MCQ Volumetric Analysis

Sr. Question mark Ans

No wer
.
1 The number of gm-equivalent of the solute per liter of solution is known as 1 a
a) Normality c) Molarity
b) Molality d) Mole fraction
2 The number of gm-mole of the solute per liter of solution is known as 1 b
a) Normality c) Molarity
b) Molality d) Mole fraction
3 The number of gm-mole of the solute per kg of solution is known as 1 c
a) Normality c) Molarity
b) Molality d) Mole fraction
4 The ratio of number of gm-mole of a component to total number of gm- 1 d
mole in mixture or solution is known as
a) Normality c) Molarity
b) Molality d) Mole fraction
5 The number of gms of solute per 100 ml of solvent is known as 1 c
a) Normality c) % weight by volume
b) Molality d) Mole fraction
6 The chemical reagent from which solution of required concentration can be 1 d
prepared is
a) Secondary standard c) Dilute solution
b) Concentrated solution d) Primary standard
7 In neutralization titration, acid react with a base to form 1 a
a) Salt and water c) salt and acid
b) Neutral solution d) Concentrated solution
8 In strong acid strong base titration, the pH of mixture at initial stage is 1 a
find out by formula
a) PH = -log[H+]
b) [H+] = NaV a Nb Vb/ (Va + Vb)
c) POH = -log[OH-]
d) [OH-] = NbV b NaVa/ (Va + Vb)
9 In strong acid strong base titration, the pH of mixture before equivalence 1 b
point is find out by formula
a) PH = -log[H+]
b) [H+] = NaV a Nb Vb/ (Va + Vb)
c) POH = -log[OH-]
d) [OH-] = NbV b NaVa/ (Va + Vb)
10 In strong acid strong base titration, the pH of mixture after equivalence 1 d
point is find out by formula
a) PH = -log[H+]
b) [H+] = NaV a Nb Vb/ (Va + Vb)
c) POH = -log[OH-]
d) [OH-] = NbV b NaVa/ (Va + Vb)
11 The PH of titration mixture for Strong acid Strong base titration at 1 b
equivalence point is
a) 4 c) 2.7
b) 7 d) 9.2
12 The titration in which voltage or potential of the titration mixture is 1 d
measured with the help of redox electrode is
a) Precipitation titration c) Acid base titration
 b) Complexometric titration d) Potentiometric titration
13 The titration in which there is formation of co-ordination complex is 1 b
a) Precipitation titration c) Acid base titration
b) Complexometric titration d) Potentiometric titration
14 Stability of coordination complex depends upon 1 d
a) PH of titration mixture
b) Ability of metal ion and ligand to form complex
c) Nature of complex
d) All of above
15 If the titration mixture contains two metal ions ,then quantity of one of them 1 c
can be found by masking other metal is
a) EDTA titration c) Masking method
b) Redox method d) Complexometric method
16 A ligand is molecule or ion which can donate a pair of electron for 1 a
formation of
a) Co ordinate bond with metal ion
b) Covalent bond with metal ion
c) Ionic bond with metal ion
d) None of these
17 The indicator which is not added in titration flask but kept on a spot plate is 1 c
a) Self indicator c) External indicator
b) Internal indicator d) None of these
18 Internal indicators for redox titration is 1 b
a) Strong oxidizing agent or strong reducing agent
b) Weak oxidizing agent or weak reducing agent
c) Weak oxidizing agent or strong reducing agent
d) Strong oxidizing agent or weak reducing agent
19 In a Potentiometric titration of Ce+4 ion vs Fe+4 ion solution , electrode 1 d
potential at equivalence point is
a) 0.71 V c) 0.75 V
b) 1.45 V d) 1.1 V
20 An equivalent quantity of I2 liberated from oxidizing reagent during 1 a
titration against Na2S2O3 is
a) Iodimetric titration c) Precipitation titration
b) Potentiometric titration d) none of these
21 The titration of KMnO4 against oxalic acid or FeSO4 is example of 1 d
a) Iodimetric titration c) Precipitation titration
b) Potentiometric titration d) Redox titration
22 The titration during which reactant react to form is precipitation 1 c
titration.
a) Water soluble solid product
b) Metal indicator complex
c) Water insoluble solid product
d) Water soluble indicator
23 In Precipitation titration , organic dye is used as 1 b
a) Absorption indicator c) self indicator
b) Adsorption indicator d) External indicator
24 The weak acid weak base titration are not performed practically because 1 d
a) Reaction between weak acid and weak base is slow.
b) PH change at equivalence point is not sharp
c) Difficult to notice correct end point
d) All of above
25 All the indicators for acid- base titration are 1 a
 a) Weak organic acid or weak organic base
b) Strong organic acid and weak organic base
c) Weak organic acid and weak organic base
d) None of these
26 Colour change at PH interval for the organic acid indicator is 1 c
a) 4 PH units c) 2 PH units
H
b) 0 P units d) 1 PH units
27 The solution of known concentration is 1 b
a) Dilute solution c) concentrated solution
b) Standard solution d) none of these
28 The chemical reagent from which solution of exact concentration cannot be 1 a
prepared is
a) Secondary standard c) Dilute solution
b) Concentrated solution d) Primary standard
29 In Mohrs method of precipitation titration, 1 d
1 ml 1M AgNO3 = .. . mg Cl- = 80 mg Br- = .mg I-
a) 36.5 , 126 c) 34.5 , 128
b) 37.5 , 125 d) 35.5 , 127

30 The reagent which forces other molecule or ion to liberate electron in 1 a

a) Oxidizing agent c) reducing agent
b) Molecule d) atom
31 The reagent which forces other molecule or ion to capture electron in 1 c
a) Oxidizing agent c) reducing agent
b) Molecule d) atom
32 The reagent of known concentration which is taken in burette is 1 b
a) Titrand c) Titration
b) Titrant d) End point
33 The unknown solution whose concentration is to be determined by titration 1 a
is
a) Titrand c) Titration
b) Titrant d) End point
34 Addition of titrant from burette into titration flask till titrant react 1 c
completely is
a) Titrand c) Titration
b) Titrant d) End point
35 In weak acid strong base titration ,the PH of titration mixture at initial 1 a
stage is find out by formula
a) PH = -log[H+]
b) PH of acidic buffer= PKa + log [salt] / [weak acid]
c) PH = PKw + PKa pC
d) POH = -log[OH-]
36 In weak acid strong base titration ,the PH of titration mixture before 1 b
equivalence point is find out by formula
a) PH = -log[H+]
b) PH of acidic buffer= PKa + log [salt] / [weak acid]
c) PH = PKw + PKa pC
d) POH = -log[OH-]
37 In weak acid strong base titration ,the PH of titration mixture at 1 c
equivalence point is find out by formula
a) PH = -log[H+]
b) PH of acidic buffer= PKa + log [salt] / [weak acid]
c) PH = PKw + PKa pC
 d) POH = -log[OH-]
38 In weak acid strong base titration ,the PH of titration mixture after 1 d
equivalence point is find out by formula
a) PH = -log[H+]
b) PH of acidic buffer= PKa + log [salt] / [weak acid]
c) PH = PKw + PKa pC
d) POH = -log[OH-]
39 In weak base strong acid titration ,the PH of titration mixture at initial 1 d
stage is find out by formula
a) PH = -log[H+]
b) POH of basic buffer= PKa + log [salt] / [weak base]
c) PH = PKw - PKb + pC
d) PH = 14 - POH
40 In weak base strong acid titration ,the PH of titration mixture before 1 b
equivalence point is find out by formula
a) PH = -log[H+]
b) POH of basic buffer= PKa + log [salt] / [weak base]
c) PH = PKw - PKb + pC
d) PH = 14 - POH
41 In weak base strong acid titration ,the PH of titration mixture at 1 c
equivalence point is find out by formula
a) PH = -log[H+]
b) POH of basic buffer= PKa + log [salt] / [weak base]
c) PH = PKw - PKb + pC
d) PH = 14 - POH
42 In weak base strong acid titration ,the PH of titration mixture after 1 d
equivalence is find out by formula
a) PH = -log[H+]
b) POH of basic buffer= PKa + log [salt] / [weak base]
c) PH = PKw - PKb + pC
d) PH = 14 - POH
43 40 ml of 0.2 N HNO3 solution is titrated against 0.2 N NaOH from burette. 2 a
The PH of mixture at initial stage is ..
a) 0.92 b) 0.29
b) 1.46 d) 1.00
44 40 ml of 0.2 N HNO3 solution is titrated against 0.2 N NaOH from burette. 2 b
The PH of mixture at 22.5 ml NaOH addition stage is ..
a) 3.32 c) 7.00
b) 2.32 d) 0.92

45 40 ml of 0.2 N HNO3 solution is titrated against 0.2 N NaOH from burette. 2 d

The PH of mixture at 24 ml addition stage is ..
a) 0.92 c) 0.29
b) 1.46 d) 7.00
46 40 ml of 0.2 N HNO3 solution is titrated against 0.2 N NaOH from burette. 2 c
The PH of mixture at 25 ml addition stage is ..
a) 0.92 c) 11.49
b) 1.46 d) 1.00
47 10 ml of Na2CO3 on titration against 0.05 N HCl from burette, gives end pt 2 d
6.7 ml, using methyl orange indicator. Hence normality of Na2CO3 is
.N
a) 0.0225 c) 0.1
b) 0.052 d) 0.0335
48 20 ml NaHCO3 solution is titrated against N/40 H2SO4 solution gives end 2 a
point 16.2 ml using phenolphthalein indicator. The gm/lit of NaHCO3
is..
a) 1.7 c) 7.2
b) 2.7 d) 3.7
49 If 0.1 N Ce+4 ion solution from burette is added in 100 ml 0.1 N Fe+2 ion 2 b
solution in flask. The electrode potential of mixture isvolts at 10 ml
Ce+4 added.
a) 1.1 c) 1.4
b) 0.69 d) 0.96
50 If 0.1 N Ce+4 ion solution from burette is added in 100 ml 0.1 N Fe+2 ion 2 a
solution in flask. The electrode potential of mixture isvolts at 100 ml
Ce+4 added.
a) 1.1 c) 1.4
b) 0.69 d) 0.96
51 If 0.1 N Ce+4 ion solution from burette is added in 100 ml 0.1 N Fe+2 ion 2 c
solution in flask. The electrode potential of mixture isvolts at 120 ml
Ce+4 added.
a) 1.1 c) 1.4
b) 0.69 d) 0.96
52 If 0.1 N Ce+4 ion solution from burette is added in 100 ml 0.1 N Fe+2 ion 2 b
solution in flask. The electrode potential of mixture isvolts at 50 ml
Ce+4 added.
a) 0.69 c) 1.4
b) 0.75 d) 0.96
53 A given solution of Fe+2 is diluted to volume 250 ml. 25 ml of this solution 2 d
in titration against 0.05 N KMnO4 takes 18.4 ml up to end point. The Fe+2
ion quantity in the given solution is
a) 412.36 mg c) 134.21 mg
b) 341.25 mg d) 513.36 mg
54 75 ml of 0.2 N NaOH is diluted to 250 ml volume. Normality of diluted 2 a
solution is
a) 0.06 N b) 0.04 N c) 0.01 N d) 0.05 N
55 If 0.5 M K2Cr2O7 (mole.wt-294) solution will be required to make 5 lit. of 2 b
0.1 N solution. The volume of stock solution will be
ml
a) 266.76 b) 166.67 c) 149.36 d) 21.6
56 A solution is prepared by dissolving 20 ml ethyl alcohol (density- 0.86) in 2 c
100 ml water. The mole fraction of ethyl alcohol and water , in solution is
a) 0.327 b) 0.721 c) 0.937 d) 0.793
57 50 ml of the water sample requires 12.5 ml of the EDTA from burette, in 2 d
the titration at PH 12. The amount of Ca+2 ions is..mg per litre.
a) 250 b) 125 c) 215 d) 150
58 If 50 ml of a solution containing Ca++ is titrated against 0.035 M disodium 2 d
EDTA from burette to get the end point 20.4 ml in the complex metric
titration . The amount of Ca++ in solution ismg per lit.
a) 671.2 b) 172.6 c) 762.1 d) 571.2
59 The weight of H2C2O4.2H2O (Mole.Wt.= 126) required to make 500 ml of 2 a
0.2 N solution is
a) 6.3 gm b) 3.6 gm C) 5.6 gm d) 4.6 gm
60 The weight of KMnO4 required to make 500 ml 0.1 N KMnO4, for titration 2 b
in acidic medium.. gm
a) 6.15 b) 1.56 c) 2.65 d) 4.12
61 The volume of concentrated H2SO4 (98%) required to make 1 lit. of 2N 2 c
H2SO4 is.ml, if the density of concentrated H2SO4 is 1.8 gm/ml.
a) 54.44 b) 52.11 c) 55.56 d) 56.41
62 If 5.3 gm of Na2CO3 anhydrous is dissolved in water to make 1200 ml of 2 d
solution, then molarity of solution is . M
a) 0.024 b) 0.24 c) 0.42 d) 0.042
63 If 5.3 gm of Na2CO3 anhydrous is dissolved in water to make 1200 ml of 2 a
solution, then normality of solution is . N
a) 0.084 b) 0.84 c) 0.48 d) 0.048
64 Equivalent weight of K2Cr2O7 (mole.Wt.=294) is using ion electron 2 b
method
a) 63 b) 49 c) 94 d) 36
65 Equivalent weight of H2C2O4.2H2O (mole.Wt.=120) is using ion 2 a
electron method
a) 63 b) 49 c) 94 d) 36
66 Equivalent weight of KBrO3 (mole.Wt.=167) is using ion electron 2 c
method
a) 63 .87 b) 49 .14 c) 27.83 d) 36.27
67 If 15.3 ml of 0.1 N KOH solution from burette is added in 25 ml 0.08 N 2 d
H2SO4, the PH of mixture is
a) 3.19 b) 4.21 c) 0.19 d) 1.93
68 If 30 ml 0.12 N HCl solution from burette is added in 20 ml 0.11 N sodium 2 b
bicarbonate solution in flask.. The PH of titration mixture is
a) 6.917 b) 1.796 c) 2.647 d) 1.621
69 100 ml of 0.1 N weak acid (Ka = 1.2 x 10-7) in conical flask is titrated 2 c
against 0.2N NaOH from burette. The PH at initial stage of titration is
a) 4.2 b) 6.38 c) 3.96 d) 6.39
70 100 ml of 0.1 N weak acid (Ka = 1.2 x 10-7) in conical flask is titrated 2 a
against 0.2N NaOH from burette. The PH at equivalence point of titration
is
a) 9.87 b) 6.38 c) 3.96 d) 6.39
-7
71 100 ml of 0.1 N weak acid (Ka = 1.2 x 10 ) in conical flask is titrated 2 d
against 0.2N NaOH from burette. The PH at 51 ml addition stage of is
a) 4.2 b) 6.38 c) 3.96 d) 11.12
72 Match the following 2 a
1) Neutralization Titration P) formation of coordination compound
2) Precipitation titration Q) oxidation reduction reaction
3) Redox titration R) Formation of salt and water
4) Complexometric titration S) formation of precipitate

a) 1-R , 2- S , 3- Q , 4- P
b) 1- Q , 2- R , 3- P ,4- S
73 Match the following
1) Methyl Orange
2) Phenolphthalein
3) Bromothymol blue
4) Alizarin Yellow R
c) 1- R , 2- P , 3- S , 4- Q
d) 1- S , 2- Q ,3- R , 4- P
2 c
P) Yellow orange red
Q) Yellow - blue
R) Orange - yellow
S) Colourless - pink

a ) 1- R , 2- P , 3- S , 4- Q c) 1-R , 2- S , 3- Q , 4- P
b) 1- Q , 2- R , 3- P ,4- S d) 1- S , 2- Q ,3- R , 4- P

74 Match the following 2 b

1) Phenol red P) Orange - yellow
 2) Methyl red
3) Phenolphthalein
4) Methyl orange
a ) 1- R , 2- P , 3- S , 4- Q
b) 1-R , 2- S , 3- Q , 4- P
75 Match the following
1) Methyl orange
2) Phenolphthalein
3) Methyl red
4) Bromothymol blue
a ) 1- R , 2- P , 3- S , 4- Q
b) 1- S , 2- Q ,3- R , 4- P
76 Match the following
1) Phenol red
2) Alizarin Yellow R
3) Methyl Orange
4) Phenolphthalein
a) 1-R , 2- S , 3- Q , 4- P
b) 1- Q , 2- R , 3- P ,4- S
77 Match the following
1) Phosphoric acid
2) Calcium hydroxide
3) Nitric acid
4) Potassium hydroxide
a ) 1- R , 2- P , 3- S , 4- Q
b) 1-R , 2- S , 3- Q , 4- P
78 Match the following
1) Perchloric acid
2) Sodium hydroxide
3) Benzoic acid
4) Organic amines
a ) 1- R , 2- P , 3- S , 4- Q
c) 1- Q , 2- R , 3- P ,4- S
79 Match the following
1) Acetic acid
2) Sodium bicarbonate
3) Hydrochloric acid
4) Sodium hydroxide
a ) 1- R , 2- P , 3- S , 4- Q
b) 1- S , 2- Q ,3- R , 4- P
80 Match the following
1) Mohrs Method
2) Fajans Method
3) Volhard Method
4) Idometric Titration
a) 1-R , 2- S , 3- Q , 4- P
b) 1- Q , 2- R , 3- P ,4- S
Q) Colourless - pink
R) Yellow - Red
S) Red - yellow
c) 1- Q , 2- R , 3- P ,4- S
d) 1- S , 2- Q ,3- R , 4- P
2 d
P) Colour change at PH 6 7.6
Q) Colour change at PH 4.2 6.3
R) Colour change at PH 3.1 4.4
S) Colour change at PH 8.3 10
c) 1- Q , 2- R , 3- P ,4- S
d) 1-R , 2- S , 3- Q , 4- P
2 a
P) Colour change at PH 8.3 10
Q) Colour change at PH 3.1 4.4
R) Colour change at PH 6.8 8.4
S) Colour change at PH 10.1 12
c) 1- R , 2- P , 3- S , 4- Q
d) 1- S , 2- Q ,3- R , 4- P
2 b
P) Strong base
Q) Strong acid
R) weak acid
S) weak base
c) 1- Q , 2- R , 3- P ,4- S
d) 1- S , 2- Q ,3- R , 4- P
2 c
P) weak base
Q) weak acid
R) Strong acid
S) Strong base
c) 1-R , 2- S , 3- Q , 4- P
d) 1- S , 2- Q ,3- R , 4- P
2 d
P) Strong base
Q) Strong acid
R) Weak acid
S) Weak base
c) 1- Q , 2- R , 3- P ,4- S
d) 1-R , 2- S , 3- Q , 4- P
2 a
P) Starch
Q) Fe+3 ion solution
R) 5% K2CrO4
S) 0.5 % Organic dye
c) 1- R , 2- P , 3- S , 4- Q
d) 1- S , 2- Q ,3- R , 4- P
81 Match the following
1) Self Indicator
2) Starch Indicator
3) Internal Indicator
4) External Indicator
2 b
P) Potassium Ferricynaide
Q) Weak oxidizing or weak reducing agent
R) KMnO4
S) Iodimetric titration

a ) 1- R , 2- P , 3- S , 4- Q c) 1- Q , 2- R , 3- P ,4- S
b) 1-R , 2- S , 3- Q , 4- P d) 1- S , 2- Q ,3- R , 4- P
82 Match the following 2 c
1) Strong acid- Strong base Titration P) Not performed practically
2) Strong base -Weak acid titration Q) NH4OH Vs HCl
3) Strong acid - Weak base titration R) NaOH Vs HCl
4) Weak acid - Weak base titration S) NaOH Vs CH3COOH

a ) 1- R , 2- P , 3- S , 4- Q c) 1-R , 2- S , 3- Q , 4- P
b) 1- Q , 2- R , 3- P ,4- S d) 1- S , 2- Q ,3- R , 4- P
83 Match the following 2 d
1) Oxidizing agent P) Zinc
2) Reducing agent Q) AgCl
3) Salts R) K2Cr2O7
4) Metal S) Na2C2O4

a ) 1- R , 2- P , 3- S , 4- Q c) 1- Q , 2- R , 3- P ,4- S
b) 1- S , 2- Q ,3- R , 4- P d) 1-R , 2- S , 3- Q , 4- P
84 Match the following 2 a
1) Mohrs Method P) Self Indicator
2) Volhards Method Q) Adsorption Indicator
3) Fajans Method R) Formation of soluble coloured compounds
4) Redox Titration S) Formation of coloured precipitate

a) 1-R , 2- S , 3- Q , 4- P c) 1- R , 2- P , 3- S , 4- Q
b) 1- Q , 2- R , 3- P ,4- S d) 1- S , 2- Q ,3- R , 4- P
85 Match the following 2 b
1) Primary Standard for Neutralisation titration. P) K2Cr2O7
2) Primary Standard for Complexometric titration Q) AgNO3
3) Primary Standard for Precipitation titration R) Potassium
hydrogen phthalate
4) Primary Standard for Redox titration S) ZnSO4

a ) 1- R , 2- P , 3- S , 4- Q c) 1- Q , 2- R , 3- P ,4- S
b) 1-R , 2- S , 3- Q , 4- P d) 1- S , 2- Q ,3- R , 4- P