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MATERIAL SAFETY DATA SHEET (Revision: 06/01/2011)

1. Identification of the Substance/Preparation and of the Company/Undertaking.


Product Type: Paint-On Die Hardener
Trade Name: P.D.Q. Die Hardener

Company: Whip Mix Corporation


361 Farmington Ave.
Louisville, Kentucky, USA 40209
Emergency Telephone Number: (502)-637-1451
Fax Number: (502) 634-4512
Transportation CHEMTREC 1(800) 424-9300 (U.S. and Canada)
Emergencies: International Calls: 1- 703-527-3887 (Collect calls accepted)
2. Hazard Identification.
Flammable liquid: UN1193.Class 3. Use in well ventilated area. Solvent vapors can travel to an ignition source,
such as a Bunsen burner and flash back.
Vapor may cause irritation to eyes and respiratory tract.
Liquid may cause irritation to skin and eyes.
3. Composition/Information on Ingredients.
Substance CAS EINECS Concentration, % R Symbols S
Methyl Ethyl Ketone 78-93-3 201-159-0 >50% +F: R11, Xi, S2, S9, S16
R36, R66,
R67
4. First-Aid Measures.
Skin contact: Wash with soap and water.
Inhalation: Move to fresh air.
Eye contact: Flush eyes(s) with water. Contact a physician if irritation occurs.
Ingestion: Do not induce vomiting. Get medical attention immediately.

5. Fire-Fighting Measures.
Use water fog, Alcohol foaming, CO2, or dry chemical.
For small bottle, smother with a water wet blanket or towel. Keep area isolated.
Hazardous decomposition product: Carbon Monoxide

6. Accidental Release Measures.


For small quantities, clean-up with paper towel and dispose of properly.

7. Handling and Storage.


Keep away from heat, spark or open flame.
Keep container closed.

8. Exposure Controls/Personal Protection.


None required under normal use in a well ventilated area.
Exposure Limits OSHA-PEL ACGIH-TLV, 2011
Methyl Ethyl Ketone 200 ppm 200 ppm
Use NIOSH approved respirator to avoid exposure above the recommended limits.

9. Physical and Chemical Properties.


Clear, light yellow liquid with low viscosity.
Vapor pressure (mm Hg): 80mm
Vapor density (air-1): >1
Evaporation rate: >1
Boiling point (C): 78.6C
Specific gravity (water=1): 0.95 - 1.0
Flash point (Tag closed cup): 6.1C
Upper flammability limit (% by volume): 11.5%

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Lower flammability limit (% by volume): 1.8%

10. Stability and Reactivity.


Flammable when exposed to heat, spark or open flame.

11. Toxicological Information.


Route of entry: skin contact, eye contact, inhalation or ingestion.
Effects of acute over exposure:
Inhalation: Vapors can cause headache, nausea, dizziness, and irritation of nose, throat and lungs.
Skin contact: Prolonged or repeated contact can cause skin irritation. Chronic exposure may cause defatting
type dermatitis.
Eye contact: Direct eye contact can cause eye irritation and temporary damage. May cause conjunctivitis.
Carcinogenicity: Not listed as carcinogen by OSHA, NTP or IARC

12. Ecological Data.


Small quantities do not pose an ecological concern. RCRA Reportable quantity is 100 lbs.

13. Disposal Considerations.


Small quantities of material can be allowed to evaporate in well ventilated area.
Small quantities of dry material may be disposed in local landfill. Check local regulations.

14. Transport Information.


DOT hazard class: Flammable liquid ORM-D consumer commodity.

15. Regulatory Information.


This product is considered hazardous under OSHA Hazardous Communications Standard (29CFR 1910.1200)
This product is a controlled product under Canadian (WHMIS)
SARA Title 3: Section 313 & CERCLA (methyl methacrylate (80-62-6) component) regulated. (40CFR37) above
deminimus concentrations: Methyl Ethyl Ketone.

16. Other Information.


HMIS Rating: Health=1 Flammability=3 Reactivity=0
Hazard: 4-Severe; 3-Serious; 2-Moderate; 1-Slight; 0-Minimum

Prepared By: Donna Ringo, CIH Translated By:

Date: 6/13/2011 Date:

CPL90536 i :\msds\pdqdie.har(rev. 06/01/2011)

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