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1 The two graphs below show what scientists believe were the concentrations of nitrogen and carbon dioxide
in the atmosphere between 4 500 and 2 000 million years ago.
There was a time in history when carbon dioxide and nitrogen were present in equal percentages in the
atmosphere.
At what time
(A) did this occur? (B)
B S B S
2 The density of any substance is given by the equation:
(C) (D)
density = mass
1.0005
volume
1.0004 The graph shows the volume of one gram of water in the temperature
Volume (cm3)
1.0002 When a pond cools, water from the surface sinks to the bottom because
of its greater density.
1.0001
B S B
1.0000 As the temperature of the air aboveSthe water drops below 0 °C, the
0 2 4 6 8 10 surface of the water freezes. The temperature of the ice formed stays at
0 °C as more water freezes.
KEY
B = bottom
Which of the graphs below shows the temperature at different depths
S = surface
in a pond of water as the surface freezes over?
4 4 4 4
0 0 0 0
B S B S B S B S
3 When a liquid in a mixture evaporates, any dissolved solids are left behind.
water in condenser
water out
pure solvent
reflux sidearm
bypass sidearm
sieve
flask
solvent + chlorophyll
heat source
If the graphs are plotted on the same set of axes, they will cross at approximately 4 300 million years ago.
From the volume versus time graph, it can be seen that at 0-°C water is less dense than at 4 °C, which is the
temperature where water has its maximum density. This means that the surface of the freezing pond is at 0 °C and
the bottom is at 4 °C.
Because pure solvent is always entering the sieve, the chlorophyll remaining in the leaves will always be at the
highest possible concentration above that in the solution, so the maximum amount will be extracted.