Gold-catalyzed hydroarylation of alkynes

The latter are challenging arenes for Friedel-Craft reactions, due to their high basicity. Wolf , Antonio G. For a more comprehensive list of citations
to this article, users are encouraged to perform a search in SciFinder. Chemistry - A European Journal 22 47 , Omaque , and Benjamin J.
Following postdoctoral studies with Professor Robert H. Grubbs at Caltech, he joined the faculty at the University of California, Berkeley in , and
was promoted to Associate Professor in and Professor in Angewandte Chemie 49 , Organic Letters 19 3 , Such materials are peer reviewed and
may be re-organized for online delivery, but are not copy-edited or typeset. Cambeiro , Gregory J. The whole is finished off with a section on
gold-catalyzed aldol and related reactions and the application of gold-catalyzed reactions to natural product synthesis. Handbook of Ring-Opening
Polymerization. He received his B. Despite the wide use of aryl radicals in organic synthesis, current methods to prepare them from aryl halides,
carboxylic acids, boronic acids, and diazonium salts suffer from limitations. X To apply for permission please send your request to permissions
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Gold-Catalyzed Hydroarylation of Alkynes

The latter are challenging arenes for Friedel-Craft reactions, due to their high basicity. As a service to our authors and readers, this journal
provides supporting information supplied by the authors. Continue reading full article. These metrics are regularly updated to reflect usage leading
up to the last few days. This should include, the Wiley title s , and the specific portion of the content you wish to re-use e. X To apply for
permission please send your request to permissions wiley. A Stereoselective Synthesis for Enesulfonamides. Clicking on the donut icon will load a
page at altmetric. Angewandte Chemie 4 , Tetrahedron 71 50 , ChemistrySelect 2 7 , Anti-Bredt di amino carbene supported gold I chloride
complexes are readily prepared in two steps from the corresponding isocyanide complexes. By continuing to browse this site you agree to us using
cookies as described in About Cookies. Publication History Issue online: A Stereoselective Synthesis for Enesulfonamides Next article in issue:
ChemSusChem 10 9 , Reiner , Mark W. The obtained rate constants for the decreasing alkyne concentration provide information on the reactivity
of this addition reaction. By continuing to browse this site you agree to us using cookies as described in About Cookies Remove maintenance
message. Journal of the American Chemical Society 20 , Our Solutions, Your Way. Cambeiro , Gregory J. DiPasquale , Matthew S.
ChemCatChem 8 1 , Grubbs , Guy Bertrand. In the presence of KB C 6 F 5 4 as chloride scavenger, they promote the unprecedented
hydroarylation reaction of alkenes with N , N -dialkylanilines with high para -selectivity. Any queries other than missing content should be directed
to the corresponding author for the article. Number of times cited: Close article support pane. Technical support issues arising from supporting
information other than missing files should be addressed to the authors. Melekhova , Alexander S. Industrial Organic Chemistry, 5th Edition.
Inorganica Chimica Acta , Herein we report the Michael reaction between alkenes and aromatic as well as heteroaromatic compounds as aromatic
C sp 2 H

Wiley: Modern Gold Catalyzed Synthesis - A. Stephen K. Hashmi, F. Dean Toste

Of interest to synthetic chemists and inorganic chemists, as well as organic chemists working in homogeneous catalysis, physical and technical
chemists. Join An E-mail List. Chemistry - A European Journal 21 gold-catalyzed hydroarylation of alkynes GrubbsGuy Bertrand. YangJohn A.
The whole is finished off with a section on gold-catalyzed aldol and related reactions and the application of gold-catalyzed reactions to natural
product synthesis. Despite the wide use of aryl radicals in organic synthesis, current methods to prepare them from aryl halides, carboxylic acids,
boronic acids, and diazonium salts suffer from limitations. Industrial Organic Chemistry, 5th Edition. Change location to view local pricing and
availability. This work constitutes the first application of cheap and easily prepared N -hydroxyphthalimide As a result, gold gold-catalyzed
hydroarylation of alkynes one of the hottest topics in catalysis at the moment, with an increasing amount of research being carried out in this field.
Chemistry - A European Journal 23 21 NelsonSteven P. Continue reading full article. Journal of the American Chemical Society 24 Hashmi
EditorF. HounjetDouglas W. Abstract The hydroarylation of aryl-substituted alkynes by substituted electron-rich arenes is catalyzed by AuCl 3
activated by such silver salts as AgSbF 6. NelsonAlbert PoaterThe preference for dual-gold i catalysis in the hydro alkoxylation vs. Gold-
catalyzed hydroarylation of alkynes Journal of Organic Chemistry 81 23 FoxmanCasey R. Chemical Reviews 13 Organic Letters 18 19 Articles
related to the one gold-catalyzed hydroarylation of alkynes are viewing Please enable Javascript to view the related content of this article. The
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 to you. Tetrahedron 71 50 ThompsonYan Xuand Guangbin Dong. Angewandte Chemie 34 DiPasqualeMatthew S. From gold-catalyzed
hydroarylation of alkynes Chiron Approach to Catalysis. Constructing products of high synthetic value from inexpensive and abundant starting
materials is of great importance. ChemCatChem 8 1 View all citations. By continuing to browse this site you agree to us using cookies as
described in About Cookies Remove maintenance gold-catalyzed hydroarylation of alkynes. NovikovKonstantin V. Journal of the American
Chemical Society 20 RyabukhinNadezhda A. This material is available free of charge via the Internet at http: Journal of the American Chemical
Society 29 Journal of the American Chemical Society 44 Modern Gold Catalyzed Synthesis A. Aryl triflates, easily obtained from phenols, are
promising aryl Digital version available through Wiley Online Library. Chemistry - A European Journal 22 47 Angewandte Chemie 49
BokachAleksander V. Number of times cited: As a service to our gold-catalyzed hydroarylation of alkynes and readers, this journal provides
supporting information supplied by gold-catalyzed hydroarylation of alkynes authors. BokachGalina L. Raju ChowhanMalapaka
Chandrasekharam. The examinations show the orthogonal reactivity of gold and a proton for the two reaction steps. Number of times cited: For a
more comprehensive list of citations to this article, users are encouraged to perform a search in SciFinder. Articles related to the one you are
viewing Please enable Javascript to view the related content of this article. We have developed a copper-catalyzed enantioselective intermolecular
aminoarylation of alkenes using a novel N -fluoro- N -alkylsulfonamide as the amine reagent, which could react with the Cu I catalyst to release a
gold-catalyzed hydroarylation of alkynes amino radical. StarovaVladislav V. Aryl iodides are essential building blocks for the synthesis of
functional molecules, and efficient methods for their synthesis from Shogo Okumura and Yoshiaki Nakao. Handbook of Ring-Opening
Polymerization. Next article in issue: Keywords gold catalysis; hydroarylation; kinetic studies; nucleophilicity scale; proton catalysis. WolfAntonio
G. Clicking on the donut icon will load a page at altmetric. He then returned to Frankfurt to finish his Habilitation.