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    May/June 2002 A-level Chemistry Paper 4 Mark Scheme

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    May/June 2002 A-level Chemistry Paper 4 Mark Scheme

    Copyright:

    © All Rights Reserved
    Download as PDF or read online from Scribd
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    11 views7 pages

    9701 s02 Ms 4

    Uploaded by

    Kraktoa
    May/June 2002 A-level Chemistry Paper 4 Mark Scheme

    Copyright:

    © All Rights Reserved
    Download as PDF or read online from Scribd
    Flag for inappropriate content
    of 7
    CAMBRIDGE INTERNATIONAL EXAMINATIONS JUNE 2002 GCE Advanced Level MARK SCHEME MAXIMUM MARK : 60 SYLLABUS/COMPONENT :9701 /4 CHEMISTRY (STRUCTURED QUESTIONS (A2 CORE)) University of Camsripce Leal Exarainations Syndieate (Faget Wark Scheie Syllabus _[ Paper t A Level Examinations ~ June 3002 ‘870% 4 1 @ Keoo= [HYIOH] (or FO" YOR) nM 1 (>) fH] = KefOR] = 11002 ( 5x10" mol dm?) ft] pR = 133 thy 2 (© NHsisa weak base or incompletely ionised [or NaOH is strong base] [1] [or an equation showing the equilibrium over to the NH + HO side} 1 ) “+ t end point “ t Send point” at 40:4 em? [1] 3 ' [ie vertical fine, or dotted line] pH shape of curve ty ic. flatish-steep down-flatish) ? start at 11,3 cm Mm {can be read off position on axis] ° 40 cm? volume added 3 (e) methy! orange i i @ NE, + HU > NH" {U [or Nels + HCI or H2SO, etc) NHS + OF ——> NER + Ht m [or NHACi + NaOH etc} At least one of the above equations should be shown, Allow a verbal eqrivatent for the other exuato. Correct verbal eqnevatens for bk eqrccons ae stl worth [1] mark ont. olay incorrect equation negaws the mark for a correct ane, but ignore “mental” equations like NECl ———> NH,” © CP} 2 total: £0 Pagez Mark Scheme Syllabus | Paper ‘A Level Examinations - June 2002 9704 4 (@ mix (a solution of) 4-nitrophenyl ethancate with (a solution of) NaOH [do NOT allow titration with NaOH] a either [esier] or volume of ester solution is known/fixed/stated ul place in colorimeter (fitted with a suitable filter) (or spectrophotometer) rit) time the reaction / the appearance of yeilow colour / the formation of product [1] measure the increase in absorbance over time or take time for a fixed absorbance/colour to occur Tr {allow take out samples at known times and titrate with standard acid for she last two marks] @) Smaxd (® from graph (see next page) [NB. the graph on the question paper has noe been reproduced corectiy'= the shapes of the curves are steeper at the stant than the original. Allowance has been made for this in the rate ranges quoted belo%s} rate(A) = 0,003/18 ~0,001/26 = 3.8-5.5x 10% mol dm? min™ for 6.3-9.0 x 107 mol dm” sec] fl] rate (B) = 0.001/7-0,001/12 = 8,314.3 x 10% mol dm” min™ [or 1,38 - 2.4 x 107 mol dar* seo] (y correct units for either rate wo [1] (i) order with respect to [OH] = 1 we {1] Gi) order with respect to [ester] = i we {1] fiv) constant (successive) half lives (look for evidence of construction lines on graph) iu) (4) rate = k{OE][ester] [allow e.c.£ - expression must fit in with answers for (ii) and Gi} ul (i) k = rate({OHJ[ester]) = dx 10°40.2x 1x 10%) = 0220.05 mol! dm’ mint [1] + [LJonis {or 0.0033 = mof' dm’ sec” [1] +[1]} Jatlow eof from part (i) for value of the rate constem and part (3) for rate equation. Units mark ix ue] 9 total: 13 Wark Scheme Syllabus [Paper ‘A Level Examinations ~ June 2002 ‘S704 4 2 Graph for pact (by (@ — CaqNOs; ——> Cad * INO: ~ 4 Jer doubted) m (©) stabitities crease down the group [or comparison of two Gp I nitrates] [1] because as the ions (NOT atomsjget bigger/have mare shells/have smaller charge density ure [1] there is tess polarisation of the nitrate ion/NOx/anion, we {l} 3 () (i) MNO; ——> MNO; + 40; {or doubled, or specific Gp Lnitrate] 1m Gi} Wog loses 085g of oxygen. this is 10.85/16 = 0.678 moles o£ or 10,339 moles of O: per 100g Ww +. 0.678 mol of MNO; has a mass of 100g 1.0. mol of MNO; has a mass of 100/0.678 = 147.5 ¢ since NO; = 62, M= 1475-62 = 853 [85 -85.5] mH 3 total: 7 Page 4 Mark Scheme ‘Syllabus | Paper I B Level Examinations - June 2002 S701 4 4 (a) [is?2s?2p*3s?3p*] 3a® ty t &) GE vaines: CCT 1.36(V) BryBE LORY) LT O54C¥) [tT [E* values could be read from the answers in (c}] (Therefore) the hatogens are less oxidising from Cl to I we [1] (i) BP values: CPCI OAV Fe? fFe® 0.77V Co™Co™ 1.82V_ [1] (E” values could be read from the answers in (¢), Allow -0.74 for CP” and -0.04 for Fe] (Therefore) the 3+ ions become more oxidising from Cr to Co we {1] 4max3 ) @ no reaction am ii) 2Co™ + 2Br ———+ 2Co™ + Bry ( Eo = 182-107 = 0.75V Oy Giiy 2Cr + lp —— 20 + ar a * = 0.54- (0.41) = 0.95V i Smax+ total: 8 5 (a) _—_ amide [NOT peptide] TV) phenol [NOT hydroxy or alcohol] uy fignore. ie, do net allow. benzene ring] i ® @ CH,CONH: OH (or isomers, > 2 bromines) a] Br (i) CHyCONH. © y ler Ne-sale~ suase clude charges}U} (i) (CH;COy) + nano for Na soit ~ must inetd charges}{1} 3 (©) @ —-X=CHsCOCI oF (CH;CO);0 [or names, NOT ester} al Gi) PCls or PC or SOCh Jor names] fy [if the anhydride is used. allow P:0s, AlPOs, CH;=C-O. PCI, then + CHCONa ‘or any other valid method of obtaining aniscrides jFam acids} Bf.X > ester then allow ecf for CHOH + cone HSO,] total: 7 Pages Wark Scheme Syllabus Faper ‘A Level Examinations ~ June 2002 9701 8 ia) (b) @ AVAICLFelFeCiy Flag), water oF tight negates this mark) — TY} Gi) light/hfuv er heat Mog} or water negates is mark} 103) 2 (i) A does not react, because the Ci-ring bond is strong/short or Clis mare closely bonded or Cl electrons delucalised into the ring [1] (ii) oat CH,OH oO + OF —-> + CY {no ect) {1} for NaOH) (or NaC 2 total: + reagents for I: conc, HNQs + HsSO, Faq) negates} 0) ject. allow a correct reagent corresponding to the sriciure of'Y eg. fF = chlorobenzene, allow Ciz + Fe etc] reagents for I: tin or iron/Fe [NOT Za] + (conc. HCL or LiAIH, [NOT NaBH) or H2+NifNOTPt] [1] [eaf: allow a correct reagent correspending tothe structure of e.g if ~ chiorobensene, allow NoNHs ‘NOT Nit} conditions fork 3S°C C\H,NH4' [+ CIOKY 0] product must show ionte 7] less basic than NE, rio Jone pair (on N) is delocalised over the ring it [this mark may be obtained jrom a chagram ~ e.g. double dot on + curly arrow) HINO: oF nitrous (nitric(HD) acid or NaNO2 + HCI ray OC

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