.
(iv)Bothformaldehydeandacetaldehydegivethehaloformtest.
(v)ThereagentAg(NH3)2+candistinguishbetweenethyleneandacetylene.
(vi)Acetyleneismoreacidicthanthylene.
(vii)Acetaldehydecanbepreparedbydistillationofcalciumacetate.
(vii)Diethyletherdoesnotreactwithsodium.

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