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2 1/6
CANDIDATO(A):______________________________________________________________
1 - Calcule a solubilidade e indique qual dos iodetos, AgI e BiI3, o mais solvel em:
a) gua? b) NaI 0,1 mol/L?
2 - Uma amostra de 0,3516g de detergente fosfatado foi levada ignio para destruir a matria
orgnica. O resduo foi ento tomado em HCl a quente para converter o P em H3PO4. O fosfato foi
precipitado como MgNH4PO4.6H2O pela adio de Mg+2 seguida por NH3 aquosa. Depois de
filtrado e lavado, o precipitado foi convertido em Mg2P2O7 aps ignio a 10000C. Este resduo
pesou 0,2161g. Calcule a percentagem de fsforo (em P) na amostra.
4 O furano sofre reao de substituio mais facilmente que o benzeno. Por exemplo, o furano
reage com bromo para levar ao 2-bromo-furano:
O Br 2 O
Br
dioxano, 25o C
7 - A reao 2H2O2(aq) 2H2O(l) + O2(g) tem o seguinte mecanismo na presena de ons Br:
9 - O potencial para a clula de Zn(s) | Zn2+(aq, ?) || Pb2+(aq,0,10 mol.L-1) | Pb(s) 0,66 V. Qual a
molaridade dos ons Zn2+ ?
Dados:
Constantes:
h = 6,62.10 -34 J s = 6,62.10-27erg s; c = 3.108 m s-1 = 3.1010 cm s-1;
me = 9,1.10-31 kg = 9,1.10-28 g; e = 1,6.10-19 C = 4,8.10-10 u.e.c.
0 = 8,85.10-12 C2J-1m-1 R = 8,31451 J.K-1.mol-1 = 0,082 atm L K-1mol-1
F = 9,6485 x 104 C mol-1 N = 6,02 x 1023 mol-1
Nmero atmico:
H = 1; C = 6; N = 7; O = 8; F = 9; Na = 11; Mg = 12;
Si = 14; P = 15; S=16; Cl = 17; Zn = 30; Br = 35; Pb = 82
Constantes de equilbrio:
Kps (AgI) = 8,3.10-17 Kps (BiI3) = 8,1.10-19 Kps (Mg(OH)2) = 1,1.10-11
Equaes:
RT 0,059
G = G + RT lnQ G = -nF = ln Q ou = log Q
nF n
Ea n2h2
ln k = ln A En =
RT 8mL2
Transformaes:
1cal = 4,184 J; 1 atm L = 101,325 J; 1 atm = 101325 Pa
Exame de Seleo para o PPG-Qumica/UFPE 2008.2 4/6
Estruturas moleculares:
OH
OH
Borneol Isoborneol
Texto: Researchers in Minnesota have shown that olefins can be produced from vegetable-oil-
derived biodiesel using methods that are more environmentally friendly than conventional methods.
The researchers have shown that soy-based biodiesel can be oxidized to valuable olefins efficiently
and fairly selectively. The reaction is conducted in an autothermal catalytic reactor, in which heat is
supplied by oxidation reactions, not by external heaters. To carry out the oxidation process, the
Minnesota group uses an automotive fuel injector to spray droplets of biodiesel, which consists of
methyl oleate, methyl linoleate, and related compounds, onto the walls of the reactor where the
droplets vaporize. A mixture of the organic material and air is then passed over a catalyst that
contains a few percent of rhodium and cerium supported on alumina. By adjusting the ratio of
biodiesel to oxygen (C/O) in the feed stream, the team is able to control the oxidation process and
reactor conditions, such as catalyst temperature, and thereby tune the product distribution. For
example, at a C/O ratio of roughly 1.3, the reaction yields about 25% ethylene and smaller
concentrations of propylene, 1-butene, and 1-pentene. In contrast, at a C/O ratio of 0.9, the product
stream consists mainly of hydrogen and CO. The researchers report that at all C/O ratios, the
process yields less than 13% CO2 (an unwanted product). They add that the catalyst remains stable
and resists deactivation by carbon buildup even under extreme conditions.
(Adapted from Chemical and Engeneering News, 83(1),10, 2005)
2 Escreva uma mensagem em ingls (simples e objetiva para ser enviada por e-mail) para o autor
americano, Prof. Vicent Ortiz do Departamento de Qumica da Universidade do Alabama, Estados
Unidos da Amrica, solicitando que ele lhe envie o artigo intitulado A New and Efficient
Theoretical Methodology to Calculate Ionization Potential Energy in Biomolecular Systems
publicado na ltima edio do Journal of Computational Chemistry.
Exame de Seleo para o PPG-Qumica/UFPE 2008.2 6/6
3 O Webofscience uma poderosa ferramenta da internet para fazer pesquisa de artigos
publicados em peridicos cientficos. Como voc escreveria em ingls nos campos de busca para
localizar artigos relacionados com os seguintes temas: a) ligaes de hidrognio, b) clulas de
hidrognio, c) parmetros de intensidade no infravermelho, d) razo sinal rudo, e) espectros
resolvidos no tempo, f) ressonncia magntica nuclear, g) cromatografia lquida de alta eficincia,
h) clculos de orbitais moleculares, i) complexos de metais de transio e j) relao quantitativa
estrutura atividade.
Mensagem:
Dear Colleagues,
The Organizing Committee is pleased to invite you to attend the *XVth International Sol-
Gel Conference that will be held from August 23 to 27, 2009 in PORTO DE GALINHAS,
Pernambuco State, Brazil.
This biennial international conference focuses on both fundamentals and applications of sol-
gel science. Previous conferences have taken place in Padova (Italy, 1981), Wuzburg (Germany,
1983), Montpellier (France, 1985), Kyoto (Japan, 1987), Rio de Janeiro (Brazil, 1989), Sevilla
(Spain, 1991), Paris (France, 1993), Faro (Portugal, 1995), Sheffield (UK, 1997), Yokohama
(Japan, 1999), Padova (Italy, 2001), Sydney (Austalia, 2003), Los Angeles (USA, 2005),
Montpellier (France, 2007).
The highly successful Sol-Gel Workshop series over 27 years ago attests that sol-gel science
and technology is an extraordinarily and exciting multidisciplinary area of research.