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Material Safety Data Sheet

MSDS 2635

Section 1: Product and Company Identification


PortaGas, Inc.
1202 E. Sam Houston Pkwy. S.
Pasadena, TX 77503
Phone: 713-928-6477
Fax: 713-928-9961
Toll free number: 800-548-2268
www.portagas.com
Sales and customer support - support@portagas.com

Product Code: MSDS 2635


Gas Name Concentration
Ethylene Oxide 0 - 1.5%
Oxygen 0 - 23.5%
Nitrogen Balance

Chemical Chemical Family Trade Names


Substance
Ethylene ETHYLENE OXIDE Organic oxide / cyclic OXIRANE; DIHYROOXIRENE; DIMETHYLENE OXIDE; EPOXYETHANE; 1,2-
Oxide ether / aliphatic EPOXYETHANE; ETHENE OXIDE; ETO; EO; OXACYCLOPROPANE; OXANE;
oxirane / aliphatic OXIDOETHANE; ALPHA,BETA-OXIDOETHANE; OXIRAN; RCRA U115; STCC
epoxide 4906610; UN 1040; C2H4O
Oxygen OXYGEN, inorganic, gas OXYGEN; DIOXYGEN; MOLECULAR OXYGEN; OXYGEN MOLECULE; PURE
COMPRESSED OXYGEN; UN 1072; O2
GAS
Nitrogen NITROGEN, inorganic, gas DIATOMIC NITROGEN; DINITROGEN; NITROGEN; NITROGEN-14; NITROGEN
COMPRESSED GAS; UN 1066; N2
GAS

Section 2: Hazards Identification

Description Main Health Hazard


Ethylene Colorless, sweet odor Harmful if inhaled or swallowed, skin burns, eye burns, respiratory tract irritation, central
Oxide May explode when heated. Flammable nervous system depression, allergic reactions, cancer hazard (in humans), possible
gas. May cause flash fire. Very reactive. reproductive hazard, mutagen
Oxygen Colorless, odorless No significant target effects reported.
Containers may rupture or explode if
exposed to heat. May ignite
combustibles.
Nitrogen Colorless, odorless Difficulty breathing
Containers may rupture or explode if
exposed to heat.

Likely Routes of Exposure:


Inhalation Ingestion Eye Skin Health Effects Target Medical
Organs Condition
Aggravated
by -

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Inhalation Ingestion Eye Skin Health Effects Target Medical
Organs Condition
Aggravated
by -
Ethylene Irritation, lack of sense Irritation (possibly Irritation Irritation Harmful if inhaled Immune Not available
Oxide of smell, tearing, severe), sore (possibly (possibly or swallowed, skin system
nausea, vomiting, throat, nausea, severe), severe), burns, eye burns, (sensitizer),
diarrhea, difficulty vomiting, diarrhea, frostbite, allergic respiratory tract central
breathing, irregular stomach pain, tearing reactions, irritation, central nervous
heartbeat, headache, chest pain, blisters nervous system system
drowsiness, symptoms headache, depression, allergic
of drunkenness, drowsiness, reactions, cancer
disorientation, bluish symptoms of hazard (in
skin color, lung drunkenness, humans), possible
congestion, lung bluish skin color reproductive
damage, kidney hazard, mutagen
damage, paralysis,
reproductive effects,
convulsions
Oxygen Irritation, changes in No information on No No No significant target Respiratory Respiratory
body temperature, significant adverse information information effects reported. system conditions
nausea, difficulty effects on significant on
breathing, irregular adverse significant
heartbeat, dizziness, effects adverse
disorientation, effects
hallucinations, mood
swings, pain in
extremities, tremors,
lung congestion,
convulsions
Nitrogen Nausea, vomiting, Ingestion of a gas Contact with No Difficulty breathing Respiratory Pre-existing
difficulty breathing, is unlikely rapidly information system conditions of
headache, drowsiness, expanding on respiratory
dizziness, tingling gas may significant system.
sensation, loss of cause burns adverse
coordination, or frostbite effects
convulsions, coma
This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200).

Section 3: Composition/Information on Ingredients

CAS # % by Volume
Ethylene Oxide 75-21-8 0 - 1.5%
Oxygen 7782-44-7 0 - 23.5%
Nitrogen 7727-37-9 Balance

Section 4: First Aid Measures

Skin Contact Eye Contact Ingestion Inhalation Note to


Physicians
Ethylene If frostbite or freezing Wash eyes Contact local poison control If adverse effects occur, For inhalation,
Oxide occur, immediately flush immediately with center or physician remove to uncontaminated consider
with plenty of lukewarm large amounts of immediately. Never make area. Give artificial respiration oxygen. For
water (105-115 F; 41-46 water, occasionally an unconscious person if not breathing. Avoid mouth- ingestion,
C). DO NOT USE HOT lifting upper and vomit or drink fluids. When to-mouth contact by using consider gastric
WATER. If warm water lower lids, until no vomiting occurs, keep head mouth guards or shields. If lavage and
is not available, gently evidence of chemical lower than hips to help breathing is difficult, oxygen activated
wrap affected parts in remains. Get medical prevent aspiration. If person should be administered by charcoal slurry.
blankets. Get immediate attention is unconscious, turn head to qualified personnel. Get
medical attention. immediately. side. Get medical attention immediate medical attention.
immediately.

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Skin Contact Eye Contact Ingestion Inhalation Note to
Physicians
Oxygen None expected None expected Not likely route of exposure If adverse effects occur, None
remove to uncontaminated
area. Give artificial respiration
if not breathing. Get immediate
medical attention.
Nitrogen Wash exposed skin with Flush eyes with If a large amount is If adverse effects occur, For inhalation,
soap and water. plenty of water. swallowed, get medical remove to uncontaminated consider
attention. area. Give artificial respiration oxygen.
if not breathing. If breathing is
difficult, oxygen should be
administered by qualified
personnel. Get immediate
medical attention.

Section 5: Fire Fighting Measures

Suitable Extinguishing Media Products of Combustion Protection of Firefighters


Ethylene Carbon dioxide, regular dry chemical, Carbon monoxide, carbon Any self-contained breathing apparatus that has
Oxide water Large fires: Use alcohol-resistant dioxide and toxic and a full facepiece and is operated in a pressure-
foam or flood with fine water spray. irritating fumes, carbon, demand or other positive-pressure mode. Full
acetaldehyde body chemical protective suit.
Any self-contained breathing apparatus that has
a full facepiece and is operated in a pressure-
demand or other positive-pressure mode. Full
body chemical protective suit.
Oxygen Non-flammable. Use extinguishing agent Oxides of burning material Respiratory protection may be needed for
appropriate for the material which is frequent or heavy exposure.
burning. Use water in large quantities for None
fires involving oxygen.
Nitrogen Non-flammable. Use suitable Non-flammable Respiratory protection may be needed for
extinguishing media for surrounding fire. frequent or heavy exposure.
Cylinders may rupture or explode if
exposed to heat.

Section 6: Accidental Release Measures

Personal Precautions Environmental Precautions Methods for Containment


Ethylene Keep unnecessary people away, isolate Avoid heat, flames, sparks and other Stop leak if possible without personal risk.
Oxide hazard area and deny entry. sources of ignition. Keep out of water Reduce vapors with water spray. Do not get
supplies and sewers. water inside container. Remove sources of
ignition.
Oxygen Keep unnecessary people away, isolate Avoid contact with combustible Stop leak if possible without personal risk.
hazard area and deny entry. Ventilate materials.
closed spaces before entering.
Nitrogen Keep unnecessary people away, isolate No significant effects from Stop leak if possible without personal risk.
hazard area and deny entry. Stay contamination expected.
upwind and keep out of low areas.

Methods for Cleanup Other Information


Ethylene Small spills: Flood Notify Local Emergency Planning Committee and State Emergency Response Commission for release
Oxide with water. Large greater than or equal to RQ (U.S. SARA Section 304). If release occurs in the U.S. and is reportable under
spills: Dike for later CERCLA Section 103, notify the National Response Center at (800)424-8802 (USA) or (202)426-2675
disposal. (USA). Subject to California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65).
Oxygen Stop leak and None
ventilate
Nitrogen N/A N/A

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Section 7: Handling and Storage

Handling Storage
Ethylene Store and handle in accordance with all current regulations and standards. Subject to storage Keep separated from
Oxide regulations: U.S. OSHA 29 CFR 1910.106. Store below 30 C. Store outside or in a detached building. incompatible substances.
Avoid contact with light. Store in a cool, dry place. Use diking sufficient to contain total contents plus Protect from physical
10%. Store with flammable liquids. Keep separated from incompatible substances. Grounding and damage.
bonding required. Notify State Emergency Response Commission for storage or use at amounts
greater than or equal to the TPQ (U.S. EPA SARA Section 302). SARA Section 303 requires facilities
storing a material with a TPQ to participate in local emergency response planning (U.S. EPA 40 CFR
355.30).
Oxygen Store and handle in accordance with all current regulations and standards. Subject to storage Keep separated from
regulations: U.S. OSHA 29 CFR 1910.101. incompatible substances.
Nitrogen Store and handle in accordance with all current regulations and standards. Subject to storage Keep separated from
regulations: U.S. OSHA 29 CFR 1910.101. incompatible substances.

Section 8: Exposure Controls/Personal Protection

Exposure Guidelines
Ethylene ETHYLENE OXIDE: 1 ppm OSHA TWA 5 ppm OSHA excursion limit 15 minute(s) 0.5 ppm OSHA action level 1 ppm ACGIH TWA
Oxide 0.1 ppm (0.18 mg/m3) NIOSH recommended TWA 10 hour(s) (not to exceed) 5 ppm (9 mg/m3) NIOSH recommended ceiling 10
minute(s)
Oxygen OXYGEN, COMPRESSED GAS: No occupational exposure limits established.
Nitrogen NITROGEN, COMPRESSED GAS: NITROGEN: ACGIH (simple asphyxiant)

Engineering Controls
Handle only in fully enclosed systems.
Eye Protection Skin Protection Respiratory Protection
Ethylene Wear splash resistant safety goggles with For the gas: Wear appropriate chemical Any self-contained breathing apparatus
Oxide a face shield. Provide an emergency eye resistant clothing. For the liquid: Wear that has a full facepiece and is operated in
wash fountain and quick drench shower appropriate protective, cold insulating a pressure-demand or other positive-
in the immediate work area. clothing. Wear appropriate chemical pressure mode. Full body chemical
resistant clothing. protective suit.
Oxygen Eye protection not required, but Protective clothing is not required. Respiratory protection may be needed for
recommended. frequent or heavy exposure.
Nitrogen Eye protection not required, but Protective clothing is not required. Respiratory protection may be needed for
recommended. frequent or heavy exposure.

General Hygiene considerations


Avoid breathing vapor or mist
Avoid contact with eyes and skin
Wash thoroughly after handling and before eating or drinking

Section 9: Physical and Chemical Properties

Physical State Appearance Color Change in Appearance Physical Form Odor Taste
Ethylene Oxide Gas Colorless Colorless N/A Liquid Sweet odor N/A
Oxygen Gas Clear Colorless N/A Gas Odorless Tasteless
Nitrogen Gas Clear Colorless N/A Gas Odorless Tasteless

Flash Point Flammability Partition Autoignition Upper Explosive Lower Explosive


Coefficient Temperature Limits Limits
Ethylene -4 F (-20 C) (CC) (pure Not available Not available 804 F (429 C) 1 0.03
Oxide ethylene oxide)
Oxygen Not flammable Not available Not available Nonflammable Nonflammable Nonflammable
Nitrogen Not flammable Not available Not available Nonflammable Nonflammable Nonflammable

Boiling Freezing Vapor Vapor Specific Water pH Odor Evaporation Viscosity


Point Point Pressure Density Gravity Solubility Threshold Rate

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Boiling Freezing Vapor Vapor Specific Water pH Odor Evaporation Viscosity
Point Point Pressure Density Gravity Solubility Threshold Rate
Ethylene 50.7 F -168 F (- 1095 1.5 0.8824 @ Soluble Not 500 ppm Not 0.0095 cP
Oxide (10.4 C) 111 C) mmHg @ 10 C applicable applicable @ 20 C
(pure 20 C
ethylene
oxide)
Oxygen -297 F -360 F (- 760 1.1 Not 3.2% @ Not Not Not 0.02075
(-183 C) 218 C) mmHg @ applicable 25 C applicable available applicable cP @ 25
-183 C C
Nitrogen -321 F -346 F (- 760 0.967 Not 1.6% @ Not Not Not 0.01787
(-196 C) 210 C) mmHg @ applicable 20 C applicable available applicable cP @ 27
-196 C C

Molecular Molecular Density Weight per Volatility by Volatility Solvent Solubility


Weight Formula Gallon Volume
Ethylene 44.06 (C-H2)2-O Not Not 100% 1 Soluble: Alcohol, ether, acetone,
Oxide available available benzene, carbon tetrachloride,
organic solvents
Oxygen 31.9988 O2 1.309 g/L Not Not Not Soluble: Alcohol
@ 25 C available applicable applicable
Nitrogen 28.0134 N2 1.2506 g/L Not 100% 1 Soluble: Liquid ammonia
available

Section 10: Stability and Reactivity

Stability Conditions to Avoid Incompatible Materials


Ethylene May decompose explosively when May decompose explosively when Acids, combustible materials, bases, metal salts,
Oxide heated above 427 C. Normally heated above 427 C. Normally metal oxides, amines, halo carbons, metals,
stable in the absence of catalysts. stable in the absence of catalysts. cyanides, oxidizing materials, porous refractory
insulation, alcohols
Oxygen Stable at normal temperatures and Stable at normal temperatures and Combustible materials, halo carbons, metals, bases,
pressure. pressure. reducing agents, amines, metal salts, oxidizing
materials, alkaline earth and alkali metals
Nitrogen Stable at normal temperatures and Stable at normal temperatures and Metals, oxidizing materials
pressure. pressure.

Hazardous Decomposition Possibility of Hazardous Reactions


Products
Ethylene Oxides of carbon May polymerize violently or explosively. May polymerize when heated. Avoid contact with
Oxide incompatible materials.
Oxygen Miscellaneous decomposition Will not polymerize.
products
Nitrogen Oxides of nitrogen Will not polymerize.

Section 11: Toxicology Information

Acute Effects
Oral LD50 Dermal Inhalation
LD50
Ethylene 72 mg/kg oral- Not Irritation, lack of sense of smell, tearing, nausea, vomiting, diarrhea, difficulty breathing, irregular
Oxide rat LD50 available heartbeat, headache, drowsiness, symptoms of drunkenness, disorientation, bluish skin color, lung
congestion, lung damage, kidney damage, paralysis, reproductive effects, convulsions
Oxygen Not Not Irritation, changes in body temperature, nausea, difficulty breathing, irregular heartbeat, dizziness,
established established disorientation, hallucinations, mood swings, pain in extremities, tremors, lung congestion,
convulsions
Nitrogen Not available Not Nausea, vomiting, difficulty breathing, headache, drowsiness, dizziness, tingling sensation, loss of
available coordination, convulsions, coma

Eye Irritation Skin Irritation Sensitization

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Eye Irritation Skin Irritation Sensitization
Ethylene Irritation (possibly severe), Irritation (possibly Harmful if inhaled or swallowed, skin burns, eye burns, respiratory tract
Oxide frostbite, tearing severe), allergic irritation, central nervous system depression, allergic reactions, cancer
reactions, blisters hazard (in humans), possible reproductive hazard, mutagen
Oxygen No information on No information on No significant target effects reported.
significant adverse effects significant adverse
effects
Nitrogen Contact with rapidly No information on Difficulty breathing
expanding gas may cause significant adverse
burns or frostbite effects

Chronic Effects
Carcinogenicity Mutagenicity Reproductive Developmental
Effects Effects
Ethylene OSHA: Carcinogen; NTP: Known Human Carcinogen; IARC: Human Available. Available. No data
Oxide Limited Evidence, Animal Sufficient Evidence, Group 1; ACGIH: A2 -
Suspected Human Carcinogen
Oxygen Not known. Available. Available. No data
Nitrogen Not hazardous Not available Not available No data

Section 12: Ecological Information

Fate and Transport


Eco toxicity Persistence / Bioaccumulation / Mobility in
Degradability Accumulation Environment
Ethylene Fish toxicity: Acute LC50 84000 to 96000 ug/L Fresh Not available Not available Not available
Oxide water Fish - Fathead minnow - Pimephales promelas 96
hours
Invertibrate toxicity: 490000 ug/L 48 hour(s) LC50
(Mortality) Brine shrimp (Artemia sp)
Algal toxicity: Not available
Phyto toxicity: Not available
Other toxicity: Not available
Oxygen Fish toxicity: Not available Not available Low bioaccumulation Not available
Invertibrate toxicity: Not available
Algal toxicity: Not available
Phyto toxicity: Not available
Other toxicity: Not available
Nitrogen Fish toxicity: Not available Not available Not available Not available
Invertibrate toxicity: Not available
Algal toxicity: Not available
Phyto toxicity: Not available
Other toxicity: Not available

Section 13: Disposal Considerations

Ethylene Subject to disposal regulations: U.S. EPA 40 CFR 262. Hazardous Waste Number(s): U115. Dispose in accordance with all
Oxide applicable regulations.
Oxygen Dispose in accordance with all applicable regulations. Subject to disposal regulations: U.S. EPA 40 CFR 262. Hazardous Waste
Number(s): D001.
Nitrogen Dispose in accordance with all applicable regulations.

Section 14: Transportation Information


US DOT; IATA; IMO; ADR:
THIS GAS MIXTURE IS HAZARDOUS AS DEFINED BY 49 CFR 172.101 BY THE U.S. DEPARTMENT OF TRANSPORTATION.
Compressed gases, n.o.s. (*Oxygen, Nitrogen)*or the gas component with the next highest
PROPER SHIPPING NAME:
concentration next to Nitrogen.

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HAZARD CLASS NUMBER and
2.2 (Non-Flammable Gas)
DESCRIPTION:
UN IDENTIFICATION NUMBER: UN 1956
PACKING GROUP: Not applicable.
DOT LABEL(S) REQUIRED: Class 2.2 (Non-Flammable Gas)
NORTH AMERICAN EMERGENCY RESPONSE GUIDEBOOK NUMBER (2000): 126
MARINE POLLUTANT: The components of this gas mixture are not classified by the DOT as Marine Pollutants (as defined by 49
CFR 172.101, Appendix B).
SPECIAL SHIPPING INFORMATION: Cylinders should be transported in a secure position, in a well-ventilated vehicle. The
transportation of compressed gas cylinders in automobiles or in closed-body vehicles can present serious safety hazards. If
transporting these cylinders in vehicles, ensure these cylinders are not exposed to extremely high temperatures (as may occur in
an enclosed vehicle on a hot day). Additionally, the vehicle should be well-ventilated during transportation.
Note: DOT 39 Cylinders ship in a strong outer carton (over pack). Pertinent shipping information goes on the outside of the
over pack. DOT 39 Cylinders do not have transportation information on the cylinder itself.
U.S. DEPARTMENT OF TRANSPORTATION (DOT) SHIPPING REGULATIONS:
This product is classified as dangerous goods, per U.S. DOT regulations, under 49 CFR 172.101.
TRANSPORT CANADA, TRANSPORTATION OF DANGEROUS GOODS REGULATIONS:
This product is classified as Dangerous Goods, per regulations of Transport Canada.
PROPER SHIPPING NAME: Compressed gases, n.o.s. (*Oxygen, Nitrogen)*or the gas
component with the next highest concentration next to Nitrogen.
HAZARD CLASS NUMBER and DESCRIPTION: 2.2 (Non-Flammable Gas)
UN IDENTIFICATION NUMBER: UN 1956
PACKING GROUP: Not Applicable
HAZARD LABEL: Class 2.2 (Non-Flammable Gas)
SPECIAL PROVISIONS: None
EXPLOSIVE LIMIT AND LIMITED QUANTITY INDEX: 0.12
ERAP INDEX: 3000
PASSENGER CARRYING SHIP INDEX: Forbidden
PASSENGER CARRYING ROAD VEHICLE OR PASSENGER CARRYING RAILWAY VEHICLE INDEX: Forbidden
NORTH AMERICAN EMERGENCY RESPONSE GUIDEBOOK NUMBER (2004): 126
Note: Shipment of compressed gas cylinders via Public Passenger Road Vehicle is a violation of Canadian law (Transport
Canada Transportation of Dangerous Goods Act, 1992).
INTERNATIONAL AIR TRANSPORT ASSOCIATION (IATA):
This product is classified as Dangerous Goods, by rules of IATA:
INTERNATIONAL MARITIME ORGANIZATION (IMO) DESIGNATION:
This product is classified as Dangerous Goods by the International Maritime Organization.

EUROPEAN AGREEMENT CONCERNING THE INTERNATIONAL CARRIAGE OF DANGEROUS GOODS BY ROAD (ADR):
This product is classified by the United Nations Economic Commission for Europe to be dangerous goods.

U.S. DOT 49 CFR 172.101


Proper Shipping ID Hazard Packing Labeling Passenger Cargo Additional
Name Number Class or Group Requirements Aircraft or Aircraft Only Shipping
Division Railcar Quantity Description
Quantity Limitations
Limitations
Ethylene ETHYLENE OXIDE; UN1040 2.3 Not 2.3; 2.1 Forbidden Forbidden Toxic-
Oxide or ETHYLENE OXIDE applicable Inhalation
WITH NITROGEN up Hazard Zone
to a total pressure of 1 D
MPa (10 bar) at 50
degrees C
Oxygen Oxygen, compressed UN1072 2.2 Not 2.2; 5.1 75 kg or L 150 kg N/A
available
Nitrogen Nitrogen, compressed UN1066 2.2 Not 2.2 75 kg or L 150 kg N/A
applicable

Canadian Transportation of Dangerous Goods


Shipping Name UN Class Packing Group / Risk
Number Group
Ethylene ETHYLENE OXIDE; or ETHYLENE OXIDE WITH NITROGEN up to a total UN1040 2.3; Not applicable
Oxide pressure of 1 MPa (10 bar) at 50 degrees C 2.1
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Oxygen Oxygen, compressed UN1072 2.2; Not applicable
5.1
Nitrogen Nitrogen, compressed UN1066 2.2 Not applicable

Section 15: Regulatory Information

U.S. Regulations
CERCLA Sections SARA 355.30 SARA 355.40
Ethylene Oxide ETHYLENE OXIDE: 10 LBS RQ Acetaldehyde: 1000 LBS RQ ACETIC ACID: 5000 LBS RQ 1000 LBS TPQ 10 LBS RQ
Oxygen Not regulated. Not regulated. Not regulated.
Nitrogen Not regulated. Not regulated. Not regulated.

SARA 370.21
Acute Chronic Fire Reactive Sudden Release
Ethylene Oxide Yes Yes Yes Yes Yes
Oxygen No No Yes No Yes
Nitrogen Yes No No No Yes

SARA 372.65
Ethylene Oxide ETHYLENE OXIDE
Oxygen Not regulated.
Nitrogen Not regulated.

OSHA Process Safety


Ethylene Oxide ETHYLENE OXIDE: 5000 LBS TQ Acetaldehyde: 2500 LBS TQ
Oxygen Not regulated.
Nitrogen Not regulated.

State Regulations
CA Proposition 65
Ethylene Known to the state of California to cause the following: ETHYLENE OXIDE Cancer (Jul 01, 1987) Female reproductive toxicity
Oxide (Feb 27, 1987) Acetaldehyde Cancer (Apr 01, 1988)
Oxygen Not regulated.
Nitrogen Not regulated.

Canadian Regulations
WHMIS Classification
Ethylene Oxide A, B1, D1A, D2A, E, F
Oxygen A,C
Nitrogen A

National Inventory Status


US Inventory (TSCA) TSCA 12b Export Notification Canada Inventory (DSL/NDSL)
Ethylene Oxide Listed on inventory. Not listed. Not determined.
Oxygen Listed on inventory. Not listed. Not determined.
Nitrogen Listed on inventory. Not listed. Listed on inventory.

Section 16: Other Information

NFPA Rating
Ethylene Oxide HEALTH=3 FIRE=4 REACTIVITY=3
Oxygen HEALTH=0 FIRE=0 REACTIVITY=0
Nitrogen HEALTH=1 FIRE=0 REACTIVITY=0
0 = minimal hazard, 1 = slight hazard, 2 = moderate hazard, 3 = severe hazard, 4 = extreme hazard

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