Datos de equilibrio L-V para la Actividad

en Clase 15.1

P [kPa] x1 y1 x2 y2 gama1 exp gama2 exp

68.728 0 0 1 1 0 1
72.278 0.0287 0.0647 0.9713 0.9353 1.681790779 1.012674715
75.279 0.057 0.1295 0.943 0.8705 1.765274349 1.011107235
77.524 0.0858 0.1848 0.9142 0.8152 1.723432618 1.005831936
78.951 0.1046 0.219 0.8954 0.781 1.706135509 1.001977278
82.528 0.1452 0.2694 0.8548 0.7306 1.580431772 1.026319945
86.762 0.2173 0.3633 0.7827 0.6367 1.497196084 1.02691705
90.088 0.2787 0.4184 0.7213 0.5816 1.395934719 1.056919
93.206 0.3579 0.4779 0.6421 0.5221 1.284584445 1.102709682
95.017 0.405 0.5135 0.595 0.4865 1.24345535 1.130403483
96.365 0.448 0.5512 0.552 0.4488 1.223753585 1.139985665
97.646 0.5052 0.5844 0.4948 0.4156 1.165855643 1.193346598
98.462 0.5432 0.6174 0.4568 0.3826 1.155098376 1.199924215
99.811 0.6332 0.6772 0.3668 0.3228 1.101787666 1.278053105
99.95 0.6605 0.6926 0.3395 0.3074 1.081772458 1.316779865
100.278 0.6945 0.7124 0.3055 0.2876 1.061697466 1.373566293
100.467 0.7327 0.7383 0.2673 0.2617 1.044897205 1.431180769
100.999 0.7752 0.7729 0.2248 0.2271 1.039369751 1.484582015
101.059 0.7922 0.7876 0.2078 0.2124 1.037025229 1.502969819
99.877 0.908 0.8959 0.092 0.1041 1.017144449 1.6443516
99.799 0.9448 0.9336 0.0552 0.0664 1.017865992 1.746712729
96.885 1 1 0 0 1 0

Grafica
Gibbs molar vs Fraccion molar
450
400
Energia libre de Gibbs molar

350
300
250 X1
200 Y1
150
100
50
0
0 0.2 0.4 0.6 0.8 1 1.2
Fraccion molar del componente 1
RTLn1 RTLn2 Ln1 Ln2 1 teorico 2 teorico DIF1
1658.840903 0 0.607991702 0 1.8367389724 1 0
1570.452969 1.370136196 0.575596111 0.000502177 1.7781902101 1.0005023029 0.00929285
1485.179164 5.429645126 0.544341899 0.001990052 1.7234737891 1.0019920332 0.001747287
1400.377242 12.3592927 0.513260639 0.004529878 1.6707299713 1.0045401537 0.002777569
1346.12493 18.4227231 0.4933763 0.006752222 1.6378367236 1.0067750701 0.004664724
1232.02387 35.71768126 0.451556438 0.013091101 1.5707550666 1.0131771646 9.36386E-05
1040.112322 80.81790979 0.381217788 0.029621056 1.4640664274 1.0300641229 0.001097574
887.9971941 134.0173052 0.325465163 0.049119484 1.3846745958 1.0503458429 0.00012679
707.9239751 223.1270245 0.259465451 0.08177962 1.2962369987 1.0852166239 0.000135782
609.7848958 287.2155473 0.22349591 0.105269088 1.2504405255 1.1110095297 4.87927E-05
526.1920223 353.0217642 0.192857785 0.129388118 1.2127103163 1.1381317683 0.000121954
424.0767783 451.4213072 0.155430917 0.165453123 1.1681612328 1.1799276505 5.31574E-06
362.0793003 523.6767215 0.13270785 0.191935888 1.1419163389 1.2115928363 0.000173766
234.2493311 716.7996598 0.085856124 0.262718531 1.0896495421 1.3004606279 0.000147334
200.8393172 781.4964172 0.073610819 0.286430926 1.0763878148 1.3316661817 2.89944E-05
162.7663941 866.046575 0.059656485 0.31741991 1.0614718521 1.3735792311 5.09015E-08
124.703164 966.2911709 0.045705703 0.354161157 1.046766305 1.4249848141 3.49353E-06
88.25628752 1084.326446 0.03234734 0.397422972 1.0328762021 1.4879851725 4.21662E-05
75.42643282 1133.452399 0.027644993 0.415428419 1.0280306616 1.5150196643 8.09022E-05
14.78749263 1496.891763 0.005419852 0.548634754 1.0054345663 1.7308883155 0.000137121
5.321799096 1622.791173 0.001950524 0.5947789 1.0019524279 1.8126301275 0.000253242
0 1820.890096 0 0.667385321 1 1.9491342911 0
SUMATORIA 0.020979348

Gibbs molar vs Datos experimental

450
450
Energia libre de GIbbs molar

400
Energia libre de GIbbs molar

400
350
350
300
300
250
250
200
200
150
150
100
100
50
50
0
0 0.2 0.4 0.6 0.8 1 1.2 1.4 1.6 1.8 2 0
0.8 1
Calculo experimental

Experi mental 1 Experi mental 2

DIF2 Gmol. Expe CELDA OBJ
0 0 0.0352155037
0.0001481676 46.32353117 T(C) 328.15
8.30869E-05 89.47175458 R(kpa*m3/Kmol*k) 8.314472
1.668703E-06 130.784311
2.301881E-05 156.3295521
0.0001727327 207.635441
9.904066E-06 285.610117
4.320639E-05 338.5995063
0.0003060071 388.4853357 A 1700.226827
0.0003761254 408.1848052 B 31.47625564
3.436933E-06 419.6232564 C -9.90966819
0.0001800681 425.092294 D 0
0.0001361567 422.5401314
0.0005020971 396.6750774
0.0002216024 383.295158
1.674058E-10 363.0164059 a1 1745.107253
3.838986E-05 335.4392827 b1 32.6496684
1.158148E-05 298.7858689 c1 -118.916018
0.0001451988 282.3609017
0.0074886032 143.624534
0.0043451034 89.7232071
0 0 a2 1655.346401
0.0142361558 b2 284.4597135
c2 -118.916018

Gibbs molar vs Datos Teoricos

450
Energia libre de GIbbs molar

400
350
300
250
200
150
100
50
0
0.8 1 1.2 1.4 1.6 1.8 2 2.2
Calculo Teorico

Teori co 1 Teori co 2
Datos de equilibrio L-V para la Actividad
en Clase 15.1

P [kPa] x1 y1 x2 y2 gama1 exp

68.728 0 0 1 1 0
72.278 0.0287 0.0647 0.9713 0.9353 1.681790779
75.279 0.057 0.1295 0.943 0.8705 1.765274349
77.524 0.0858 0.1848 0.9142 0.8152 1.723432618
78.951 0.1046 0.219 0.8954 0.781 1.706135509
82.528 0.1452 0.2694 0.8548 0.7306 1.580431772
86.762 0.2173 0.3633 0.7827 0.6367 1.497196084
90.088 0.2787 0.4184 0.7213 0.5816 1.395934719
93.206 0.3579 0.4779 0.6421 0.5221 1.284584445
95.017 0.405 0.5135 0.595 0.4865 1.24345535
96.365 0.448 0.5512 0.552 0.4488 1.223753585
97.646 0.5052 0.5844 0.4948 0.4156 1.165855643
98.462 0.5432 0.6174 0.4568 0.3826 1.155098376
99.811 0.6332 0.6772 0.3668 0.3228 1.101787666
99.95 0.6605 0.6926 0.3395 0.3074 1.081772458
100.278 0.6945 0.7124 0.3055 0.2876 1.061697466
100.467 0.7327 0.7383 0.2673 0.2617 1.044897205
100.999 0.7752 0.7729 0.2248 0.2271 1.039369751
101.059 0.7922 0.7876 0.2078 0.2124 1.037025229
99.877 0.908 0.8959 0.092 0.1041 1.017144449
99.799 0.9448 0.9336 0.0552 0.0664 1.017865992
96.885 1 1 0 0 1

Grafica
Gibbs molar vs Fraccion Molar
500
450
Energia Libre de Gibbs molar

400
350
300
250
200
150
100
50
0
0 0.2 0.4 0.6 0.8 1 1.2
Fraccion Molar componente 1

X1 Y1
 gama2 exp RTLn1 RTLn2 Ln1 Ln2 1 teorico 2 teorico
1 1697.022983 0 0.621986044 0 1.862623624 1
1.012674715 1603.098735 1.367897839 0.587561306 0.000501356 1.7995944004 1.0005014821
1.011107235 1512.982982 5.402685246 0.554532443 0.00198017 1.7411267181 1.0019821323
1.005831936 1423.834023 12.25783925 0.521857925 0.004492694 1.685155635 1.0045028013
1.001977278 1367.037305 18.23393959 0.50104102 0.00668303 1.6504385157 1.0067054115
1.026319945 1248.163776 35.20182145 0.457471971 0.01290203 1.5800744584 1.0129856204
1.02691705 1049.890132 79.10328172 0.384801512 0.028992617 1.4693226497 1.0294169942
1.056919 894.0930958 130.4890869 0.327699409 0.047826336 1.3877717573 1.0489884677
1.102709682 711.0436443 215.9727507 0.260608859 0.079157465 1.2977199749 1.0823747445
1.130403483 611.8403658 277.1530984 0.224249272 0.10158104 1.2513829155 1.1069196194
1.139985665 527.6117419 339.7948424 0.193378135 0.12454024 1.2133415142 1.1326275967
1.193346598 425.0109339 433.2284525 0.1557733 0.158785151 1.1685612597 1.1720860987
1.199924215 362.8482812 501.7167247 0.132989694 0.183887198 1.1422382263 1.2018802407
1.278053105 234.8879223 684.5247166 0.086090177 0.250889248 1.0899046086 1.285167742
1.316779865 201.4673811 745.7408262 0.073841015 0.273325931 1.0766356229 1.3143285552
1.373566293 163.3797688 825.7566858 0.059881296 0.302653022 1.0617105101 1.3534447677
1.431180769 125.2863177 920.6748455 0.045919438 0.337442045 1.0469900596 1.4013583898
1.484582015 88.7787326 1032.547932 0.032538824 0.378445319 1.0330740008 1.4600129695
1.502969819 75.91563518 1079.154054 0.027824294 0.395527207 1.0282150045 1.4851669755
1.6443516 14.95598982 1425.062779 0.005481609 0.522308283 1.0054966608 1.6859147302
1.746712729 5.392799447 1545.447288 0.001976547 0.56643113 1.0019785018 1.7619675835
0 0 1735.563207 0 0.636111652 1 1.8891210203
SUMATORIA

n Molar Gibbs molar vs Dato Experimental

500
450
Energia LIbre de Gibbs molar

400
350
300
250
200
150
100
50
0.8 1 1.2 0
0 0.2 0.4 0.6 0.8 1 1.2 1.4 1.6 1.8 2
onente 1
Calculo experimental

Experimenta l 2 Experimenta l 1
 DIF1 DIF2 Gmol. Expe CELDA OBJ
0 0 0 0.0272747539
0.013877693 0.0001481876 47.33757287 T(C)
0.000583108 8.32675E-05 91.33476219 R(kpa*m3/Kmol*k)
0.001465127 1.7666E-06 133.3710758
0.003102155 2.235525E-05 159.3187716
1.27673E-07 0.0001778042 211.3238973
0.000776928 6.24972E-06 290.0552642
6.66339E-05 6.289334E-05 343.3055242
0.000172542 0.0004135097 393.1586236 A 1716.293095
6.28463E-05 0.0005514919 412.7014417 B 19.27011181
0.000108411 5.414117E-05 423.9368134 C 0
7.32036E-06 0.0004520088 429.0769621 D 0
0.000165383 0.000003826 426.2833862
0.000141207 5.061806E-05 399.8146984
2.63871E-05 6.008918E-06 386.2482157
1.70157E-10 0.0004048758 365.735917 a1 1774.103431
0.00000438 0.0008893743 337.8936711 b1 -77.0804472
3.96365E-05 0.000603638 300.9380487
7.76201E-05 0.0003169412 284.3885786
0.000135671 0.0017274938 144.6858144
0.000252412 0.0002327106 90.40380724
0 0 0 a2 1658.48276
0.021065591 0.0062091625 b2 77.08044723

ntal Gibbs molar vs Dato Teorico

500
450
Energia LIbre de Gibbs molar

400
350
300
250
200
150
100
50
0
0.8 1 1.2 1.4 1.6 1.8 2
1.4 1.6 1.8 2
Calculo teorico

Teori co 1 Teori co 2
 328.15
8.314472

1.6 1.8 2
 Podemos observar, para los dos casos, que en la parte
experimental podemos observar de mejor manera cuando uno
de los compuestos esta puro ya que muestra datos, exactos de 0,
demostrando asi el comportamiento de la sustancias con
respecto al cambio de presion, aunque al ver los resultados en la
parte teorica se puede concluir que es mas preciso por la
cantidad de datos que se pueden obtener con el calculo.

En consideracion al modelo, se puede concluir que el desarrollo

con 2 parametros es mejor, ya que emplea una mayor precision
en sus datos, viendo en las graficas correspondientes menos
dispersion en los resultados, ademas la funcion se desarrolla de
manera mas simple manejando los mismos parametros,
mostrando de forma practica la energia de gibbs en exceso.